Search results for "SEPARATION"
showing 10 items of 865 documents
Competing factors on the frequency separation between the OH stretching modes in water
2015
Abstract Recent simulations demonstrated that the inhomogeneous broadening as observed in the vibrational spectra of liquid water at ambient conditions can be viewed as a large vibrational splitting of symmetric and asymmetric OH stretching modes, due to the asymmetry of the local hydrogen-bonding network [J. Phys. Chem. Lett., 2013, 4(19), pp 3245–3250]. In this work, we show that the finite temperature and the liquid phase do not only modulate the local hydrogen-bonding asymmetry of water molecules, but also the intramolecular coupling strength. These two factors compete together in the determination of the overall magnitude of the frequency separation between the two OH stretching modes …
D2 and H2 adsorption capacity and selectivity in CHA zeolites: Effect of Si/Al ratio, cationic composition and temperature
2020
International audience; The work deals with the effect of composition of CHA zeolites on the adsorption and separation of H2 and D2 under cryogenic temperatures. In the first part of this work the effect of Si/Al ratio and cationic composition on single gas adsorption of H2 and D2 was studied at 77.4 K. It was found that the adsorption capacities increase with Al content up to Si/Al = 2.1. Unexpectedly, Na-CHA zeolite with the highest Al content (Si/Al = 1.1) adsorbs only negligible amount because of the collapse of the zeolite structure upon dehydration at 400°C. The Na-and Li-containing chabazites with Si/Al = 2.1 possess similar adsorption capacities. In contrast, progressive replacement…
Some insights on the description of gradient elution in reversed-phase liquid chromatography
2014
The so-called "fundamental equation for gradient elution" has been used for modeling the retention in gradient elution. In this approach, the instantaneous retention factor (k) is expressed as a function of the change in the modifier content (φ(ts )), ts being the time the solute has spent in the stationary phase. This approach can only be applied at constant flow rate and with gradients where the elution strength depends on the column length following a f(t-l/u) function, u being the linear mobile phase flow rate, and l the distance from the column inlet to the location where the solute is at time t measured from the beginning of the gradient. These limitations can be solved by using the h…
Effect of different aqueous solutions of pure salts and salt mixtures in reverse electrodialysis systems for closed-loop applications
2018
Abstract Reverse Electrodialysis (RED) in a closed-loop arrangement is a viable way to convert low-grade heat into electric power. The present work experimentally investigates the use of pure salt- and equimolar two salts-water solutions as feeds in a lab-scale RED unit. RED performances were analysed in terms of Open Circuit Voltage (OCV), stack resistance and corrected power density. The pure salts and the mixtures employed were chosen via a computational analysis. Effect of feed solution velocity and concentration was investigated. Results concerning the pure salt-water experiments show that NH4Cl is the most performing salt in the concentration range probed, while higher power density v…
Source separation on hyperspectral cube applied to dermatology
2010
International audience; This paper proposes a method of quantification of the components underlying the human skin that are supposed to be responsible for the effective reflectance spectrum of the skin over the visible wavelength. The method is based on independent component analysis assuming that the epidermal melanin and the dermal haemoglobin absorbance spectra are independent of each other. The method extracts the source spectra that correspond to the ideal absorbance spectra of melanin and haemoglobin. The noisy melanin spectrum is fixed using a polynomial fit and the quantifications associated with it are reestimated. The results produce feasible quantifications of each source compone…
Prise en eau par composites carbone/époxy et leur effet sur le comportement mécanique : application aux réparations de structures en composite par co…
2013
Le travail présenté dans ce mémoire avait pour objectif d’étudier le processus de la pénétration d'eau dans les composites en carbone/époxyde dans un premier temps, et dans un deuxième temps, d’étudier l’effet de la prise en eau par ces matériaux sur les performances mécaniques des composites et leur joints collés. L'intégration de ces phénomènes physiques dans la modélisation numérique est d'une grande importance dans la prédiction de la durabilité d’une structure en composite subissant un vieillissement hygrothermique. Par conséquent, ce travail consiste non seulement en des observations expérimentales, mais aussi en des simulations numériques. Des corrélations entre les résultats obtenus…
Prospects for advanced electron cyclotron resonance and electron beam ion source charge breeding methods for EURISOL
2011
International audience; As the most ambitious concept of isotope separation on line (ISOL) facility, EURISOL aims at producing unprecedented intensities of post-accelerated radioactive isotopes. Charge breeding, which transforms the charge state of radioactive beams from 1+ to an n+ charge state prior to postacceleration, is a key technology which has to overcome the following challenges: high charge states for high energies, efficiency, rapidity and purity. On the roadmap to EURISOL, a dedicated R&D is being undertaken to push forward the frontiers of the present state-of-the-art techniques which use either electron cyclotron resonance or electron beam ion sources. We describe here the gui…
Influence de l'état protéique sur la dynamique de séparation de phase et de gélification dans un système ternaire aqueux à base de protéines de pois …
2012
Two aqueous systems at 20°C in 0.1 M NaCl and pH 7.2 containing globular pea proteins and sodium alginate were investigated in this study. First, phase behavior of (i) either low-denatured mixed globulins or (ii) their thermally pre-aggregated counterparts - alginate mixtures was compared using a multi-scale approach, by means of phase diagram and microstructure analysis by confocal microscopy. Thermodynamic incompatibility was the main driving force leading to phase separation within the mixtures, which presented according to their initial biopolymer composition both different morphological and time-evolution features of coexisting phases. Thereafter, a cold-set gelation for each system wa…
The Mistigri Thermal Infrared Project: Scientific Objectives And Mission Specifications
2013
ISI Document Delivery No.: 147NI Times Cited: 4 Cited Reference Count: 117 Cited References: Abrams M, 2000, INT J REMOTE SENS, V21, P847, DOI 10.1080/014311600210326 Agam N, 2007, J GEOPHYS RES-ATMOS, V112, DOI 10.1029/2007JD008407 Allen RG, 2007, J IRRIG DRAIN E-ASCE, V133, P380, DOI 10.1061/(ASCE)0733-9437(2007)133:4(380) Alletto L, 2006, CHEMOSPHERE, V64, P1053, DOI 10.1016/j.chemosphere.2005.12.004 Arnfield AJ, 2003, INT J CLIMATOL, V23, P1, DOI 10.1002/joc.859 Baschek B., 2010, 2010 OC SCI M PORTL Bastiaanssen WGM, 1998, J HYDROL, V212, P198, DOI 10.1016/S0022-1694(98)00253-4 Bastiaanssen WGM, 2005, J IRRIG DRAIN E-ASCE, V131, P85, DOI 10.1061/(ASCE)0733-9437(2005)131:1(85) Beck LR, 2…
The standard GC retention index library of flavour compounds
1994
International audience