Search results for "STIFFNESS"
showing 10 items of 524 documents
Influence of polymer flexibility on nanoparticle dynamics in semidilute solutions
2018
The hierarchical structure and dynamics of polymer solutions control the transport of nanoparticles (NPs) through them. Here, we perform multi-particle collision dynamics simulations of solutions of semiflexible polymer chains with tunable persistence length lp to investigate the effect of chain stiffness on NP transport. The NPs exhibit two distinct dynamical regimes - subdiffusion on short time scales and diffusion on long time scales. The long-time NP diffusivities are compared with predictions from the Stokes-Einstein relation (SER), mode-coupling theory (MCT), and a recent polymer coupling theory (PCT). Increasing deviations from the SER as the polymer chains become more rigid (i.e. as…
Standard Definitions of Persistence Length Do Not Describe the Local “Intrinsic” Stiffness of Real Polymer Chains
2010
On the basis of extensive Monte Carlo simulations of lattice models for linear chains under good and Θ solvents conditions, and for bottle-brush polymers under good solvent conditions, different me...
Influence of chain stiffness on knottedness in single polymers.
2013
In the present article, we investigate and review the influence of chain stiffness on self-entanglements and knots in a single polymer chain with Monte Carlo simulations spanning good solvent, theta and globular phases. The last-named are of particular importance as a model system for DNA in viral capsids. Intriguingly, the dependence of knot occurrence and complexity with increasing stiffness is non-trivial, but can be understood with a few simple concepts outlined in the present article.
Unconventional ordering behavior of semi-flexible polymers in dense brushes under compression
2014
Using a coarse-grained bead-spring model for semi-flexible macromolecules which form a polymer brush, the structure and dynamics of the polymers were investigated, varying the chain stiffness and the grafting density. The anchoring conditions for the grafted chains were chosen such that their first bonds were oriented along the normal to the substrate plane. The compression of such a semi-flexible brush by a planar piston was observed to be a two-stage process: for a small compression the chains were shown to contract by "buckling" deformation whereas for a larger compression the chains exhibited a collective (almost uniform) bending deformation. Thus, the stiff polymer brush underwent a 2n…
Competition between liquid-crystalline ordering and glassy freezing in melts of semiflexible polymers: A monte carlo simulation
1999
We present results of a Monte Carlo simulation of dense melts of semiflexible polymers using the bond-fluctuation model. The chosen Hamiltonian increases the chain stiffness upon cooling which in turn leads to glass-transition like freezing of the polymer mobility. Employing an efficient simulation algorithm, which is able to equilibrate the simulated systems to lower temperature than the Rouse-type algorithm showing the glassy freezing, we are able to observe an isotropic-nematic phase transition. This transition lies above the glass transition temperature one would extrapolate from the observed freezing behavior.
Photoplethysmography Analysis of Artery Properties in Patients with Cardiovascular Diseases
2008
In this study arterial parameters of healthy subjects were compared to those of patients with cardiovascular diseases. The photoplethysmography (PPG) measurements of blood volume pulsations have been performed. Using a novel algorithm for analysis of simultaneously measured ear and finger PPG signals, arterial parameters were evaluated in representative groups of healthy subjects and patients with cardiovascular diseases. Digital volume pulse (DVP), pulse cycle duration (T), augmentation index (AIx), reflection index (RI) and transit time of reflected wave (RTT) were evaluated in every heartbeat cycle. Correlations between the AIx and RI, T and RTT, AIx and standard deviation of AIx, RTT an…
Peripheral Nerve Responses to Muscle Stretching: A Systematic Review
2021
Stretching is commonly used to increase range of motion and flexibility. Therefore, investigations are usually oriented towards the muscle-tendon unit. Limited evidence exists regarding potential effects of stretching on peripheral nerves which lie within muscles. The objective of this investigation will be to elucidate the responses of peripheral nerves to stretching. A literature search was performed using the following databases: Scopus, NLM Pubmed and ScienceDirect. Studies regarding the effects of stretching protocols on responses of peripheral nerves were retrieved for investigation. The NHLBI tool was used for quality assessment. Outcomes included nerve stiffness, nerve displacement,…
Generalized curved beam on elastic foundation solved by Transfer Matrix Method
2011
A solution of space curved bars with generalized Winkler soil found by means of Transfer Matrix Method is presented. Distributed, concentrated loads and imposed strains are applied to the beam as well as rigid or elastic boundaries are considered at the ends. The proposed approach gives the analytical and numerical exact solution for circular beams and rings, loaded in the plane or perpendicular to it. A well-approximated solution can be found for general space curved bars with complex geometry. Elastic foundation is characterized by six parameters of stiffness in different directions: three for rectilinear springs and three for rotational springs. The beam has axial, shear, bending and tor…
Functional muscle architecture in aging
2014
Reliability of liver stiffness measurement in non-alcoholic fatty liver disease: the effects of body mass index.
2011
Background Liver stiffness measurement (LSM) using transient elastography (TE) is used to stage fibrosis in patients with liver disease, diagnostic reliability and the factors affecting its performance in patients with non-alcoholic fatty liver disease (NAFLD) are incompletely understood. Aim To assess LSM. Methods Consecutive NAFLD patients (n = 169), assessed by liver biopsy (Kleiner score), anthropometrical, biochemical and metabolic features, underwent LSM using TE with standard M probe. Results Liver stiffness measurement was not reliable in 23 patients (14%) due to obesity. Among patients with a reliable TE, a LSM value >7.25 kPa was the best cut-off for predicting significant fibrosi…