Search results for "SEPARATION"

showing 10 items of 865 documents

Simultaneous screening and quantification of aminoglycoside antibiotics in honey using mixed-mode liquid chromatography with quadrupole time-of-fligh…

2018

An analytical method based on liquid chromatography with quadrupole time-of-flight mass spectrometry has been developed for the simultaneous determination of six aminoglycoside antibiotics in honey. The sample pretreatment included extraction with aqueous trichloroacetic acid followed by solid-phase extraction on Strata-X polymeric reversed phase cartridges. Liquid chromatography separation was performed on an Obelisc R zwitterionic type mixed-mode column. An ionBooster™ heated electrospray source was used and showed enhanced ionization efficiency in comparison to a conventional electrospray source. The observed signal enhancement ranged from 3- (neomycin) to 16-fold (gentamicin C1). A data…

Spectrometry Mass Electrospray IonizationElectrosprayTime FactorsElectrospray ionizationDrug Evaluation PreclinicalFiltration and Separation02 engineering and technologyMass spectrometry01 natural sciencesMass SpectrometryAnalytical ChemistryIonizationChromatographyChemistry010401 analytical chemistryAminoglycosideExtraction (chemistry)HoneyRepeatability021001 nanoscience & nanotechnologyAnti-Bacterial Agents0104 chemical sciencesAminoglycosidesGentamicin C10210 nano-technologyChromatography LiquidJournal of Separation Science
researchProduct

Solution of XXZ and XYZ spin chains with boundaries by separation of variables

2014

In this thesis we give accounts on the solution of the open XXZ and XYZ quantum spin-1/2 chains with the most generic integrable boundary terms. By using the the Separation of Variables method (SoV), due to Sklyanin, we are able, in the inhomogeneous case, to build the complete set of eigenstates and the associated eigenvalues. The characterization of these quantities is made through a maximal system of N quadratic equations, where N is the size of the chain. Different methods, like the Algebraic Bethe ansatz (ABA) or other generalized Bethe ansatz techniques, have been used, in the past, in order to tackle these problems. None of them resulted effective in the reproduction of the full set …

SpinXXZOpenXYZBoundaryChainsSeparation of variablesBethe[MATH.MATH-MP] Mathematics [math]/Mathematical Physics [math-ph]AnsatzSklyanin
researchProduct

Signal detection for spread spectrum communication systems with gradient algorithm

2012

Retrieval process of original symbols of a spread spectrum based communication system is tried to be improved by Gradient Algorithm (GA) and Blind Source Separation (BSS) principles. Two simple schemes, based on two energy functions are presented. Time correlation properties of the channel are used as advantages in developing the filter coefficients for the receiver. Direct Sequence - Code Division Multiple Access (DS-CDMA) technique based system setup is used for algorithm testing purposes. This is identified as one of the most stable spread spectrum communication technique where most of the technologies developed for that are highly compatible with High Speed Packet Access (HSPA) transmis…

Spread spectrumHigh Speed Packet AccessTransmission (telecommunications)Computer scienceCode division multiple accessDirect-sequence spread spectrumCommunications systemChipAlgorithmBlind signal separation2012 IEEE 8th International Conference on Wireless and Mobile Computing, Networking and Communications (WiMob)
researchProduct

Independent component analysis based on symmetrised scatter matrices

2007

A new method for separating the mixtures of independent sources has been proposed recently in [Oja et al. (2006). Scatter matrices and independent component analysis. Austrian J. Statist., to appear]. This method is based on two scatter matrices with the so-called independence property. The corresponding method is now further examined. Simple simulation studies are used to compare the performance of so-called symmetrised scatter matrices in solving the independence component analysis problem. The results are also compared with the classical FastICA method. Finally, the theory is illustrated by some examples. peerReviewed

Statistics and ProbabilityApplied MathematicsIndependence propertyStatistical computationhajontamatriisitIndependent component analysisComputational MathematicsComputational Theory and MathematicsComponent analysisSimple (abstract algebra)CalculusSource separationFastICAApplied mathematicsICAIndependence (probability theory)MathematicsComputational Statistics & Data Analysis
researchProduct

On Independent Component Analysis with Stochastic Volatility Models

2017

Consider a multivariate time series where each component series is assumed to be a linear mixture of latent mutually independent stationary time series. Classical independent component analysis (ICA) tools, such as fastICA, are often used to extract latent series, but they don't utilize any information on temporal dependence. Also financial time series often have periods of low and high volatility. In such settings second order source separation methods, such as SOBI, fail. We review here some classical methods used for time series with stochastic volatility, and suggest modifications of them by proposing a family of vSOBI estimators. These estimators use different nonlinearity functions to…

Statistics and ProbabilityAutoregressive conditional heteroskedasticity01 natural sciencesQA273-280GARCH model010104 statistics & probabilityblind source separation0502 economics and businessSource separationEconometricsApplied mathematics0101 mathematics050205 econometrics MathematicsStochastic volatilitymultivariate time seriesApplied MathematicsStatistics05 social sciencesAutocorrelationEstimatorIndependent component analysisHA1-4737nonlinear autocorrelationFastICAStatistics Probability and UncertaintyVolatility (finance)Probabilities. Mathematical statistics
researchProduct

Blind Source Separation Based on Joint Diagonalization in R: The Packages JADE and BSSasymp

