Search results for "SSB"
showing 10 items of 537 documents
Potential Vorticity Dynamics of Forecast Errors: A Quantitative Case Study
2018
Abstract Synoptic-scale error growth near the tropopause is investigated from a process-based perspective. Following previous work, a potential vorticity (PV) error tendency equation is derived and partitioned into individual contributions to yield insight into the processes governing error growth near the tropopause. Importantly, we focus here on the further amplification of preexisting errors and not on the origin of errors. The individual contributions to error growth are quantified in a case study of a 6-day forecast. In this case, localized mesoscale error maxima have formed by forecast day 2. These maxima organize into a wavelike pattern and reach the Rossby wave scale around forecast…
The Extratropical Transition of Tropical Cyclones. Part II: Interaction with the Midlatitude Flow, Downstream Impacts, and Implications for Predictab…
2019
Abstract The extratropical transition (ET) of tropical cyclones often has an important impact on the nature and predictability of the midlatitude flow. This review synthesizes the current understanding of the dynamical and physical processes that govern this impact and highlights the relationship of downstream development during ET to high-impact weather, with a focus on downstream regions. It updates a previous review from 2003 and identifies new and emerging challenges and future research needs. First, the mechanisms through which the transitioning cyclone impacts the midlatitude flow in its immediate vicinity are discussed. This “direct impact” manifests in the formation of a jet streak …
Steered Response Power Localization of Acoustic Passband Signals
2017
The vast majority of localization approaches using phase transform (PHAT) consider that the sources of interest are wideband low-pass sources. While this may be the usual case for common audio signals such as speech, PHAT methods are affected negatively by modulation artifacts when the sources to be localized are passband signals. In these cases, steered response power PHAT localization becomes less robust. This letter analyzes the form of generalized cross-correlation functions with PHAT when passband acoustic signals are considered, proposing approaches for increasing the localization performance through the mitigation of these negative effects.
Surface spectroscopic study of the corrosion of ultrathin57Fe-evaporated and Langmuir-Blodgett films in humid SO2 environments
2000
Integral conversion electron Mossbauer spectroscopy (ICEMS), x-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and scanning electron microscopy (SEM) have been used to carry out a comparative study of the corrosion resistance against humid SO2-aggressive environments of ultrathin 57Fe films. These films, having a thickness ≤ 2.5 nm, have been prepared by evaporation of 57Fe under vacuum and by 57Fe coating by a Langmuir–Blodgett (LB) technique on SiO2/Si wafers. The results have shown that the corrosion resistance of the evaporated films is similar to that of massive Fe. However, the LB films show a remarkably higher corrosion resistance. Thus, although the Fe films …
Functionalization using biocompatible carboxylated cyclodextrins of iron-based nanoMIL-100
2021
9 pags., 7 figs., 1 tab.
A CEMS/AES study of the passivation of iron
1989
The passivation of iron and steel (DIN 1623) was studied by integral and depth selective conversion electron Mossbauer spectroscopy and Auger electron spectroscopy. Thickness and phase composition of the passive layer formed in sulphate solution and in a phosphate buffer were determined in dependence on the anodic potential and the duration of the passivating procedure. The experimental results lead to the conclusion that not the whole oxidic layer is responsible for the passivity but only a very thin intermediate layer formed between the cubic substrate and the rhombic oxide (γ-FeOOH) cover.
A corrosion study of austenitic and martensitic steels under boiler conditions by means of 57Fe conversion electron mössbauer spectroscopy
1978
Abstract The growth of protective oxide layers on a martensitic FeCr (1.4122) and two austenitic FeCrNi steel samples (1.4550 and Incoloy 800) was studied by means of the 57Fe Conversion Electron Mossbauer Spectroscopy (CEMS). Scanning electron microscopy was applied to characterize the topographical nature of the oxide layers. Following a technical procedure of running-in steam generators, the steel specimens were oxidized in oxygen-free water at 295°C, 142 bar and a pH value between 9 and 10 for periods up to 70 h. In the case of the steels 1.4122 and 1.4550 the only oxide phase detected was non-stoichiometric magnetite, whereas nickel ferrite of nonstoichiometric composition was found…
Synthesis and structural studies by infrared and Mössbauer spectroscopy of adducts of tin(IV) and organotin(IV) derivatives with 2,2′-azopyridine
1985
Abstract A number of complexes have been prepared by the reaction between 2,2′-azopyridine(AZP) and tin(IV) halides and organotin(IV) halides, and characterized by elemental analysis and infrared and variable temperature 119Sn Mossbauer spectroscopies. All of the new compounds have 1:1 stoichiometry, with the AZP ligand occupying two coordination sites by bonding through one of the ring and one of the azo group nitrogen atoms, to give rise to distorted octahedral structures. In the diorganotin complexes the two organic groups occupy trans positions. The infrared and Mossbauer spectroscopic data suggest that these compounds are monomeric in the solid state.
Fe Mossbauer spectroscopy as a tool in astrobiology
2006
The element Fe and Fe-bearing minerals occur ubiquitously throughout the field of astrobiology. Cycling between the various oxidation states of Fe provides a source of energy available for life. Banded iron formations may record the rise of oxygenic photosynthesis. The distribution of Fe between Fe-bearing minerals and its oxidation states can help to characterize and understand ancient environments with respect to the suitability for life by constraining the primary rock type and the redox conditions under which it crystallized, the extent of alteration and weathering, the type of alteration and weathering products, and the processes and environmental conditions for alteration and weatheri…
Diorganotin(IV) N-acetyl-L-cysteinate complexes: synthesis, solid state, solution phase, DFT and biological investigations.
2009
Diorganotin(IV) complexes of N-acetyl-L-cysteine (H(2)NAC; (R)-2-acetamido-3-sulfanylpropanoic acid) have been synthesized and their solid and solution-phase structural configurations investigated by FTIR, Mössbauer, (1)H, (13)C and (119)Sn NMR spectroscopy. FTIR results suggested that in R(2)Sn(IV)NAC (R = Me, Bu, Ph) complexes NAC(2-) behaves as dianionic tridentate ligand coordinating the tin(IV) atom, through ester-type carboxylate, acetate carbonyl oxygen atom and the deprotonated thiolate group. From (119)Sn Mössbauer spectroscopy it could be inferred that the tin atom is pentacoordinated, with equatorial R(2)Sn(IV) trigonal bipyramidal configuration. In DMSO-d(6) solution, NMR spectr…