Search results for "SELE"

showing 10 items of 4721 documents

Regio- and Stereoselective Chloro Sulfoximidations of Terminal Aryl Alkynes Enabled by Copper Catalysis and Visible Light

2021

Advanced synthesis & catalysis 2552-2556 (2021). doi:10.1002/adsc.202100162

copper catalysisvinyl sulfoximine660StereochemistryAryldifunctionalizationchemistry.chemical_elementGeneral Chemistryalkyne additionCoppervisible-light photoredox catalysisCatalysischemistry.chemical_compoundTerminal (electronics)chemistryddc:660StereoselectivityVisible spectrum
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Market Entry and Priority of Small and Medium-Sized Enterprises in the Software Industry: An Empirical Analysis of Cultural Distance, Geographical Di…

2007

This paper investigates the influence of cultural distance, geographical distance, and three market size variables to the target country preference of SMEs in the software industry. In addition, we examine the shift of priorities in SMEs’ country selection by analyzing how these factors impact the selection of the first, second, and third target countries. Empirical findings of this study suggest that almost 70% of country choices can be explained by software market size and geographical distance alone. The findings adduced also that entry priority of SMEs shifts very fast from countries within a short geographical distance to countries with high purchasing power and within a greater geogra…

country selectionsoftware firmsMarket entrySMEsinternationalization
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Criteria for selecting children with special needs for dental treatment under general anaesthesia

2007

Objective: To study criteria for helping to select children with special needs for dental treatment under general anaesthesia. Materials and methods: Group of 30 children (aged under 18) examined on the Course at the Universidad Complutense de Madrid (UCM) (Specialisation on holistic dental treatment of children with special needs) and subsequently referred to the Disabled Children’s Oral Health Unit (DCOHU) within Primary Health Care Area 2 of the Madrid Health Service (SERMAS) where dental treatment under general anaesthesia was given during 2005. Relevant data were taken from their case histories with regard to their general health, oral health and behaviour. Results: In most of the chil…

criterios selección anestesia generalChildren with special needs and general anaesthesiaUNESCO::CIENCIAS MÉDICASbehaviour and general anaesthesia:CIENCIAS MÉDICAS [UNESCO]comportamiento y anestesia generalselection criteria for general anaesthesiaNiños especiales y anestesia general
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Organotin(IV) selenate derivatives – Crystal structure of [{(Ph 3 Sn) 2 SeO 4 } ⋅ CH 3 OH] n

2021

Abstract Crystallization of [(Ph3Sn)2SeO4] ⋅ 1.5H2O in methanol leads to the formation of [{(Ph3Sn)2SeO4} ⋅ CH3OH] n (1) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex 1 is arranged in polymeric zig-zag chains, composed of alternating Ph3Sn and SeO4 groups. In addition, pendant Ph3Sn ⋅ CH3OH moieties are branched along chains according to a syndiotactic organization and via Sn-O-Se connections. From a supramolecular point of view, intermolecular hydrogen bonds established between the selenate groups (uncoordinated oxygen) and the hydroxyl functions (CH3OH) of the pendant groups link the chains together.

crystal structure010405 organic chemistryMetals and AlloysGeneral ChemistryCrystal structureorganotin(iv)010402 general chemistryCondensed Matter Physics01 natural sciencesSelenate3. Good health0104 chemical scienceschemistry.chemical_compoundCrystallographyChemistrychemistryMaterials Chemistryinorganic chain[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryseleniumsn-o-se moietyQD1-999
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5-Methylbenzo[d][2,1,3]selenadiazole

2017

In the crystal of the title compound, C7H6N2Se, the molecules are arranged in rods along theb-axis direction and form dimeric units due to intermolecular Se...N contacts of 2.982 (2) Å. The molecules are further linked by weak π–π stacking interactions between the 2,1,3-selenadiazole and six-membered aromatic rings [centroid–centroid distance = 3.8509 (11) Å and ring slippage = 1.539 (3) Å].

crystal structure010405 organic chemistryStereochemistrySe...N contactsStackingselenadiazoleAromaticityCrystal structure010402 general chemistryRing (chemistry)01 natural sciences0104 chemical sciencesCrystallographychemistry.chemical_compoundchemistryπ–π interactionslcsh:QD901-999Diazolelcsh:CrystallographyIUCrData
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A highly selective, Hg2+ triggered hydrogelation: modulation of morphology by chemical stimuli

