Search results for "Scientific"

Melting Process of the Sn-45 wt.% In and Sn-77 wt.% In Alloys as Viewed by Positron Annihilation

2006

The temperature dependences of the positron annihilation parameters F and R were determined for Sn–45 wt.% In and Sn–77 wt.% In alloys. The obtained results enabled to verify the vacancy and the quasicrystalline models of the melting process. It was found that for metals transforming into the liquid state from the structures different than the close packed structure, the melting transition are hardly explainable in terms of the vacancy model of melting. The strong trapping of positrons in metallic liquids is an indication of the presence of microvoids (vacancy clusters) or microcrystals containing defects more immense than vacancies. The share of these positron trapping centers in the volum…

Solid state bonding in extrusion and FSW: process mechanics and analogies

2006

Abstract The solid state bonding occurring in extrusion and in friction stir welding (FSW) processes is investigated through FEM models previously developed and validated. In particular, for the AA6082-T6 aluminum alloys, the most relevant field variables have been monitored and compared, such as strain, strain rate, effective stress and pressure. The aim of the research is the development of an effective FSW bonding criterion.

Modeling of Electrochemical Process for Water Treatment Using Diamond Films

2011

Near-Infrared Emission of O2 Embedded in Amorphous SiO2 Nanoparticles

2011

We report an experimental study on the emission properties of O2 molecules loaded by a thermal diffusion process at 200 °C into high-purity silica nanoparticles with mean diameters of 7 and 40 nm. The embedded O 2 features a singlet to triplet emission band peaked at 1272 nm in agreement with the band observed for bulk silica materials. The photoluminescence excitation spectra have been determined in the visible and in the infrared range and are characterized by narrow bands peaked at 691, 764, and 1069 nm, respectively. By comparison of the transition energies, the vibrational quanta have been determined for the ground and for both the excited states; the values found are lower than the co…

Evaporation-induced assembly of colloidal crystals

2018

Colloidal crystals are often prepared by evaporation from solution, and there is considerable interest to link the processing conditions to the crystal morphology and quality. Here, we study the evaporation-induced assembly of colloidal crystals using massive-scale nonequilibrium molecular dynamics simulations. We apply a recently developed machine-learning technique to characterize the assembling crystal structures with unprecedented microscopic detail. In agreement with previous experiments and simulations, faster evaporation rates lead to earlier onset of crystallization and more disordered surface structures. Surprisingly, we find that collective rearrangements of the bulk crystal durin…

Electrochemical conversion of CO2 to formic acid using a Sn based electrode: A critical review on the state-of-the-art technologies and their potenti…

2021

Abstract The electrochemical conversion of carbon dioxide is considered one of the most promising strategies to convert waste-CO2 into value-added chemicals. This review focuses on the synthesis of formic acid/formate in aqueous electrolyte using Sn-based cathodes; this material is considered relatively cheap and shows promising results in terms of faradaic efficiency. In order to be suitable at an industrial scale, the process should present simultaneously high current densities, faradaic efficiencies close to 100%, high concentrations of formic acid and long-term stability. Analysing the main results reported in the literature, it was observed that to date further studies are necessary to…

Integrated Cleanroom Process for the Vapor-Phase Deposition of Large-Area Zeolitic Imidazolate Framework Thin Films

2019

Chemistry of materials XX(XX), acs.chemmater.9b03435 (2019). doi:10.1021/acs.chemmater.9b03435

Autohydrolysis pretreatment of Arundo donax: a comparison between microwave-assisted batch and fast heating rate flow-through reaction systems

2015

Background: Autohydrolysis of lignocellulosic biomass in liquid hot water has been widely studied owing to its high efficiency and relatively low cost. In the perspective of industrial applications, continuous or semi-continuous processes are more interesting than batch systems. Moreover, microwave heating of pretreatment systems has been proposed to intensify the kinetics of the process. In this study, the autohydrolysis of Arundo donax was performed in pure liquid hot water using a microwave-heated batch reactor and a semi-continuous flow-through reaction system with fast heating rate at the same operating conditions with the aim of performing a systematic comparison between the two diffe…

Crystallization in suspensions of hard spheres: a Monte Carlo and molecular dynamics simulation study

2011

The crystallization of a metastable melt is one of the most important non-equilibrium phenomena in condensed matter physics, and hard sphere colloidal model systems have been used for several decades to investigate this process by experimental observation and computer simulation. Nevertheless, there is still an unexplained discrepancy between the simulation data and experimental nucleation rate densities. In this paper we examine the nucleation process in hard spheres using molecular dynamics and Monte Carlo simulation. We show that the crystallization process is mediated by precursors of low orientational bond-order and that our simulation data fairly match the experimental data sets.

Phase Composition and Morphology of Tungsten Oxide Nanoparticles Produced via a Pyrolytic Process

2018

The chemical synthesis is a leading route for the purposeful design of nanomaterials, whereas the tungsten oxides are employed in a variety of special applications. The production of nanomaterials by traditional synthetic methods is still a cumbersome multistep procedure. Here we propose an improved method to produce tungsten oxide nanoparticles via a pyrolytic process. A tungsten-containing precursor was prepared by liquid extraction using n-trioctylamine (C8H17)3N solution in toluene. We have shown that the conditions of thermal treatment of the W-based precursor determine the crystalline structure and nanomorphology of the final product. Monoclinic WO3 nanocrystallites are produced condu…