Search results for "SPECTRA"
showing 10 items of 3542 documents
Solvent effects of pyridine on the NMR spectra of carboxylic acids. I—study of the acrylic,trans-crotonic and 3-butenoic acids
1975
Proton magnetic resonance spectral parameters of acrylic, trans-crotonic and 3-butenoic acids, their methyl esters and the corresponding alcohols (COOH substituted by CH2OH) have been measured for 5% (w/v) solutions in carbon tetrachloride and in pyridine-d5 at 33·5 °C. The total solvent effect of pyridine on the shifts of the skeleton protons of the acid was found to consist of three different effects independently measured from the reference samples.
Measurement and Analysis of the Raman Intensities of 12CD4
1995
0022-2852; The stimulated Raman spectrum of 12CD4 was recorded at high resolution, in the spectral range 1963 to 2260 cm(-1). Intensities of the rovibrational transitions were estimated by fitting the line profiles. The recorded elementary spectrum was 1 cm(-1) wide; all recordings were then intensity calibrated. Afterward, the relative Raman intensities were analyzed by using a polarizability model developed previously [A. Boutahar and M. Loete, Can. J. Phys. 69, 26-35 (1991); J. P. Champion, M. Loete, and G. Pierre, in ''Spectroscopy of the Earth's Atmosphere and Interstellar Molecules'' (K. Narahari Rao and A. Weber, Eds.), pp. 388-397, Academic Press, Boston. 1992]. The investigated reg…
Role of Ge nanoclusters in the performance of photodetectors compatible with Si technology
2013
In this work, we investigate the spectral response of metal-oxide- semiconductor photodetectors based on Ge nanoclusters (NCs) embedded in a silicon dioxide (SiO2) matrix. The role of Ge NC size and density on the spectral response was evaluated by comparing the performance of PDs based on either densely packed arrays of 2 nm-diameter NCs or a more sparse array of 8 nm-diameter Ge NCs. Our Ge NC photodetectors exhibit a high spectral responsivity in the 500-1000 nm range with internal quantum efficiency of ~ 700% at - 10 V, and with NC array parameters such as NC density and size playing a crucial role in the photoconductive gain and response time. We find that the configuration with a more…
FTIR Studies of Silicon Carbide 1D-Nanostructures
2015
Stable 1D silicon carbide nanostructures (nanowires) have been obtained via combustion synthesis route. Infrared absorption and reflection spectra for as-obtained and purified SiC nanowires were compared with the spectra of commercially available SiC nanomaterials. Principal vibrational modes have been identified. Reflectivity spectrum has been reconstructed by modeling of the dielectric function
Single Out-of-Resonance Dielectric Nanoparticles as Molecular Sensors.
2021
Light scattering from single nanoparticles and nanostructures is a commonly used readout method for nanosensors. Increasing the spectral sensitivity of resonant nanosensors to changes in their local surrounding has been the focus of many studies. Switching from spectral to intensity monitoring allows one to investigate nonresonant or out-of-resonance dielectric nanoparticles. Here, we systematically compared such dielectric silica nanoparticles with plasmonic gold nanorods by deriving analytical expressions and by performing experiments. The experiments show a similar sensitivity for the detection of an adsorbate layer for both particle types, which is in good agreement with theory. The fla…
Combustion Formation of Novel Nanomaterials: Synthesis and Cathodoluminescence of Silicon Carbide Nanowires
2009
This paper presents the combustion synthesis and characterization of one-dimensional silicon carbide nanostructures (nanowires of 3C-SiC polytype with zincblend structure) by means of cathodoluminescence technique. Cathodoluminescence spectra of nano-SiC samples and, as a reference, of a commercially available SiC micropowder are compared. It is shown that the emission band at 1.97 eV which is slightly evidenced in the spectrum of the commercial SiC under 10 keV electron beam irradiation becomes the prevailing band in CL of the purified silicon carbide nanowires.
Discerning the Origins of the Amplitude Fluctuations in Dynamic Raman Nanospectroscopy
2012
International audience; We introduce a novel experimental and analytical method for discerning rare surface-enhanced Raman scattering (SERS) events observable at the nanoscale. We show that the kinetics of the Raman activity recorded on an isolated nanostructure is punctuated by intense and rare events of large amplitude and spectral variations. The fluctuations of thousands of SERS spectra were analyzed statistically in terms of power density functions, and the occurrence of the rare events was quantified by a wavenumber statistics. Our analysis enables one to extract valuable and unique spectroscopic signature of Raman variations usually hidden in time-average or space-average measurement…
ETUDE ET RÉALISATION D'UN DETECTEUR (FILTRE) MULTISPECTRAL PAR DISPERSION NON DESTRUCTIVE SPECTRALE A TRAVERS DES FILMES A NONSTRUCTURE
2020
The development of multispectral imaging, holography and lithography techniques exploits the properties of diffracting arrays in a wide variety of photonic components. They are incorporated in laser diodes as distributed Bragg reflectors, in various integrated optical functions for wavelength division multiplexing or optical interconnections, or inscribed within the fibers themselves, leading to a wide variety of sensors for detection of chemical elements, measurement of temperatures, pressures, accelerations of acquisition and or restitution of multispectral images, etc. [Lee et al. 2007] [Pagnoux et al. 2005].Among these devices, the resonant networks arouse a great interest because they …
Time-Dependent Density Functional Theory Calculations of N- and S-Doped TiO2 Nanotube for Water-Splitting Applications
2021
This research was funded by the Latvian Council of Science grant LZP-2018/2-0083. Institute of Solid State Physics, University of Latvia, as the Center of Excellence, has received funding from the European Union?s Horizon 2020 Framework Program H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under Grant Agreement No. 739508, project CAMART2.
Land surface temperature derived from airborne hyperspectral scanner thermal infrared data
2006
Abstract The AHS (airborne hyperspectral scanner) instrument has 80 spectral bands covering the visible and near infrared (VNIR), short wave infrared (SWIR), mid-infrared (MIR), and thermal infrared (TIR) spectral range. The instrument is operated by Instituto Nacional de Tecnica Aerospacial (INTA) and it has been involved in several field campaigns since 2004. The main goal of this paper is to analyze the feasibility of retrieving land surface temperature from the 10 AHS thermal infrared bands, from 71 to 80, located in the region between 8 and 13 μm. For this purpose, three different methods have been considered: (i) the single-channel method, which uses only one thermal band; (ii) the sp…