Search results for "SSB"

Integration of Dye-Sensitized Solar Cells with Glassblock

2012

The paper will show the first results of a research (included in a larger work about the Improvement of glassblocks performance in order to use them for the construction of sustainable translucent building envelops even in Mediterranean and Tropical Areas) aimed to the integration of glassblock with the DSC technology. Glassblock is a high-performance type of glass in the field of sustainable architectural claddings: the process of deposition of the cells on the single glassblock, their best position and the performance of this new kind of glassblock, DSC integrated, will be discussed in the paper in terms of transmittance, light transmission and aesthetical effects, together with the probl…

“Hypotheses of Integration of DSC into the Glassblock for teh Construction of Translucent Building Envelope”

2012

New configurations of the glassblock have been designed at the Department of Architecture of the University of Palermo in order to reduce its U value responding to the latest national and international regulation limits for the thermal insulation of the buildings with glass façades. One of these new configurations consists in the insertion of a special plastic "belt" between the two glass shells composing the glassblock, which have to be glued to it (cold assembly); the plastic belt effectively interrupts the thermal bridge between the two glass shells. Thanks to the particular design of its shape, the "thermal belt" can be also used for the insertion of one or more additional sheets of dif…

El declive de la ética de las capacidades

2013

Capability approach is one of the most important contributions of contemporary political philosophy to the subject of international distributive justice and more generally to the implementation of development policies. In this paper I aim to shed light on some pitfalls of the last production of Amartya Sen and Martha Nussbaum. Sen’s last book “The idea of justice” introduced his theory as a “comparative” approach to issues of justice, while rejecting “transcendental” approaches such as Rawls’one. I will show how this dichotomy between comparative and transcendental approach is mistaken, since it rests on wrong assumptions on what we can require from a theory of justice. As far as Nussbaum i…

Echi pirandelliani nel film Despair di Rainer Werner Fassbinder

2014

Configurable Passband Imaging Spectrometer Based on Acousto-optic Tunable Filter

2008

This work presents a new configurable imaging spectrometer called Autonomous Tunable Filtering System (ATFS). The system can be configured to acquire a single narrow spectral band, a composite multispectral image, or a broad pass-band. This flexibility is given by the use of an Acousto-Optic Tunable Filter (AOTF) driven by a programmable radio frequency (rf) signal generator. The AOTF acts as a light-diffraction element which output wavelength is selected by the frequency of an rf signal applied to it. The designed rf driver is based on a high-speed Digital-to-Analog converter, which can synthesize any composite rf waveform formed by a combination of sine signals. The images are formed thro…

Field-portable Mössbauer spectroscopy on Earth, the Moon, Mars, and beyond

2011

ABSTRACT Iron occurs naturally as Fe 2+ , Fe 3+ , and, to a lesser extent, as Fe 0 . Many fundamental (bio)geochemical processes are based on redox cycling between these oxidation states. Mossbauer spectroscopy provides quantitative information about the distribution of Fe among its oxidation states, identification of Fe-bearing phases, and relative distribution of Fe among those phases. Portable, miniaturised Mossbauer spectrometers were developed for NASA9s Mars Exploration Rovers (in operation since 2004) and provide a means for non-destructive, in-situ field investigations. On Mars, these instruments provided evidence for aqueous activity with implications for habitability, were applied…

Thermal and pressure-induced spin crossover in a novel three-dimensional Hoffman-like clathrate complex

2011

The synthesis and crystal structure of the interpenetrated metal–organic framework material Fe(bpac)2[Ag(CN)2]2 (bpac = 4,4′-bis(pyridyl)acetylene) are reported along with the characterization of its spin crossover properties by variable temperature magnetometry and Mossbauer spectroscopy. The complex presents an incomplete stepped spin transition as a function of temperature that is modified upon successive thermal cycling. The pressure-induced transition has also been investigated by means of high pressure Raman spectroscopy using a diamond anvil cell. The results show that it is possible to reach the thermally-inaccessible fully low spin state at room temperature by applying hydrostatic …

A spin transition molecular material with a wide bistability domain.

2002

International audience; [Fe(hyptrz)3](4-chloro-3-nitrophenylsulfonate)22 H2O (1; hyptrz=4-(3-hydroxypropyl)-1,2,4-triazole) has been synthesized and its physical properties have been investigated by several physical techniques including magnetic susceptibility measurements, calorimetry, and Mössbauer, optical, and EXAFS spectroscopy. Compound 1 exhibits a spin transition below room temperature, together with a very wide thermal hysteresis of about 50 K. This represents the widest hysteresis loop ever observed for an FeII-1,2,4-triazole spin transition material. The cooperativity is discussed on the basis of temperature-dependent EXAFS studies and of the structural features of a CuII analogu…

The photocycle and the structure of iron containing bacteriorhodopsin ?a kinetic and M�ssbauer spectroscopy investigation

1990

Bacteriorhodopsin (bR), converted by deionization to the blue form was reconstituted to the active purple membrane by the addition of Fe2+ or Fe3+ ions. 57Fe Mossbauer spectra of these samples were measured at different pH values (pH 3.9, pH 5.0 and pH 7.0) and at temperatures ranging from 4 K to 300 K. The hyperfine parameters reveal two iron environments with oxygen atoms in the neighbourhood of iron. Iron type 1 is in the 3+ high spin state. It is bound to acid side chains of the protein and/or the phosphate groups of the lipids. Iron type 2 is in the 2+ high spin state and is linked to carboxy groups of the protein in a rather unspecific way. Dynamics as measured by Mossbauer spectrosco…

Supersaturation and activity-rotation relation in PMS stars: the young Cluster h Per

2016

The magnetic activity of late-type MS stars is characterized by different regimes, and their activity levels are well described by Ro, the ratio between P_rot and the convective turnover time. Very young PMS stars show, similarly to MS stars, intense magnetic activity. However they do not show clear activity-rotation trends, and it still debated which stellar parameters determine their magnetic activity levels. To bridge the gap between MS and PMS stars, we studied the activity-rotation relation in the young cluster h Per, a ~13 Myr old cluster, that contains both fast and slow rotators, whose members have ended their accretion phase and have already developed a radiative core. It offers us…