Search results for "SPECTRA"

showing 10 items of 3542 documents

Multiconfigurational perturbation theory (CASPT2) applied to the study of the low-lying singlet and triplet excited states of cyclopropene

1996

The electronic spectrum of cyclopropene has been studied using multiconfigurational second-order perturbation theory (CASPT2) with extended ANO-type basis sets. The calculation comprises two valence states and the 3s, 3p, 3d members of the Rydberg series converging to the π and σ ionization limits. A total of twenty singlet and twenty triplet excited states have been analyzed. The results confirm the valence nature of the lowest energy singlet-singlet band and yield a conclusive assignment: the first dipole-allowed transition in cyclcopropene is due to absorption to a (σ → π*) state. The (π → π*) (V) state is interleaved among a number of Rydberg states in the most intense band of the syste…

PhysicsValence (chemistry)Spectral bandsCyclopropeneAtomic and Molecular Physics and OpticsSpectral linechemistry.chemical_compoundsymbols.namesakechemistryExcited stateIonizationRydberg formulasymbolsSinglet stateAtomic physicsZeitschrift f�r Physik D Atoms, Molecules and Clusters
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Correlation and Spectral Properties of Vehicle-to-Vehicle Channels in the Presence of Moving Scatterers

2013

This paper derives a vehicle-to-vehicle (V2V) channel model assuming a typical propagation scenario in which the local scatterers move with random velocities in random directions. The complex channel gain of the proposed V2V channel model is provided. Subsequently, for different scatterer velocity distributions, the corresponding autocorrelation function (ACF), power spectral density (PSD), and the Doppler spread of the channel are derived, shown, and confirmed by the available measurement data. It is shown that the Gaussian mixture (GM) and the exponential distribution can accurately describe the velocity distribution of relatively fast and slow moving scatterers, respectively. Since the p…

PhysicsVehicular communication systemsExponential distributionComputer Networks and CommunicationsGaussianMathematical analysisAutocorrelationAerospace EngineeringSpectral densityVehicle-to-vehiclesymbols.namesakeDistribution (mathematics)Automotive EngineeringsymbolsElectronic engineeringElectrical and Electronic EngineeringCommunication channelIEEE Transactions on Vehicular Technology
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Precision Spectroscopy of Deeply Bound Pionic Atoms and Partial Restoration of Chiral Symmetry in Medium

2011

We study theoretically the formation spectra of deeply bound pionic atoms expected to be observed by experiments with high energy resolution at RIBF/RIKEN, and we discuss in detail the possibilities to extract new information on the pion properties at finite density from the observed spectra, which may provide information on partial restoration of chiral symmetry in medium. We find that the non-yrast pionic states such as 2s are expected to be seen in the (d,3He) spectra, which will be helpful to reduce uncertainties of the theoretical calculations in the neutron wave functions in nucleus. The observation of the 2s state with the ground 1s state is also helpful to reduce the experimental un…

PhysicsWave function renormalizationPhysics and Astronomy (miscellaneous)Nuclear TheoryNuclear TheoryFOS: Physical sciencesState (functional analysis)Spectral lineNuclear Theory (nucl-th)PionNeutronAtomic physicsWave functionConstant (mathematics)Nuclear ExperimentExcitation
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Uniqueness verification of blue fraction as a parameter of spectral irradiance quantification

2021

The spectral distribution of global irradiance is measured in the optimal tilt (45° south) plane of array for the calender year 2020 in Grimstad, Norway. In this work the spectral distribution is quantified in terms of the Blue Fraction (BF). The uniqueness of BF has been tested and reported using the same methodology used for uniqueness verification of average photon energy (APE). The results show that the coefficient of correlation between the APE and BF was 0.98, meaning a possible bijective relation between these two parameters whereby both indicate a similar spectrum. The percentage contribution of integrated irradiance (Rc) was calculated for 25 nm wavelength bins for the BF region 35…

PhysicsWavelengthSpectral power distributionCoefficient of variationDispersion (optics)Analytical chemistryIrradiancePhoton energySpectral lineStandard deviation2021 IEEE 48th Photovoltaic Specialists Conference (PVSC)
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Multiphoton One-step Ionization of Helium at 1064 nm

1989

Abstract The multiphoton ionization of helium by a strong radiation field having a wavelength of 1064 nm and a field intensity up to 5 × 1014 W cm −2 is considered within a non-perturbative treatment partially accounting for the electron-electron correlations in the initial bound state and approximately for the Coulomb interaction between the residual ion and the ejected electron in the final state. Only single-electron transitions are considered, the main emphasis being on the field polarization effects. The obtained results are compared with the few results available in the literature in the same regime as well as with very recent experimental findings. In particular, the calculated photo…

PhysicsWavelengthchemistryIonizationBound statechemistry.chemical_elementElectronAtomic physicsPolarization (waves)Atomic and Molecular Physics and OpticsSpectral lineHeliumIonJournal of Modern Optics
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The use of the integral-bias summing coincidence spectrometer in directional correlation measurements