2017

Blind source separation (BSS) is a well-known signal processing tool which is used to solve practical data analysis problems in various fields of science. In BSS, we assume that the observed data consists of linear mixtures of latent variables. The mixing system and the distributions of the latent variables are unknown. The aim is to find an estimate of an unmixing matrix which then transforms the observed data back to latent sources. In this paper we present the R packages JADE and BSSasymp. The package JADE offers several BSS methods which are based on joint diagonalization. Package BSSasymp contains functions for computing the asymptotic covariance matrices as well as their data-based es…

Statistics and ProbabilityComputer scienceJADE (programming language)02 engineering and technologyLatent variableMachine learningcomputer.software_genre01 natural sciencesBlind signal separation010104 statistics & probabilityMatrix (mathematics)nonstationary source separationMixing (mathematics)0202 electrical engineering electronic engineering information engineeringsecond order source separation0101 mathematicslcsh:Statisticslcsh:HA1-4737computer.programming_languageta113Signal processingta112matematiikkamultivariate time seriesmathematicsbusiness.industryEstimator020206 networking & telecommunicationsriippumattomien komponenttien analyysiindependent component analysis; multivariate time series; nonstationary source separation; performance indices; second order source separationIndependent component analysisperformance indicesstatisticsindependent component analysisArtificial intelligenceStatistics Probability and UncertaintybusinesscomputerAlgorithmSoftwareJournal of Statistical Software
researchProduct

A review of second‐order blind identification methods

2021

Second-order source separation (SOS) is a data analysis tool which can be used for revealing hidden structures in multivariate time series data or as a tool for dimension reduction. Such methods are nowadays increasingly important as more and more high-dimensional multivariate time series data are measured in numerous fields of applied science. Dimension reduction is crucial, as modeling such high-dimensional data with multivariate time series models is often impractical as the number of parameters describing dependencies between the component time series is usually too high. SOS methods have their roots in the signal processing literature, where they were first used to separate source sign…

Statistics and ProbabilityComputer sciencebusiness.industryDimensionality reductionSecond order blind identificationPattern recognitionArtificial intelligencebusinessBlind signal separationWIREs Computational Statistics
researchProduct

Identifying Causal Effects with the R Package causaleffect

2017

Do-calculus is concerned with estimating the interventional distribution of an action from the observed joint probability distribution of the variables in a given causal structure. All identifiable causal effects can be derived using the rules of do-calculus, but the rules themselves do not give any direct indication whether the effect in question is identifiable or not. Shpitser and Pearl constructed an algorithm for identifying joint interventional distributions in causal models, which contain unobserved variables and induce directed acyclic graphs. This algorithm can be seen as a repeated application of the rules of do-calculus and known properties of probabilities, and it ultimately eit…

Statistics and ProbabilityFOS: Computer and information sciencesTheoretical computer sciencecausalityDistribution (number theory)C-componentComputer sciencecausal model02 engineering and technologyCausal structureMethodology (stat.ME)03 medical and health sciences0302 clinical medicinedo-calculusJoint probability distribution0202 electrical engineering electronic engineering information engineering030212 general & internal medicineDAG; do-calculus; causality; causal model; identifiability; graph; C-component; hedge; d-separationlcsh:Statisticslcsh:HA1-4737Statistics - Methodologycomputer.programming_languageCausal modelta112DAGd-separationgraphhedgeidentifiabilityExpression (mathematics)PEARL (programming language)Action (philosophy)kausaliteetti020201 artificial intelligence & image processingStatistics Probability and UncertaintycomputerSoftware
researchProduct

A more efficient second order blind identification method for separation of uncorrelated stationary time series

2016

The classical second order source separation methods use approximate joint diagonalization of autocovariance matrices with several lags to estimate the unmixing matrix. Based on recent asymptotic results, we propose a novel unmixing matrix estimator which selects the best lag set from a finite set of candidate sets specified by the user. The theory is illustrated by a simulation study.

Statistics and ProbabilityMathematical optimizationaffine equivarianceminimum distance indexasymptotic normalityAsymptotic distributionlinear process01 natural sciencesSet (abstract data type)010104 statistics & probabilityMatrix (mathematics)SOBIComputingMethodologies_SYMBOLICANDALGEBRAICMANIPULATION0502 economics and businessSource separationjoint diagonalization0101 mathematicsFinite set050205 econometrics Mathematicsta112Series (mathematics)05 social sciencesEstimatorAutocovarianceStatistics Probability and UncertaintyAlgorithmStatistics & Probability Letters
researchProduct

Statistical properties of a blind source separation estimator for stationary time series

2012

Abstract In this paper, we assume that the observed p time series are linear combinations of p latent uncorrelated weakly stationary time series. The problem is then, using the observed p -variate time series, to find an estimate for a mixing or unmixing matrix for the combinations. The estimated uncorrelated time series may then have nice interpretations and can be used in a further analysis. The popular AMUSE algorithm finds an estimate of an unmixing matrix using covariances and autocovariances of the observed time series. In this paper, we derive the limiting distribution of the AMUSE estimator under general conditions, and show how the results can be used for the comparison of estimate…

Statistics and ProbabilityMatrix (mathematics)Random variateSeries (mathematics)Covariance matrixStatisticsAsymptotic distributionApplied mathematicsEstimatorStatistics Probability and UncertaintyLinear combinationBlind signal separationMathematicsStatistics & Probability Letters
researchProduct