Search results for "SPECTRA"
showing 10 items of 3542 documents
SrP3N5O: a highly condensed layer phosphate structure solved from a nanocrystal by automated electron diffraction tomography.
2011
The oxonitridophosphate SrP(3)N(5)O has been synthesized by heating a multicomponent reactant mixture that consisted of phosphoryl triamide OP(NH(2))(3), thiophosphoryl triamide SP(NH(2))(3), SrS, and NH(4)Cl enclosed in evacuated and sealed silica-glass ampoules up to 750 °C. The compound was obtained as nanocrystalline powder with needle-shaped crystallites. The crystal structure was solved ab initio on the basis of electron diffraction data by means of automated electron diffraction tomography (ADT) and verified by Rietveld refinement with X-ray powder diffraction data. SrP(3)N(5)O crystallizes in the orthorhombic space group Pnma (no. 62) with unit-cell data of a=18.331(2), b=8.086(1), …
A study of Type B uncertainties associated with the photoelectric effect in low-energy Monte Carlo simulations
2021
The goal of this manuscript is to estimate Type B uncertainties in absorbed-dose calculations arising from the different implementations in current state-of-the-art Monte Carlo codes of low-energy photon cross-sections (<200 keV). Monte Carlo simulations are carried out using three codes widely used in the low-energy domain: PENELOPE-2018, EGSnrc, and MCNP. Mass energy-absorption coefficients for water, air, graphite, and their respective ratios; absorbed dose; and photon-fluence spectra are considered. Benchmark simulations using similar cross-sections have been performed. The differences observed between these quantities when different cross-sections are considered are taken to be a go…
Spectrophotometric determination of phthalocyanines Part II. Phthalocyanines stable in concentrated sulfuric acid
2001
Celem pracy było wykazanie możliwości zastosowania spektroskopii VIS do badań ilościowych różnych związków ftalocyjaniny, w szczególności niepodstawionych kompleksów z metalami, które są trwałe w środowisku stężonego kwasu siarkowego(Vl). Zaproponowano prostą metodę, analizy spektrofotometrycznej VIS, stanowiącą kontynuację wcześniej przedstawionej pracy [1], umożliwiając oznaczanie wielu kompleksów ftalocyjaniny z metalami bloku d, Mpc (gdzie M = Cu, Co, Ni, Zn oraz pc (C(32)H(16)N(8)2- = ligand ftalocyjaninowy). Analiza statystyczna wyników uzyskanych w badaniach kontrolnych wykazała, że opisana metoda może być użyteczna zarówno w zastosowaniach przemysłowych jak i badaniach naukowych.
New NEMESIS Results
2021
Funding Information: This work has been supported in part by the EU INTERREG for the Baltic Sea programme within the BSUIN project, and by the Polish Ministry of Science and Higher Education (Grant no. Funding Information: This work has been supported in part by the EU INTERREG for the Baltic Sea programme within the BSUIN project, and by the Polish Ministry of Science and Higher Education (Grant no. 3988/INTERREG BSR/2018/2). Publisher Copyright: © Copyright owned by the author(s) under the terms of the Creative Commons. Preliminary results from a 349-day run (live time) with a 565 kg Pb target and a 166-day background measurement are presented. Three minor anomalies were detected in muon-…
Solar UV radiation and plant responses : assessing the methodological problems in research concerning stratospheric ozone depletion
2010
VUV emission spectroscopy combined with H- density measurements in the ion source Prometheus I
2016
“Prometheus I” is a volume H− negative ion source, driven by a network of dipolar electron cyclotron resonance (ECR; 2.45 GHz) modules. The vacuum-ultraviolet (VUV) emission spectrum of low-temperature hydrogen plasmas may be related to molecular and atomic processes involved directly or indirectly in the production of negative ions. In this work, VUV spectroscopy has been performed in the above source, Prometheus I, both in the ECR zones and the bulk (far from ECR zones and surfaces) plasma. The acquired VUV spectra are correlated with the negative ion densities, as measured by means of laser photodetachment, and the possible mechanisms of negative ion production are considered. The well-e…
Analysis of FBG reflection spectra under uniform and non-uniform transverse loads
2019
Loads applied transversely on the external surface of waveguides change their circular cross-sectional geometry generating birefringence. Due to this effect the reflected spectrum of a Fibre Bragg grating (FBG) undergoes a splitting of the single peak of the Bragg wavelength. In this work, we employed the Transfer Matrix Method (TMM) for x- and y-polarized wave-modes to model the uniform FBG reflection spectra for uniform and non-uniform transverse loads. We also performed experimental measurements for two different transverse load scenarios. The load profiles chosen for these experiments were applied on the FBG sensor through a block of steel and a roll bearing pin. Then, the modelled and …
The Hamburg/ESO R-process Enhanced Star survey (HERES)
2004
We report on a dedicated effort to identify and study metal-poor stars strongly enhanced in r-process elements ([r/Fe] > 1 dex; hereafter r-II stars), the Hamburg/ESO R-process Enhanced Star survey (HERES). Moderate-resolution (~2A) follow-up spectroscopy has been obtained for metal-poor giant candidates selected from the Hamburg/ESO objective-prism survey (HES) as well as the HK survey to identify sharp-lined stars with [Fe/H] < -2.5dex. For several hundred confirmed metal-poor giants brighter than B~16.5mag (most of them from the HES), ``snapshot'' spectra (R~20,000; S/N~30 per pixel) are being obtained with VLT/UVES, with the main aim of finding the 2-3% r-II stars expected to be a…
Effect of Er3+-doping on 65GeS2-25Ga2S3-10CsCl glass probed by annihilating positrons
2019
Abstract Effect of Er3+-doping resulting in pronounced mid-IR fluorescence functionality was examined first in chalcohalide 65GeS2-25Ga2S3-10CsCl glass using positron annihilation lifetime (PAL) spectroscopy. The detected PAL spectra were reconstructed from unconstrained x2-term analysis employing two-state simple trapping model for one kind of positron trapping free-volume defects, the parameterization being performed at the example of 65GeS2-25Ga2S3-10CsCl glass doped with 0.6 at. % of Er3+. The observed decrease in positron trapping rate was proved to be primary void-evolution process in this Er-activated glass, like in many other chalcogenide glasses affected by rare earth doping. The n…
New high-pressure phase and equation of state of Ce2Zr2O8
2012
In this paper we report a new high-pressure rhombohedral phase of Ce2Zr2O8 observed from high-pressure angle-dispersive x-ray diffraction and Raman spectroscopy studies up to nearly 12 GPa. The ambient-pressure cubic phase of Ce2Zr2O8 transforms to a rhombohedral structure beyond 5 GPa with a feeble distortion in the lattice. Pressure evolution of unit-cell volume showed a change in compressibility above 5 GPa. The unit-cell parameters of the high-pressure rhombohedral phase at 12.1 GPa are ah = 14.6791(3) {\AA}, ch = 17.9421(5) {\AA}, V = 3348.1(1) {\AA}3. The structure relation between the parent cubic (P2_13) and rhombohedral (P3_2) phases were obtained by group-subgroup relations. All t…