Search results for "SITES"

Graphene oxide and Fumed silica graphene oxide nanocomposites modification by thermal treatments

2014

In the present study we investigate post synthesis thermal treatments up to 400 °C of graphene oxide (GrO) prepared from commercial graphite and of GrO–silica nanocomposites prepared by a solution of commercial Fumed silica nanoparticles (average diameter 7 nm or 40 nm) and the GrO. The thermal treatments were carried out in air, vacuum or He atmosphere to highlight tunable changes. Two GrO batches with small differences in the D (~1350 cm–1) and G (~1580 cm–1) Raman bands have been employed to evaluate effects depending on preparation. Thermal effects have been monitored through the Raman spectroscopy focusing on D, G and 2D (2500–3500 cm–1) bands spectral ranges. The experiments evidenced…

Polyamide 6/Graphene Oxide Nanohybrids

2013

GREEN COMPOSITES BASED ON BIODEGRADABLE POLYMERS AND WOOD FLOUR

2010

Green Composites Based on Mater-Bi® and Solanum lycopersicum Plant Waste for 3D Printing Applications

2023

3D printability of green composites is currently experiencing a boost in importance and interest, envisaging a way to valorise agricultural waste, in order to obtain affordable fillers for the preparation of biodegradable polymer-based composites with reduced cost and environmental impact, without undermining processability and mechanical performance. In this work, an innovative green composite was prepared by combining a starch-based biodegradable polymer (Mater-Bi®, MB) and a filler obtained from the lignocellulosic waste coming from Solanum lycopersicum (i.e., tomato plant) harvesting. Different processing parameters and different filler amounts were investigated, and the obtained sample…

Guided Wave Techniques for Damage Detection in Composite Aerospace Structures

2018

Composite materials make up an increasing portion of today’s aerospace structures (see, e.g. Boeing 787 and Airbus 380). These aircrafts’ fuselage, for example, is composed of a laminated composite skin connected to composite stringers and C-frames. Of primary importance is the detection of damage in these built-up structures, whether caused by the manufacturing process or in service (e.g. impacts). A related issue is the characterization of the composite (visco)elastic mechanical properties, that can also be related to the quantification of potential damage. Guided elastic waves propagating in the ~100s kHz regime lend themselves to provide the necessary sensitivity to these two conditions…

Very strong −N–X+⋯−O–N+ halogen bonds

2016

A new (-)N-X(+)(-)O-N(+) paradigm for halogen bonding is established by using an oxygen atom as an unusual halogen bond acceptor. The strategy yielded extremely strong halogen bonded complexes with very high association constants characterized in either CDCl3 or acetone-d6 solution by (1)H NMR titrations and in the solid-state by single crystal X-ray analysis. The obtained halogen bond interactions, RXB, in the solid-state are found to be in the order of strong hydrogen bonds, viz. RXB ≈ RHB.

Heat capacity and thermal conductivity of multiferroics Bi1-xPrxFeO3

2019

The heat capacity and thermal conductivity of multiferroics Bi1–xPrxFeO3 (0 ≤ x ≤ 0.50) has been studied in the temperature range of 130–800 K. A slight substitution of praseodymium for bismuth is found to lead to a noticeable shift of the antiferromagnetic phase transition temperature whilst the heat capacity increases. The temperature dependences of the heat capacity and thermal conductivity exhibit additional anomalies during phase transitions. The experimental results suggest that the excess heat capacity can be attributed to the Schottky effect for three-level states. The basic mechanisms of the heat transfer of phonons are highlighted and the dependence of the mean free path on temper…

Open-air Conservation of Ruins and the Concept of “Non-Dislocation”

2012

Most of the on-going debate is about “how” to protect archaeological ruins, whilst at the same time allowing the general public to enjoy them. Today it is clear how important it is, from the actual planning stages of excavations, to interact with experts from other disciplines, who are working on their own findings and offering them up for collective enjoyment. Whatever might be feasible for an indoor museum is not always feasible with an architectonic ruin, as regards both presenting objects with explicative apparatus that determines their significance, and exploring them in a new way when interpretations change or new ideologies are introduced. First of all, conserving excavations is the …

Ecofriendly Biopolymer-Based Nanocomposite Films with Improved Photo-Oxidative Resistance

2022

The interest towards high performance biopolymer-based materials increases continuously and, to guarantee appropriately industrial applications, the photo-oxidative resistance and stability of these materials must be adequately addressed. In this study, innovative biopolymer-based nanocomposites, i.e., Polyamide 11 (PA11), containing ad-hoc modified Layered Double Hydroxides (LDH), were successfully formulated and characterized. Particularly, LDH were considered carriers for hindered amine light stabilizing molecules, so two different hindered amine moieties (HALS1 and HALS2) were anchored on LDH layered internal structures and/or outer surfaces. The presence of HALS1 and HALS2 in LDH were …

Experimental approaches to study the transmission and infection of Cardiocephaloides longicollis (Rudolphi, 1819) Dubois, 1982 (Trematoda, Strigeidae…

2023

Los trematodos (Platyhelminthes, Trematoda) son componentes ubicuos de los ecosistemas y, en las últimas décadas, los investigadores han mostrado un interés creciente en ellos, especialmente en sus estrategias y mecanismos de transmisión e infección. Los digeneos forman un grupo grande y generalmente tienen un ciclo de vida complejo con tres huéspedes. El primer huésped intermedio suele ser un molusco, el segundo huésped intermedio puede ser un huésped invertebrado o vertebrado, y el huésped definitivo suele ser un vertebrado. En el huésped definitivo, el parásito se convierte en adulto y se reproduce sexualmente. Luego, los huevos del parásito se liberan en el medio ambiente donde el mirac…