Search results for "SO2"

Understanding the SO 2 degassing budget of Mt Etna’s paroxysms: First clues from the december 2015 sequence

2019

The persistent open-vent activity of basaltic volcanoes is periodically interrupted by spectacular but hazardous paroxysmal explosions. The rapid transition from quiescence to explosive eruption poses a significant challenge for volcanic hazard assessment and mitigation, and improving our understanding of the processes that trigger these paroxysmal events is critical. Although magmatic gas is unquestionably the driver, direct measurements of a paroxysm’s gas flux budget have remained challenging, to date. A particularly violent paroxysmal sequence took place on Etna on December 2015, intermittently involving all summit craters, especially the Voragine (VOR) that had previously displayed no…

In-situ observations of young contrails – overview and selected results from the CONCERT campaign

2010

Lineshaped contrails were detected with the research aircraft Falcon during the CONCERT – CONtrail and Cirrus ExpeRimenT – campaign in October/November 2008. The Falcon was equipped with a set of instruments to measure the particle size distribution, shape, extinction and chemical composition as well as trace gas mixing ratios of sulfur dioxide (SO<sub>2</sub>), reactive nitrogen and halogen species (NO, NO<sub>y</sub>, HNO<sub>3</sub>, HONO, HCl), ozone (O<sub>3</sub>) and carbon monoxide (CO). During 12 mission flights over Europe, numerous contrails, cirrus clouds and a volcanic aerosol layer were probed at altitudes between 8.5 and 11.6 km…

Total CO2 output from Vulcano island (Aeolian Islands, Italy)

2012

Total CO2 output from fumaroles, soil gas, bubbling gas discharges and water dissolved gases discharged from the island, was estimated for Vulcano island, Italy. The CO2 emission from fumaroles from the La Fossa summit crater was estimated from the SO2 crater output, while CO2 discharged through diffuse soil emission was quantified on the basis of 730 measurements of CO2 fluxes from the soil of the island, performed by using the accumulation chamber method. The results indicate an overall output of ≅500 t day 1 of CO2 from the island. The main contribution to the total CO2 output comes from the summit area of the La Fossa cone (453 t day 1), with 362 t day 1 from crater fumaroles and 91 t d…

Shrinkage Bubbles: The C–O–H–S Magmatic Fluid System at San Cristóbal Volcano

2018

New analytical results for the composition of shrinkage bubbles (09-70 vol. %) in olivine-hosted (Fo <80%) primary melt inclusions (MIs) have been incorporated into a novel geochemical model for San Cristó bal volcano, Nicaragua. The vapour, liquid, and mineral components found inside shrinkage bubbles may represent relics of early C-O-H-S fluids exsolved from a magmatichydrothermal system. This conclusion is supported by high-resolution Raman microspectroscopy revealing: (1) gaseous CO2 (d=0·17-0·31 g/cm3 in 31 samples) coexisting with liquid H2O (in seven samples) at ambient temperature (<22°C) inside the shrinkage bubbles of naturally quenched inclusions; (2) several mineral phases (i.e.…

From atomic to molecular Bose-Einstein condensates: a physically realizable term-crossing model for cold atom association

2010

Using an exact third-order NL di®erential equation for the molecular state probability, we develop a variational approach which enables us to construct highly accurate analytic approximations describing time dynamics of the coupled atom-molecular system in each of the interaction regimes. We show that the approximation describing time evolution of the molecular state probability both in the weak interaction limit and in the large detuning regime of the strong interaction limit can be written as a sum of two distinct terms; the ¯rst one, being a solution to a limit ¯rst-order NL equation, e®ectively describes the process of the molecule formation while the second one, being a scaled solution…

Ground-Based measurements of the 2014-2015 holuhraun volcanic cloud (Iceland)

2018

he 2014–2015 Bárðarbunga fissure eruption at Holuhraun in central Iceland was distinguished by the high emission of gases, in total 9.6 Mt SO2, with almost no tephra. This work collates all ground-based measurements of this extraordinary eruption cloud made under particularly challenging conditions: remote location, optically dense cloud with high SO2 column amounts, low UV intensity, frequent clouds and precipitation, an extensive and hot lava field, developing ramparts, and high-latitude winter conditions. Semi-continuous measurements of SO2 flux with three scanning DOAS instruments were augmented by car traverses along the ring-road and along the lava. The ratios of other gases/SO2 were …

Forecasting Etnean eruptions by real-time observations of volcanic gas composition.

2007

It is generally accepted but not experimentally proven that a quantitative prediction of volcanic eruptions is possible from the evaluation of volcanic gas data. By discussing the results of two years of real-time observation of H2O, CO2 and SO2 in volcanic gases from Mt. Etna volcano, we unambiguously demonstrate that increasing CO2/SO2 ratios can allow detecting the pre-eruptive degassing of uprising magmas. Quantitative modeling by the use of a saturation model allows us to relate the pre-eruptive increases of the CO2/SO2 ratio to the refilling of Etna’s shallow conduits with CO2-rich deep-reservoir magmas, leading to pressurization and eruption triggering. The advent of real-time observ…

Protocols for UV camera volcanic SO2 measurements

2010

Abstract Ultraviolet camera technology offers considerable promise for enabling 1 Hz timescale acquisitions of volcanic degassing phenomena, providing two orders of magnitude improvements on sampling frequencies from conventionally applied scanning spectrometer systems. This could, for instance enable unprecedented insights into rapid processes, such as strombolian explosions, and non-aliased corroboration with volcano geophysical data. The uptake of this technology has involved disparate methodological approaches, hitherto. As a means of expediting the further proliferation of such systems, we here study these diverse protocols, with the aim of suggesting those we consider optimal. In part…

Insights into magma and fluid transfer at Mount Etna by a multiparametric approach: A model of the events leading to the 2011 eruptive cycle

2013

33S hyperfine interactions in H2S and SO2 and revision of the sulfur nuclear magnetic shielding scale

2014

Using the Lamb-dip technique, the hyperfine structure in the rotational spectra of H2(33)S and (33)SO2 has been resolved and the corresponding parameters--that is, the sulfur quadrupole-coupling and spin-rotation tensors--were determined. The experimental parameters are in good agreement with results from high-level coupled-cluster calculations, provided that up to quadruple excitations are considered in the cluster operator, sufficiently large basis sets are used, and vibrational corrections are accounted for. The (33)S spin-rotation tensor for H2S has been used to establish a new sulfur nuclear magnetic shielding scale, combining the paramagnetic part of the shielding as obtained from the…