Search results for "SELE"

Introspection and equilibrium selection in 2 � 2 matrix games

1994

Game theory lacks an explanation of how players' beliefs are formed and why they are in equilibrium. This is the reason why it has failed to make significant advances with the problem of equilibrium selection even for quite siniple games, as 2x2 games with two strict Nash equilibria. Our paper models the introspection process by which the selected equilibrium is achieved in this class of games. Players begin their analysis with imprecise priors, obtained under weak restrictions formulated as Axioms. For a large class of reasoning dynamics we obtain as the solution the risk dominant Nash equilibrium.

Indium-Gallium Segregation inCuInxGa1−xSe2: AnAb Initio–Based Monte Carlo Study

2010

Thin-film solar cells with ${\mathrm{CuIn}}_{x}{\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Se}}_{2}$ (CIGS) absorber are still far below their efficiency limit, although lab cells already reach 20.1%. One important aspect is the homogeneity of the alloy. Large-scale simulations combining Monte Carlo and density functional calculations show that two phases coexist in thermal equilibrium below room temperature. Only at higher temperatures, CIGS becomes more and more a homogeneous alloy. A larger degree of inhomogeneity for Ga-rich CIGS persists over a wide temperature range, which contributes to the observed low efficiency of Ga-rich CIGS solar cells.

Nanostructured Based Electrochemical Sensors.

2019

In this work, we present some results concerning the electrochemical behavior of nanostructured-based electrochemical sensors. In particular, the attention has been focused on Pd and Cu nanowires for detection of hydrogen peroxide and NiO thin film or Ni@NiO core–shell nanowires for detection of mercury ions. Ordered array of Pd and Cu nanowires was obtained through displacement deposition reaction in a commercial polycarbonate membrane acting as a template. The method leads to stable nanostructured electrodes of Pd and Cu with high surface area. For the detection of mercury ions, we have fabricated a Ni/NiO electrochemical sensor, obtained by mild thermal oxidation of Ni-foil. Some results…

Large thermoelectric figure of merit in hexagonal phase of 2D selenium and tellurium

2020

Influence of crystallinity and OH surface density on the photocatalytic activity of TiO2 powders

2014

Abstract The aim of the work was to study the influence of crystallinity and OH surface density on the photocatalytic activity of two commercial and two home-prepared TiO 2 powders. The samples were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TG) and electron paramagnetic resonance (EPR) measurements. The photoactivity of the powders was tested employing the photodegradation of 4-nitrophenol (4-NP) and the selective oxidation of 4-methoxybenzyl alcohol (4-MBA) to 4-methoxybenzaldehyde ( p -anisaldehyde) under UV irradiation. An anti-correlation between oxidant power and selectivity of the various samples was found. A higher rate of 4-NP degradation was exhibited by…

A highly reduced graphene oxide/ZrOx–MnCO3 or –Mn2O3 nanocomposite as an efficient catalyst for selective aerial oxidation of benzylic alcohols

2017

Highly reduced graphene oxide (HRG) nanocomposites of manganese carbonate doped with (1%) zirconia (ZrOx) nanoparticles [ZrOx(1%)–MnCO3/(X%)HRG (where X = 0–7)] were prepared employing a facile co-precipitation method in which the percentage of HRG was varied. The resulting nanocomposite was calcined at 300 °C. Further calcination of the catalyst at 500 °C resulted in the conversion of manganese carbonate to manganese oxide [ZrOx(1%)–Mn2O3/(X%)HRG]. The effect of the inclusion of HRG on the catalytic activity along with its comparative performance between carbonates and their respective oxides was studied for the liquid-phase selective oxidation of benzylic alcohols into corresponding aldeh…

“The tale of the three little tits”: Different nest building solutions under the same environmental pressures

2020

Evolutionary selection pressures, and species-specific ecology and behavior, promote a great variability in the size and composition of nests. However, it would be expected that phylogenetically close species, with similar ecological needs, breeding at the same time in the same place, would also build similar nests. In contrast with this, previous studies have found differences in nest mass and composition among closely related sympatric species. These differences have been attributed to small differences in body size (smaller species building larger and/or more insulated nests), or to the different ways in which species perceive the environment (e.g. perceived predation risk). In this stud…

Synthesis and Photoelectrical Properties of 3-(Diphenylamino)Carbazolyl-Functionalized DMABI Derivatives

2019

A modular approach was used in the synthesis of the 3-(diphenylamino)carbazolyl- functionalized 2-(4-(dimethylamino)benzylidene)-1H-indene-1,3(2H)-dione (DMABI) derivatives. For this purpose, carboxyl functional group was introduced into the framework of DMABI molecule. Additionally, a regioselective method for substitution of carbonyl group of DMABI with dicyanomethylene group was investigated and verified using the heteronuclear multiple bond correlation NMR spectra. Steglich esterification method was used to connect the 3‑(diphenylamino)carbazolyl moiety via an unconjugated spacer. The UV-Vis absorption spectra and molecular energy level data were obtained for the evaluation of the synth…

New Gold(I) Organometallic Compounds with Biological Activity in Cancer Cells

2014

N-Heterocyclic carbene gold(I) complexes bearing a fluorescent coumarin ligand were synthesized and characterized by various techniques. The compounds were examined for their antiproliferative effects in normal and tumor cells in vitro; they demonstrated moderate activity and a certain degree of selectivity. The compounds were also shown to efficiently inhibit the selenoenzyme thioredoxin reductase (TrxR), whereas they were poorly effective towards the glutathione reductase (GR) and glutathione peroxidase enzymes. Notably, {3-[(7-methoxy-2-oxo-2H-chromen-4-yl) methyl]-1-methylimidazol-2-ylidene}(tetra-O-acetyl-1-thio-beta-D-glucopyranosido) gold(I) (3) showed a pronounced inhibition of TrxR…

Qualità della didattica universitaria e sviluppo della capacità decisionale. Il modello ADVP per garantire i passaggi da L-19 a LM-85bis.

2020

Il presente contributo intende offrire una riflessione sulle competenze attese individuate attraverso la formulazione dei descrittori di Dublino dei CdS in Scienze dell’Educazione (L-19) e Scienze della Formazione Primaria (LM-85bis) istituiti presso l’Ateneo di Palermo e nello stesso tempo proporre un modello per lo sviluppo della maturità professional e necessaria a garantire scelte consapevoli, mature e responsabili. L’analisi condotta ci ha permesso, in una seconda fase di individuare gli obiettivi formativi finali scelti seguendo il modello proposto dalle Linee Guida dell ’Anvur, e di scegliere il modello dell’Activaction du Developpement Vocationnel et Personnel quale strumento per lo…