2014

We report the first Hg2+ selective hydrogelation by 4´-[4-(4- aminophenyl)phenyl]-2,2´:6´,2´´-terpyridine. The gel showed remarkable response towards specific chemical agents such as benzo-18-crown-6 ether and K+ which enabled extensive 10 modulation of the gel morphology. peerReviewed

crystal structureSuzuki reactionmorphologytransmission electron microscopygelationselective hydrogelationhydrogelmodulation of morphologyscanning electron microscopy
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Selective formation of a unique diphosphonium-diphosphine from a tetraphosphine double protonation induced by zirconium salts

2008

A mixed ferrocenyl diphosphonium-diphosphine cation, associated with two [ZrCl(5).thf](-) anions, is obtained from a ferrocenyl tetraphosphine, as a unique didentate ionic metalloligand in a perfectly selective reaction induced by ZrCl(4) in THF.

crystal structureZirconiumSelective reaction010405 organic chemistryChemistryprotonationInorganic chemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistryzirconiumIonic bondingchemistry.chemical_elementProtonationphosphonium010402 general chemistry01 natural sciencesferrocenyl0104 chemical sciences3. Good healthInorganic ChemistryPolymer chemistrypolyphosphine[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSDalton Transactions
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Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative

2018

Abstract The polymeric organotin(IV) selenate complex [(Me3Sn)3(SeO4)(OH)]n (1) has been isolated as single crystals from the reaction of [(Me2NH2)2SeO4] and Me3SnCl in methanol. In the solid state, compound 1 was characterized by X-ray diffraction analysis, Fourier transform-infrared spectroscopy, and elemental analysis. 1 crystallizes in the orthorhombic system space group Pbca with a=11.0231(2) Å, b=16.3461(3) Å, c=20.9945(4) Å, α=β=γ=90°, V=3782.89(12) Å3, and Z=8. Its structure can be described as a polymeric zigzag chain based on Me3Sn moieties linked by tridentate selenate anions. Pendant (Me3Sn)2OH groups are also connected to the chain, according to a syndiotactic organization, and…

crystal structurechemistry.chemical_elementCrystal structureorganotin(iv)010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesSelenateoxoanionschemistry.chemical_compoundComputational chemistryMaterials Chemistry[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryseleniumQD1-999ComputingMilieux_MISCELLANEOUSMetals and AlloysGeneral ChemistryCondensed Matter Physics0104 chemical sciencesChemistrychemistrysn-o-se moietySeleniumDerivative (chemistry)Main Group Metal Chemistry
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rac-11-Selena-12,13-diazabicyclo[10.3.0]pentadeca-10a(13a),12-dien-1-ol

2021

The title compound, C12H20N2OSe, crystallizes in strands of enantiomeric molecules connected via O—H...N hydrogen bonds. There are only slight deviations from an ideal gauche conformation in the decamethylene chain, indicating just a little strain.

crystal structureheterocyclesCrystallographyBicyclic moleculeStrain (chemistry)010405 organic chemistryHydrogen bondChemistryStereochemistryCrystal structure010403 inorganic & nuclear chemistry01 natural sciences0104 chemical sciencesQD901-999medium-sized ringseleniumDeca-IUCrData
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rac-12-Selena-13,14-diazatricyclo[9.3.0.02,4]tetradeca-11,13-diene

2020

The centrosymmetric crystal structure of the title compound, C11H16N2Se, is built up from alternating strands of (R,R)- and (S,S)-enantiomers. These strands, which propagate along the c-axis direction, are composed of homochiral molecules related to each other by twofold screw axes. The shape of the molecule is an almost planar unit around the selenadiazole ring with a hexamethylene chain as an arched handle.

crystal structureheterocyclesbiologyDieneGeneral MedicineCrystal structure010402 general chemistry010403 inorganic & nuclear chemistrybiology.organism_classificationRing (chemistry)01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryChain (algebraic topology)lcsh:QD901-999Tetramedium-sized ringlcsh:CrystallographyseleniumUnit (ring theory)Deca-IUCrData
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