Search results for "Scale (chemistry)"
showing 10 items of 40 documents
Local electrochemical impedance measurements on inclusion-containing stainless steels using microcapillary-based techniques
2009
MnS inclusions are good precursor sites for pitting corrosion of stainless steel. The objective of this paper was to quantify the passive properties of resulfurized stainless steel after immersion in chloride media. This was done by combining microcapillary techniques with electrochemical impedance spectroscopy and numerical analysis (specific equivalent circuit). It was shown that sulfur species produced in the electrolyte during the dissolution of inclusions react with the native passive film to CrS and FeSO 4 . Local electrochemical impedance spectroscopy measurements provided data describing the behaviour of the affected matrix at the microscale. For example, the value of the charge tra…
Thermomagnetic Properties Improved by Self-Organized Flower-Like Phase Separation of Ferromagnetic Co2Dy0.5Mn0.5Sn
2012
A thermodynamically stable phase separation of Co2Dy0.5Mn0.5Sn into the Heusler compound Co2MnSn and Co8Dy3Sn4 is induced by rapid cooling from the liquid phase. The phase separation forms an ordered flower-like structure on the microscale. The increased scattering of phonons at the phase boundaries reduces the thermal conductivity and thus improves thermoelectric and spincaloric properties.
A microscale Kjeldahl nitrogen determination for environmental waters.
2008
A microscale Kjeldahl system has been designed which has been homemade reduced. The digestor unit of a macroKjeldahl system and a modified glassware microdistillation unit have been used. The optimal conditions for digestion and distillation have been established for ammonium and methylamine as model compound of organic amino nitrogen. The optimised procedure has been applied to the determination of Kjeldahl nitrogen in water samples. Recoveries near 100% and good precision have been achieved. This procedure combines nitrogen miniaturized system and the use of a selective ion electrode for ammonia detection. The analysis time was reduced 4.8 times and the analysis cost 6.6 times compared wi…
Poor-Contrast Particle Image Processing in Microscale Mixing
2010
Particle image velocimetry (PIV) often employs the cross-correlation function to identify average particle displacement in an interrogation window. The quality of correlation peak has a strong dependence on the signal-to-noise ratio (SNR), or contrast of the particle images. In fact, variable-contrast particle images are not uncommon in the PIV community: Strong light sheet intensity variations, wall reflections, multiple scattering in densely-seeded regions and two-phase flow applications are likely sources of local contrast variations. In this paper, we choose an image pair obtained in a micro-scale mixing experiment with severe local contrast gradients. In regions where image contrast is…
Aqueous Processed Biopolymer Interfaces for Single-Cell Microarrays
2020
Single-cell microarrays are emerging tools to unravel intrinsic diversity within complex cell populations, opening up new approaches for the in-depth understanding of highly relevant diseases. However, most of the current methods for their fabrication are based on cumbersome patterning approaches, employing organic solvents and/or expensive materials. Here, we demonstrate an unprecedented green-chemistry strategy to produce single-cell capture biochips onto glass surfaces by all-aqueous inkjet printing. At first, a chitosan film is easily inkjet printed and immobilized onto hydroxyl-rich glass surfaces by electrostatic immobilization. In turn, poly(ethylene glycol) diglycidyl ether is graft…
Time-resolved velocity measurements in a magnetic micromixer
2015
Abstract Mixing efficiency is lower in passive micromixers due to viscous forces and substantial research effort is focused on designing high performance micromixers. Active micromixers make use of external forces to enhance mixing efficiency. Among these, magnetic forces are popular because they are non-contact and therefore the micromixer design can be kept simple. Laser-based diagnostic tools have great potential in providing multi-parameter information in microfluidics research on mixing. MicroPIV experiments are performed to investigate the transient flow field in a magnetic micromixer undergoing labyrinthine instability. Velocity and interface front information is extracted from a seq…
Heat Pipe-Cooled Microstructured Reactor Concept for Highly Exothermal Ionic Liquid Syntheses
2010
Heat pipes used for cooling of microstructured reactors are a new approach for sustainable processing also in the lab-scale within a temperature range from ambient to more than 180 °C. The main advantage of heat pipe cooling is the dynamic behavior, i.e., the cooling rate depends on the heat released. Heat pipes can also suppress thermal runaways due to their extremely short response times on momentary temperature rises. As an example, the highly exothermal synthesis of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate from the respective reactants 1-ethyl-imidazole and methyltrifluoromethanesulfonate was investigated. By transferring the protocol to continuous-flow conditions in the mi…
Numerical Modelling of the Urban Climate
1988
Three-dimensional numerical models of the urban climate have been developed in order to simulate climatic changes and air pollution in urban regions due to anthropogenic activities. Two versions are presented. Model A covers mesoscale γ and uses the roughness length to characterize surface structure. The microscale version B approximates the actual urban build-up by rectangular blocks. Model A results agree reasonably well with observations. For complex building structures, the microscale model must be applied. Model B results on neutral flow and pollutant transport within a particular building configuration are discussed.
Microscale Marangoni actuation: All-optical and all-electrical methods
2006
We present experimental results from an all-optical microfluidic platform that may be complimented by a thin film all-electrical network. Using these configurations we have studied the microfluidic convective flow systems of silicone oil, glycerol, and 1,3,5-trinitrotoluene on open surfaces through the production of surface tension gradients derived from thermal gradients. We show that sufficient localized thermal variation can be created utilizing surface plasmons and/or engaging individually addressable resistive thermal elements. Both studies manipulate fluids via Marangoni forces, each having their unique exploitable advantages. Surface plasmon excitation in metal foils are the driving …
Resistive switching behaviour in ZnO and VO 2 memristors grown by pulsed laser deposition
2014
The resistive switching behaviour observed in microscale memristors based on laser ablated ZnO and VO 2 is reported. A comparison between the two materials is reported against an active device size. The results show that devices up to 300 × 300 μm 2 exhibit a memristive behaviour regardless of the device size, and 100 × 100 μm 2 ZnO-based memristors have the best resistance off/on ratio.