Search results for "SSB"
showing 10 items of 537 documents
Pressure induced increase in Tc for the organic-based magnet FeII(TCNE)2 (TCNE=tetracyanoethylene)
2013
Abstract Pressure dependent magnetization and 57Fe Mossbauer studies were performed on Fe(TCNE)[C4(CN)8]1/2·zCH2Cl2 (TCNE = tetracyanoethylene). Pressure did not influence the Mossbauer parameters in paramagnetic state. Mossbauer data reveals the onset of magnetic ordering at 130 K and significant enhancement of the magnetic ordering temperature from 100 to 150 K accompanied by an increase of the spontaneous magnetization, which is higher than reported from the magnetic data, and application of pressure induces the reversible formation of a new, metastable magnetic species. These changes suggest an increase of the dimensionality of magnetic interaction, i.e., stronger interlayer coupling. A…
Debye-Waller factor in the spin crossover complex Fe(ppi)2(NCS)2
1997
Abstract Mossbauer spectroscopy and magnetic susceptibility measurements for the complex Fe(ppi) 2 (NCS) 2 in the temperature range 11–300 K indicate that the spin transition of this compound is incomplete until 11 K. The similar Debye-Waller factors in high spin (HS) and low spin (LS) states is shown by the comparison of the HS fractions from the two different methods. The Debye temperature of the compound was calculated from the defined Debye-Waller factors obtained from Mossbauer measurement at each experimental temperature and was found to depend on the temperature as well as on the HS fraction. The modification of the Debye-Waller factors in the HS and LS states for the HS fraction fro…
Quantitative View on the Processes Governing the Upscale Error Growth up to the Planetary Scale Using a Stochastic Convection Scheme
2019
Abstract Two diagnostics based on potential vorticity and the envelope of Rossby waves are used to investigate upscale error growth from a dynamical perspective. The diagnostics are applied to several cases of global, real-case ensemble simulations, in which the only difference between the ensemble members lies in the random seed of the stochastic convection scheme. Based on a tendency equation for the enstrophy error, the relative importance of individual processes to enstrophy-error growth near the tropopause is quantified. After the enstrophy error is saturated on the synoptic scale, the envelope diagnostic is used to investigate error growth up to the planetary scale. The diagnostics re…
Tropical–extratropical interactions related to upper-level troughs at low latitudes
2007
Abstract Momentum and kinetic energy fluxes associated with low-latitude transient disturbances at upper-levels play an important role in the general circulation of the atmosphere. They are related to eastward and equatorward propagating, positively tilted wave trains from the extratropics. Theoretical, modelling and observational studies show that this particular kind of tropical–extratropical interaction is most common in regions of mean upper-level westerlies at low latitudes, i.e. over the central and eastern Pacific and Atlantic Oceans during boreal winter and spring. The penetration of an upper-level trough into the Tropics is often associated with enhanced convection and the formatio…
Complexes of organometallic compounds. L. The correlation between 119Sn mössbauer isomer shifts and calculated partial charges on tin in adducts of t…
1981
Abstract The relationship between Mossbauer isomer shifts, δ, and atomic charges on tin, QSn has been studied for homologous series RnSnhal4−n· L2 [ n = 0−3; L2 = donor atoms of 1, 2-bis(dipheylphosphino)ethane, N, N′-ethylenebes(salicylideneimine) and N, N′-ethylenbes(acetylacetoneimine)] and Snhal4· 2PR3. Semiempirical values of QSn have been calculated by two methods based on the concept of orbital electronegativity equalization upon bond formation. Linear correlations δ/QSn are obtained, which can be function of the coordination number of the metal atom, for terms of the series characterized by different orbital electronegativities of atoms directly bound to tin. Deviations occur for ad…
Early motherhood: voices from female adolescents in the Hohoe Municipality, Ghana—a qualitative study utilizing Schlossberg’s Transition Theory
2020
ABSTRACT Purpose: Using Schlossberg’s Transition Theory, this study explored the lived experiences of pregnant adolescents and adolescent mothers coping strategies during their transition to motherhood. Methods: Based on a phenomenological perspective, this qualitative study used in-depth interviews (IDIs) and focus group discussions (FGDs) to answer the research aim. The process of data gathering included 8 FGDs and 12 IDIs held with adolescent mothers and pregnant adolescents. Audio recordings were transcribed and imported into MAXQDA 2018 for analysis. Results: Applying the interpretative phenomenologial analysis (IPA), four key themes emerged. This included: news of pregnancy; adolescen…
COMMUNICATION. OBSERVATIONS ON THE 121-Sb MÖSSBAUER PARAMETERS OF ANTIMONY (III) COMPOUNDS FEATURING A PYRAMIDAL SbS3SKELETAL UNIT
1991
Abstract A linear correlation between the chemical isomer shift and the quadrupole coupling constant for a number of antimony tris-thiolates has been evidenced. This behaviour can be rationalized on considering a modulation of the s/p character of the lone pair of electrons from the influence of secondary bonds.
Mössbauer spectroscopic studies of clusters Mn2(CO)8[μ-Sn(hal)Mn(CO)5]2 (hal = Cl, Br) and related Mn and Re compounds
1977
Abstract In order to be acquainted with the nature of bonds at Sn involved in the title compounds, as well as to get information on the configuration of the strictly related derivatives I2Sn2Mn4(CO)18 and Cl2Sn2Re4(CO)18, the Mossbauer spectroscopic investigation reported in this paper has been carried out. The experimental parameters (isomer shifts, δ; nuclear quadrupole splittings, ΔE; for the bromide derivative only, the asymmetry parameter η and the sign of the nuclear quadrupole coupling constant e2qQ) have been discussed in connection with data concerning compounds with tin-transition metal bonds, mainly hal2Sn[Mn(CO)5]2 (hal = Cl, Br) and ClSn[Mn(CO)5]3. Rationalizations of ΔE and η …
Antimony-121 Mössbauer spectra of organoantimony derivatives containing Sb-Sb bonds
1994
121-Sb Mossbauer data are reported for a number of organoantimony rings and catena-stibanes. These compounds are representative of RSb(Sb)2 and R2SbSb type of coordination, and spectral parameters are compared and discussed in relation to RSbCl2 and R2SbCl systems. Although the trend in isomer shift is similar, the present compounds show slightly less negative isomer shift values together with a remarkable reduction of the quadrupolar coupling constant. A rationalization of the quadrupolar interaction in the above series of compounds appears feasible by using point charge model calculations whose results, in terms of bonding, indicate a large contribution of p-electron density along Sb-Sb b…
On-line Mössbauer measurements at low temperatures of 83mKr implanted into Al
1978
Abstract A vacuum ion implantation chamber housing a helium flow cryostat and a Mossbauer transducer has been constructed and coupled directly to an ion separator for low temperature implantation and on-line Mossbauer measurements. 83m Kr, produced by thermal neutron activation of enriched 82 Kr gas, has been implanted into Al foils in the temperature range 15–300 K. Annealing effects and the temperature dependence of the Lamb-Mossbauer factor have been studied by Mossbauer measurements (at 15–35 K) using the implanted Al targets as sources and Kr/hydrochinone as absorber.