Search results for "SPECTRA"
showing 10 items of 3542 documents
Kernspinlabel-Untersuchungen zur Struktur und Dynamik von flüssigkristallinen Hauptkettenpolymeren
1984
Thermotropic nematic polyesters, specifically deuterated at different positions of the polymer chain, were macroscopically aligned by strong magnetic fields and solid state extrusion. Analysis of the observed 2H NMR spectra was achieved, employing a dynamic NMR model, based on the stochastic Liouville equation. The model considers various double and multiple pulse sequences, recently employed in FT-NMR spectroscopy.
Effect of Pressure on Direct Optical Transitions of ?-InSe
2000
We have investigated the effect of hydrostatic pressure on direct optical transitions of the layered semiconductor γ-InSe by photoreflectance (PR) spectroscopy (T = 300 K). In addition, electroreflectance (ER) measurements were performed at ambient pressure. Six structures are resolved in the ER spectra in the energy range from 1.1 to 3.6 eV. The pressure dependence of four of these structures was determined by PR spectroscopy for pressures up to 8 GPa. In order to assign the features observed above the fundamental gap we have carried out band structure calculations for InSe at ambient pressure using a full-potential linear augmented plane wave method. Based on calculated band gap deformati…
X-ray-absorption fine-structure study of ZnSexTe1−x alloys
2004
X-ray-absorption fine-structure experiments at different temperatures in ZnSexTe1−x (x=0, 0.1, 0.2, 0.55, 0.81, 0.93, 0.99, and 1.0) have been performed in order to obtain information about the structural relaxation and disorder effects occurring in the alloys. First and second neighbor distance distributions have been characterized at the Se and Zn K edges, using multiple-edge and multiple-scattering data analysis. The first neighbor distance distribution was found to be bimodal. The static disorder associated with the Zn–Te distance variance did not depend appreciably on composition. On the other hand, the static disorder associated with the Zn–Se distance increased as the Se content dimi…
Nature of the non-exponential primary relaxation in structural glass-formers probed by dynamically selective experiments
1998
Several experimental methods feature the potential to distinguish between slow and fast contributions to the non-exponential, ensemble averaged primary response in glass-forming materials. Some of these techniques are based on the selection of subensembles using multi-dimensional nuclear magnetic resonance, optical bleaching, and non-resonant spectral hole burning. Others, such as the time-dependent solvation spectroscopy, measure microscopic responses induced by local perturbations. Using several of these methods it could be demonstrated for various glass-forming materials that the non-exponential relaxation results from a superposition of dynamically distinguishable entities. The experime…
Quantum Monte Carlo study of insulating state in NaV2O5
2003
Abstract Quantum Monte Carlo (QMC) methods are being increasingly used as complements to Hartree–Fock (HF) methods for computing the electronic structure of molecules and materials. We investigate the nature of the insulating state driven by electronic correlations in the ladder compound NaV 2 O 5 ; considered as a quarter-filled system. We use an extended Hubbard model (EHM) to study the role of on-site and inter-site Coulomb interaction. It is found that the insulating state in the charge-disordered phase of this compound take origin from the transfer of spectral density and dynamical fluctuations. Our calculation allows us also, to understand the origin of the insulating states above T C…
Two-phonon magneto-Raman scattering in quantum wells: Fröhlich interaction
1996
We have developed a theoretical model of two-phonon resonant magneto-Raman scattering in a semiconductor quantum well (QW). Frohlich electron-phonon interaction has been considered and the corresponding selection rules are derived for Faraday geometry and backscattering configuration. The resonant profiles are analyzed as a function of magnetic field and laser energy. To simplify the discussion a three-band model with parabolic masses has been used as a first approach, studying later the role of heavy-hole light-hole admixture in the scattering process. It is shown that, due to mixing effects, Frohlich interaction contributes to the two-phonon Raman spectra in the parallel (z(σ ± , σ ± ) z)…
Support Vector Machines for Crop Classification Using Hyperspectral Data
2003
In this communication, we propose the use of Support Vector Machines (SVM) for crop classification using hyperspectral images. SVM are benchmarked to well–known neural networks such as multilayer perceptrons (MLP), Radial Basis Functions (RBF) and Co-Active Neural Fuzzy Inference Systems (CANFIS). Models are analyzed in terms of efficiency and robustness, which is tested according to their suitability to real–time working conditions whenever a preprocessing stage is not possible. This can be simulated by considering models with and without a preprocessing stage. Four scenarios (128, 6, 3 and 2 bands) are thus evaluated. Several conclusions are drawn: (1) SVM yield better outcomes than neura…
Cloud-screening algorithm for ENVISAT/MERIS multispectral images
2007
This paper presents a methodology for cloud screening of multispectral images acquired with the Medium Resolution Imaging Spectrometer (MERIS) instrument on-board the Environmental Satellite (ENVISAT). The method yields both a discrete cloud mask and a cloud-abundance product from MERIS level-lb data on a per-pixel basis. The cloud-screening method relies on the extraction of meaningful physical features (e.g., brightness and whiteness), which are combined with atmospheric-absorption features at specific MERIS-band locations (oxygen and watervapor absorptions) to increase the cloud-detection accuracy. All these features are inputs to an unsupervised classification algorithm; the cloud-proba…
Large scale semi-supervised image segmentation with active queries
2011
A semiautomatic procedure to generate classification maps of remote sensing images is proposed. Starting from a hierarchical unsupervised classification, the algorithm exploits the few available labeled pixels to assign each cluster to the most probable class. For a given amount of labeled pixels, the algorithm returns a classified segmentation map, along with confidence levels of class membership for each pixel. Active learning methods are used to select the most informative samples to increase confidence in the class membership. Experiments on a AVIRIS hyperspectral image confirm the effectiveness of the method, especially when used with active learning query functions and spatial regular…
A Support Vector Domain Description Approach to Supervised Classification of Remote Sensing Images
2007
This paper addresses the problem of supervised classification of remote sensing images in the presence of incomplete (nonexhaustive) training sets. The problem is analyzed according to two different perspectives: 1) description and recognition of a specific land-cover class by using single-class classifiers and 2) solution of multiclass problems with single-class classification techniques. In this framework, we analyze different one-class classifiers and introduce in the remote sensing community the support vector domain description method (SVDD). The SVDD is a kernel-based method that exhibits intrinsic regularization ability and robustness versus low numbers of high-dimensional samples. T…