Search results for "SITES"
showing 10 items of 2851 documents
Effects of phenolic-like intercalated layered double hydroxides on poly(lactic acid) based nanocomposites
2015
Two phenolic-like antioxidants (AOs), 3-(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate and 6-hydroxy-2,5,7,8-tetrametilcromano-2-carboxylate anions, were intercalated by anion exchange in layered double hydroxides (LDHs). The two AO-LDHs were dispersed by ultrasound-assisted solution mixing in poly(lactic acid) (PLA) and the thermal oxidation stability of the composites was evaluated following the variation of the molecular weight by SEC, after a controlled aging process, and determining the oxidation induction time (OIT) by DSC. The results evidenced that the intercalation of both the AO molecules within the LDH galleries prevent their own thermal and thermo-oxidative degradation as well a…
Polycationic Monomeric and Homodimeric Asymmetric Monomethine Cyanine Dyes with Hydroxypropyl Functionality—Strong Affinity Nucleic Acids Binders
2021
New analogs of the commercial asymmetric monomethine cyanine dyes thiazole orange (TO) and thiazole orange homodimer (TOTO) with hydroxypropyl functionality were synthesized and their properties in the presence of different nucleic acids were studied. The novel compounds showed strong, micromolar and submicromolar affinities to all examined DNA ds-polynucleotides and poly rA–poly rU. The compounds studied showed selectivity towards GC-DNA base pairs over AT-DNA, which included both binding affinity and a strong fluorescence response. CD titrations showed aggregation along the polynucleotide with well-defined supramolecular chirality. The single dipyridinium-bridged dimer showed intercalatio…
Original data for manuscript: Quantity and Quality of Aquaculture Enrichments Influence Disease Epidemics and Provide Ecological Alternatives to Anti…
2021
The data processed and analyzed in this study are given in a single file: Karvonen et al. exposure data.xlsx. For detailed description of the material, methods and results of the study, see the article.
On site archaeological museums: types of protection
2011
The decision to preserve, in their original context, even the most fragile artefacts, such as floor and wall coverings and to exhibit the delicate stratigraphic or clay manufactures, has favoured the spread of archaeological museums in situ, by interventions aimed at the preservation of archaeological remains. Archaeological museums represent a particular typology capable of relating history through its ruins. Therefore, it is not a museum having typological and functional characteristics that answer to codified museum-graphical and display rules . The arrangement and the public opening of the archaeological sites in recent years have been the object of discussions, debates and interdiscipl…
Proteggere e Valorizzare: una buona pratica per i siti archeologici
2014
Tra i beni culturali quelli archeologici hanno più animato il dibattito culturale sul rapporto tra conservazione e loro messa in valore. La fragilità con cui la materia ci viene consegnata dalla storia, la frammentarietà del reperto, la scarsa disponibilità di risorse finanziarie, anche in relazione alla vastità del patrimonio a noi pervenuto, impongono interventi mirati e talvolta urgenti per la salvaguardia e la conservazione dei beni archeologici. Ma la sola conservazione non può però costituire l’obiettivo ultimo dell’intervento: poiché i beni archeologici rappresentano il nostro lontano passato è anche necessario recuperarne il valore e comunicarne l’identità. La conoscenza storica, st…
Open air ruins: protection systems for Lucentum Rovine all’aria aperta: sistemi di protezione per Lucentum
2013
John H. Stubbs scrive che le costruzioni, opera dell’uomo, si trovano tutte in un dinamico stato d’interscambio verso un equilibrio con le forze della natura e che il patrimonio archeologico, per la sua particolare e intrinseca fragilità, essendo costituito di materia in avanzato stato di deterioramento, è particolarmente esposto all’azione degli agenti naturali, pertanto i problemi della conservazione e della presentazione in situ dei reperti archeologici rappresentano una delle maggiori difficoltà cui vanno incontro archeologi e conservatori di elementi architettonici. Tale giudizio, profondamente vero per tanti siti archeologici extra-urbani spesso lontani da qualsiasi possibilità di tut…
Asymmetric synthesis of functionalized tetrahydrofluorenones via an NHC-catalyzed homoenolate Michael addition
2018
The first example of an N-heterocyclic carbene-catalyzed asymmetric desymmetrization of enal-tethered cyclohexadienones via an intramolecular homoenolate Michael addition/esterification reaction is described. This new protocol offers a direct entry to various functionalized tetrahydrofluorenones with three contiguous stereocenters in high yields, good diastereoselectivities and excellent enantioselectivities.
Céramiques diélectriques commandables pour applications micro-ondes : composites à base de titanate de baryum-strontium et d'un oxyde non ferroélectr…
2001
Since the last decades, dielectric ceramics have been considered as attractive for microwave applications as tunable dielectric resonators or phase shifters. For that, ceramic devices should be tunable – change in dielectric constant with applied voltage- with moderate to low dielectric constant (30 to 1000) and loss tangent as low as possible. To reconcile these properties, composite ceramics based on Ba0.6Sr0.4TiO3 (BSTO) and a non-ferroelectric oxide with a low dielectric constant (MgTiO3 or MgO) were synthesised. The aim of this study was to correlate the microstructure with the dielectric properties, especially the Curie temperature and the dielectric relaxation phenomena.Ceramics with…
Novel Insights into the Cellular Localization and Regulation of the Autophagosomal Proteins LC3A, LC3B and LC3C
2020
Macroautophagy is a conserved degradative process for maintaining cellular homeostasis and plays a key role in aging and various human disorders. The microtubule-associated protein 1A/1B light chain 3B (MAP1LC3B or LC3B) is commonly analyzed as a key marker for autophagosomes and as a proxy for autophagic flux. Three paralogues of the LC3 gene exist in humans: LC3A, LC3B and LC3C. The molecular function, regulation and cellular localization of LC3A and LC3C have not been investigated frequently, even if a similar function to that described for LC3B appears likely. Here, we have selectively decapacitated LC3B by three separate strategies in primary human fibroblasts and analyzed the evoked e…
Strengthening of Masonry Columns with BFRCM or with Steel Wires: An Experimental Study
2016
Nowadays, innovative materials are more frequently adopted for strengthening historical constructions and masonry structures. The target of these techniques is to improve the structural efficiency with retrofitting methods while having a reduced aesthetical impact. In particular, the use of basalt fiber together with a cementitious matrix emerges as a new technique. This kind of fiber is obtained by basalt rock without other components, and consequently it could be considered a natural material, compatible with masonry. Another innovative technique for strengthening masonry columns consists of applying steel wires in the correspondence of mortar joints. Both techniques have been recently pr…