Search results for "SPECTRA"
showing 10 items of 3542 documents
How Many Secret Details Could a Systematic Multi-Analytical Study Reveal About the Mysterious Fresco Trionfo della Morte?
2019
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SINGLE-PEAK RESOLUTION CRITERIA FOR OPTIMIZATION OF MOBILE PHASE COMPOSITION IN LIQUID CHROMATOGRAPHY
2001
Three criteria that evaluate the single peak resolution (peak purity) in chromatography, the free height fraction, free area fraction, and valley ratio, are examined. The main advantages of these criteria against other criteria based on peak pair separation, are that the measurements are not affected by the identity of neighboring peaks and are normalized, which make them very intuitive. The methodology is illustrated through the isocratic separation of mixtures of several sulphonamides (sulphacetamide, sulphadiazine, sulphadimethoxine, sulphaguanidine, sulphamerazine, sulphamethazine, sulphamethoxazole, sulphamethizole, sulphamonomethoxine, sulphanilamide, sulphapyridine, sulphaquinoxaline…
Studies of the bromine spectrum and determination of transition probabilities for Br I and Br II lines
1999
In a wall-stabilized cascade arc at atmospheric pressure in mixtures of argon and bromine vapors thermal plasmas were generated. Arc currents between 25 and 60 A were used. Applying a spectrometer of medium dispersion, equipped with an optical multichannel analyzer (CCD detector), the spectra of neutral and singly ionized bromine in the range between 3300 and 10400 A were recorded. Line intensity measurements, corrected for self-absorption, at different operating conditions of the arc, were performed. A complete set of Br I transitions (5 lines) originating from a common upper level (branching fractions) was measured. In the case of the Br II spectrum intensities of 14 lines were determined…
Sensitivity of noble gas NMR parameters to the heterocyclic ring proximity. Density functional theory studies of Ne–furan and Ar–furan complexes
2014
Theoretical modeling of noble gas interaction with furan as a simple heterocyclic ring was performed. The structures of neon–furan and argon–furan complexes were calculated at the MP2, M06-2X, CAM-B3LYP, APFD, and VSXC levels of theory using 6-311++G** basis set. The predicted 21Ne and 39Ar NMR chemical shifts for the Ne–furan and Ar–furan complexes calculated with pcS-3 and aug-pcS-3 basis sets were sensitive to the presence of the aromatic furan ring. Our results indicate a higher sensitivity of the neon and argon NMR probes than the previously reported 3He NMR spectroscopic parameters in studies of small heterocyclic rings containing the oxygen atom.
Measurements of transition probabilities for two N I infrared transitions and their application for diagnostics of low temperature plasmas
2010
Abstract Spectra emitted from a wall-stabilized arc, running in a gas mixture of helium, argon, nitrogen, oxygen and traces of hydrogen have been studied. Intensities of selected spectral transitions of neutral nitrogen and oxygen have been measured. Applying the Boltzmann plot method and using a reliable set of O I transition probabilities of spectral lines, originating from levels considerably spread in excitation energies, the temperatures of arc plasmas have been determined. Line intensities of two N I infrared transitions, originating from doubly excited terms 3p′ 2 F o and 3p′ 2 G have been measured. In order to obtain the corresponding transition probabilities ( A ki ) for these line…
Diagnostics of Helium-Argon Arc Discharge Plasma Based on Spectral Line Shape Measurements
1999
Electron densities and ion (gas) temperatures on the axis of an arc discharge plasma, produced at atmospheric pressure in a gas mixture of 95% helium and 5% argon, are determined at two arc currents. The evaluation of both main plasma parameters is based on line shape measurements, the ion temperature on the Doppler broadening of selected ArII lines, while the electron density on the Stark broadening of the hydrogen Hp line which appear in the spectrum due to hydrogen traces in the applied gases. The significance of reliable plasma diagnostics for determination of atomic structure data is discussed.
High resolution Fourier transform infrared spectroscopy and analysis of the ν 6 band of jet-cooled Mo(CO) 6
2000
Abstract Rovibrational FTIR spectra of Mo(CO) 6 have been recorded in supersonic argon expansions at 0.004 cm −1 resolution. Rotational constants have been determined for the ν 6 fundamental band of Mo( 12 CO) 6 and for the parallel band of the symmetric top isotopomer Mo( 13 CO)( 12 CO) 5 . From these results, a precise estimate of the Coriolis parameter for the ν 6 band of the main isotopomer Mo( 12 CO) 6 is derived, necessary for the analysis of the ν 6 spectrum. The observation of an octahedral splitting clearly resolved for the highest J-lines in the R branch prompted the use of a specific treatment based on the tensorial formalism developed by J.P. Champion, M. Loete, G. Pierre (Spher…
Mössbauer relaxation spectra in arbitrarily ordered absorbers—Line shape analysis for an iron(II) spincrossover complex in the presence of texture
1989
The stochastic theory of Mossbauer line shapes is formulated in a fashion which allows the evaluation of the spectral shapes for absorbers of arbitrary thickness, texture, and an anisotropic Lamb—Mossbauer factor. The results are specialized to a two-state-relaxation model of fluctuating electric hyperfine interaction in the case of an absorber of axially symmetric texture. The formalism is applied to the line shape analysis of Mossbauer spectra of a textured sample of the spin-crossover complex [Fe(mtz)6] (PF6)2 (mtz=1-methyltetrazole). It is found that between 185 and 240 K the rate constants for the HS→LS conversion are temperature independent, whereas an Arrhenius behaviour is found for…
A refugee newborn with heart failure and initial hydrops: Diagnostic clues of spectral Doppler examinations
2022
A newnborn admitted to NICU showed a severe clinical profile
Wronskian Addition Formula and Darboux-Pöschl-Teller Potentials
2013
For the famous Darboux-Pöschl-Teller equation, we present new wronskian representation both for the potential and the related eigenfunctions. The simplest application of this new formula is the explicit description of dynamics of the DPT potentials and the action of the KdV hierarchy. The key point of the proof is some evaluation formulas for special wronskian determinant.