1968

Abstract The performance of the integral-bias summing coincidence spectrometer (the sum-peak spetrometer) in measurements of directional correlations of gamma rays has been tested. As compared with the conventional method, the sum-peak spectrometer is easier to use and seems to yield results which agree with those obtained with the ordinary method. Because of the complex shapes of response functions of gamma rays above about 3 MeV, the new method is best suited to the study of cascading transitions below this energy, where the two methods appear to complement each other. The analysis of the sum-peak spectra in the present work is based on a simple graphical method which seems to yield satis…

PhysicsWork (thermodynamics)Spectrometer010308 nuclear & particles physicsGamma rayGeneral Medicine01 natural sciencesCoincidenceSpectral lineNuclear physicsYield (chemistry)0103 physical sciences010306 general physicsEnergy (signal processing)Complement (set theory)Nuclear Instruments and Methods
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Element-specific magnetic moments and spin-resolved density of states in CoFeMnZ(Z=Al, Ga; Si, Ge)

2011

Using circular dichroism in x-ray-absorption spectroscopy (XAS/XMCD), we determined element-specific magnetic moments and spin-resolved unoccupied densities of states (DOS) for Co, Fe, and Mn in the quaternary Heusler compounds CoFeMn$Z$ ($Z=\text{Al}$, Ga; Si, Ge). These compounds belong to a class of highly spin-polarized materials with cubic LiMgPdSn-type structure. Different structure models for the sublattice occupation leading to similar average magnetization values can be distinguished by comparison of element-specific moments with theory. We find that the compounds form similar structures, where Co, Fe, Mn, and $Z$ occupy the $X$, ${X}^{\ensuremath{'}}$, $Y$, and $Z$ sublattice of t…

PhysicsX-ray absorption spectroscopyMagnetizationCircular dichroismMagnetic momentCondensed matter physicsDensity of statesAtomic physicsCondensed Matter PhysicsSpin (physics)SpectroscopySpectral lineElectronic Optical and Magnetic MaterialsPhysical Review B
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The Sax Mission for X-Ray Astronomy

1990

The satellite for X-ray astronomy SAX, to be launched at the end of 1993, is devoted to systematic, integrated and comprehensive, studies of galactic and extra-galactic sources in the energy band 0.1–200 keV, and is under joint development by the Italian Space Agency (ASI) and the Netherlands Agency for Aerospace programs (NIVR), with the participation of SRU/SRON and SSD/ESTEC. The basic scientific objectives can be summarized as follows: — Broad band spectroscopy (E/△ E=12) from 0.1–10 keV with imaging resolution of 1 arcmin. — Continuum and line spectroscopy (E/△ E=5-20) in the energy range 3–200 keV. — Variability studies of bright source energy spectra on timescales from milliseconds t…

PhysicsX-ray astronomyEinstein TelescopeSkyAstrophysics::High Energy Astrophysical Phenomenamedia_common.quotation_subjectX-ray detectorBroad bandAstronomyAstrophysicsSpectroscopySpectral linemedia_common
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X-ray and gamma-ray astronomy with NTD germanium-based microcalorimeters

2002

We report on the performance of our NTD-Ge microcalorimeters. To date, the spectral resolution for x-ray and gamma-ray lines from radioactive sources and laboratory plasmas is 4.8 eV in the entire 1 - 6 keV band and 52 eV at 60 keV. Technical details responsible for this performance are presented as well as an innovative electro-thermal approach for enhancing count-rate capability.

PhysicsX-ray astronomyX-raychemistry.chemical_elementGermaniumPlasmaGamma-ray astronomyAstrophysicsmicrocalorimeterlaw.inventionX-rayAstrophysicGermanium radiation detectorsSettore FIS/05 - Astronomia E AstrofisicachemistrylawNTD Germaniumgamma-raySpectral resolutionLight-emitting diode
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A Preliminary Analysis of a New Chandra Observation (ObsID 6148) of Cir X-1

2008

We present the preliminary spectral analysis of a 25 ks long Chandra observation of the peculiar source Cir X–1 near the periastron passage. We estimate more precise coordinates of the source compatible with the optical and radio counterpart coordinates. We detect emission lines associated to Mg XII, Si XIII, Si XIV, S XV, S XVI Ar XVII, Ar XVIII, Ca XIX, Ca XX, Fe XXV, Fe XXVI showing a redshift of 470 km s−1. The more intense emission features at 6.6 keV show a double‐peaked shape that can be modelled with two or three Gaussian lines.

PhysicsX-ray binaries Accretion and accretion disks Neutron stars Distances redshifts radial velocities; spatial distribution of galaxies Black holesX-ray binaries Accretion and accretion disks Neutron stars Distances redshifts radial velocitieGaussianX-ray binaryAstronomyAstrophysicsRedshiftPreliminary analysisRed shiftNeutron starsymbols.namesakeSettore FIS/05 - Astronomia E AstrofisicasymbolsSpectral analysisEmission spectrumspatial distribution of galaxies Black holes
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