Search results for "SPECTRA"
showing 10 items of 3542 documents
Slow Dielectric Relaxation of Supercooled Liqutos Investigated by Nonresonant Spectral Hole Burning
1996
ABSTRACTWhen supercooled propylene carbonate and glycerol are subjected to a large-amplitude, low-frequency electric field, a spectral hole develops in their dielectric relaxation that is significantly narrower than their bulk response. This observation of nonresonant spectral hole burning establishes that the non-Debye response is due to a distribution of relaxation times. Refilling of the spectral hole occurs abruptly, indicative of a single recovery rate that corresponds to the peak in the distribution. The general shape of the spectral hole is preserved during recovery, indicating negligible interaction between the degrees of freedom that responded to the field. All relevant features in…
Ultra-broad spectral photo-response in FePS3 air-stable devices
2021
Van der Waals materials with narrow energy gaps and efficient response over a broadband optical spectral range are key to widen the energy window of nanoscale optoelectronic devices. Here, we characterize FePS as an appealing narrow-gap p-type semiconductor with an efficient broadband photo-response, a high refractive index, and a remarkable resilience against air and light exposure. To enable fast prototyping, we provide a straightforward guideline to determine the thickness of few-layered FePS nanosheets extracted from the optical transmission characteristics of several flakes. The analysis of the electrical photo-response of FePS devices as a function of the excitation energy confirms a …
Hackmanite—The Natural Glow-in-the-Dark Material
2020
“Glow-in-the-dark” materials are known to practically everyone who has ever traveled by airplane or cruise ship, since they are commonly used for self-lit emergency exit signs. The green afterglow, persistent luminescence (PeL), is obtained from divalent europium doped to a synthetic strontium aluminate, but there are also some natural minerals capable of afterglow. One such mineral is hackmanite, the afterglow of which has never been thoroughly investigated, even if its synthetic versions can compete with some of the best commercially available synthetic PeL materials. Here we combine experimental and computational data to show that the white PeL of natural hackmanite is generated and cont…
Excited state absorption spectra of dissolved and aggregated distyrylbenzene: A TD-DFT state and vibronic analysis
2017
Made available in DSpace on 2018-12-11T17:33:14Z (GMT). No. of bitstreams: 0 Previous issue date: 2017-07-21 Federación Española de Enfermedades Raras Ministerio de Economía y Competitividad A time-dependent density functional theory study is performed to reveal the excited state absorption (ESA) features of distyrylbenzene (DSB), a prototype π-conjugated organic oligomer. Starting with a didactic insight to ESA based on simple molecular orbital and configuration considerations, the performance of various density functional theory functionals is tested to reveal the full vibronic ESA features of DSB at short and long probe delay times. UNESP-Universidade Estadual Paulista POSMAT-Graduate Pr…
Metallization of the Na 14 Cl 13 Cluster
1994
The structure and energetics of multiple-excess-electron alkali halide clusters Na14Cl14-n, (1 ≤ n ≤ 6) is studied by ab initio calculations using norm-conserving pseudopotentials and local-spin-density-functional theory. Analysis of various electronic properties (Kohn-Sham one-electron eigenvalue spectra, ionization potentials, participation ratios of Kohn-Sham orbitals), as well as multiple F-center formation energies, suggests that these clusters can be characterized as Nan(NaCl)14-n having a "phase-separated" metallic part NaI. The Na14Cl9 (or Na14Cl9+) cluster exhibits a face (surface) segregated metallic Na5 (Na5+) overlayer, the stability of which is demonstrated by a molecular-dynam…
Simultaneous recording of skin blood pulsations at different vascular depths by multiwavelength photoplethysmography.
2007
A new technique for parallel recording of reflection photoplethysmography (PPG) signals in a broad spectral band (violet to near-infrared) has been developed, and its potential for assessment of blood microcirculation at various depths from the skin surface is discussed. PPG signals have been simultaneously detected at cw laser wavelength sets comprising 405, 532, 645, 807, and 1064 nm. Various signal baseline responses to breath holding and different shapes of the PPG pulses originated from the same heartbeat but recorded at different wavelengths have been observed, indicating a depth variety of the skin blood pulsation dynamics.
Contact probe pressure effects in skin multi-spectral photoplethysmography
2007
A novel technique ensuring parallel recording of reflection photoplethysmography signals in broad spectral range has been tested for assessment of pressure-induced vascular changes at various depths from the skin surface. PPG signals have been simultaneously detected at three combinations of the cw laser wavelengths 405 nm, 532 nm, 645 nm, 807 nm and 1064 nm. The PPG baseline responses to the probe-skin contact pressure changes and shapes of the PPG pulses originated from the same heartbeat but recorded at different wavelengths have been detected and analyzed.
Multi-wavelength photoplethysmography for simultaneous recording of skin blood pulsations at different vascular depths
2007
Parallel recording of reflection photoplethysmography (PPG) signals in broad spectral band has been performed, and potential of this approach for assessment of blood microcirculation at various vascular depths is discussed. PPG signals have been simultaneously detected at cw laser wavelengths sets comprising 405 nm, 532 nm, 645 nm, 807 nm and 1064 nm. Different signal baseline responses to breath holding at different wavelengths have been observed, as well as different shapes of the PPG pulses originated from the same heartbeat.
Effect of Hydrothermal Treatment on Adsorption Properties of Silica Gel
2011
It has been proven by coupling near infared spectroscopy to second derivative processing of the spectra that the free and hydrogen bonded silanol groups attached to water molecules absorb at 5314 a...
On the blue phase structure of hydrogen-bonded liquid crystals via 19F NMR
2018
Abstract 19 F NMR spectra are simulated for blue phase I of FPHG( St 1.5 ∗ Ap 1.5 ) based on a model of a double-twisted substructure inside cylinders that form a body-centred cubic lattice. A kinetic matrix is included to describe jump processes over quarter pitch lengths. Though the lines in the NMR spectra are broad and featureless, changes in the widths and positions with temperature are well described by the blue phase model structure. The spectra in the chiral nematic N∗ phase are also simulated. Dynamics in the BP I are found to be slower than in the N∗ phase.