Search results for "SPECT"
showing 10 items of 28650 documents
Collapse of a two-dimensional brittle granular column: Implications for understanding dynamic rock fragmentation in a landslide
2015
We investigate numerically the failure, collapse and flow of a two-dimensional brittle granular column over a horizontal surface. In our discrete element simulations, we consider a vertical monolayer of spherical particles that are initially held together by tensile bonds, which can be irreversibly broken during the collapse. This leads to dynamic fragmentation within the material during the flow. Compared to what happens in the case of a non-cohesive granular column, the deposit is much rougher, and the internal stratigraphic structure of the column is not preserved during the collapse. As has been observed in natural rockslides, we find that the deposit consists of large blocks laying on …
ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …
2019
Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …
High-resolution spectroscopy and analysis of the nu3/2nu4 dyad of CF4
2011
International audience; CF4 is a strong greenhouse gas of both anthropogenic and natural origin [D.R. Worton et al., Environ. Sci. Technol. 41, 2184 (2007)]. However, high-resolution infrared spectroscopy of this molecule has received only a limited interest up to now. Until very recently, the public databases only contained cross-sections for this species, but no detailed line list. We reinvestigate here the strongly absorbing ν3 region around 7.8 μm. New Fourier transform infrared (FTIR) spectra up to a maximal resolution of 0.0025 cm−1 have been recorded: (i) room-temperature spectra in a static cell and (ii) a supersonic expansion jet spectrum at a 23 K estimated temperature. Following …
Applications of a new set of methane line parameters to the modeling of Titan's spectrum in the 1.58 μm window
2012
International audience; In this paper we apply a recently released set of methane line parameters (Wang et al., 2011) to the modeling of Titan spectra in the 1.58 mu m window at both low and high spectral resolution. We first compare the methane absorption based on this new set of methane data to that calculated from the methane absorption coefficients derived in situ from DISR/Huygens (Tomasko et al., 2008a; Karkoschka and Tomasko, 2010) and from the band models of Irwin et al. (2006) and Karkoschka and Tomasko (2010). The Irwin et al. (2006) band model clearly underestimates the absorption in the window at temperature-pressure conditions representative of Titan's troposphere, while the Ka…
Global modeling of the lower three polyads of PH_{3} Preliminary results
2009
International audience; In order to model the high-resolution infrared spectrum of the phosphine molecule in the 3 mu m region, a global approach involving the lower three polyads of the molecule (Dyad, Pentad and Octad) as been applied using an effective hamiltonian in the form of irreducible tensors. This model allowed to describe all the 15 vibrational states involved and to consider explicitly all relevant ro-vibrational interactions that cannot be accounted for by conventional perturbation approaches. 2245 levels (up to J=14) observed through transitions arising from 34 cold and hot bands including all available existing data as well as new experimental data have been fitted simultaneo…
Comparison and Evaluation of the TES and ANEM Algorithms for Land Surface Temperature and Emissivity Separation over the Area of Valencia, Spain
2017
Land Surface temperature (LST) is a key magnitude for numerous studies, especially for climatology and assessment of energy fluxes between surface and atmosphere. Retrieval of accurate LST requires a good characterization of surface emissivity. Both quantities are coupled in a single radiance measurement; for this reason, for N spectral bands available in a remote sensor, there will always be N + 1 unknowns. To solve the indeterminacy, temperature-emissivity separation methods have been proposed, among which the Temperature Emissivity Separation (TES) algorithm is one of the most widely used. The Adjusted Normalized Emissivity Method (ANEM) was proposed as a modification of the Normalized E…
Calculating pressure with elastic geobarometry: A comparison of different elastic solutions with application to a calc-silicate gneiss from the Rhodo…
2020
Abstract Raman elastic geobarometry has increasingly been used complementary to metamorphic phase equilibria to estimate the conditions of recrystallization in metamorphic rocks. The procedure of applying Raman elastic barometry to host-inclusion mineral systems requires several steps that involve various assumptions. One of the most essential assumptions is that the mineral host-inclusion system behaves in an elastic and reversible manner. We discuss the discrepant results obtained by different authors employing different analytical solutions for elasticity and explore the assumptions lying behind each method. Furthermore, we evaluate numerically linear and non-linear elastic solutions and…
Quantifying vegetation biophysical variables from the Sentinel-3/FLEX tandem mission: Evaluation of the synergy of OLCI and FLORIS data sources
2020
The ESA’s forthcoming FLuorescence EXplorer (FLEX) mission is dedicated to the global monitoring of the vegetation’s chlorophyll fluorescence by means of an imaging spectrometer, FLORIS. In order to properly interpret the fluorescence signal in relation to photosynthetic activity, essential vegetation variables need to be retrieved concomitantly. FLEX will fly in tandem with Sentinel-3 (S3), which conveys the Ocean and Land Colour Instrument (OLCI) that is designed to characterize the atmosphere and the terrestrial vegetation at a spatial resolution of 300 m. In this work we present the retrieval models of four essential biophysical variables: (1) Leaf Area Index (LAI), (2) leaf chlorophyll…
Hyperspectral dimensionality reduction for biophysical variable statistical retrieval
2017
Abstract Current and upcoming airborne and spaceborne imaging spectrometers lead to vast hyperspectral data streams. This scenario calls for automated and optimized spectral dimensionality reduction techniques to enable fast and efficient hyperspectral data processing, such as inferring vegetation properties. In preparation of next generation biophysical variable retrieval methods applicable to hyperspectral data, we present the evaluation of 11 dimensionality reduction (DR) methods in combination with advanced machine learning regression algorithms (MLRAs) for statistical variable retrieval. Two unique hyperspectral datasets were analyzed on the predictive power of DR + MLRA methods to ret…
Empirical and physical estimation of Canopy Water Content from CHRIS/PROBA data
2013
20 páginas, 4 tablas, 7 figuras.