Search results for "Sepiolite"

“AD HOC” MODIFIED CLAYS FOR BIOTECHNOLOGICAL APPLICATIONS

Nowadays, the scientific community has to face with cogent problems strictly linked to the improvement of quality of live. Among the different tasks to achieve the prefixed objective the focus has been put on the drug administration, i.e., attention has been paid to propose an appropriate solution to improve the performance of a drug delivery system and to eliminate both the side effect and drawbacks. With the aim to achieve the design, synthesis, and characterization of versatile systems, with peculiar characteristics, based on clays and clays modified with a biocompatible surfactant, able to adsorb and release organic substances of pharmaceutical interest the present PhD thesis has been u…

Morphology, flexural, and thermal properties of sepiolite modified epoxy resins with different curing agents

2006

A bisphenol A-based epoxy resin was modified with 5 wt% organically modified sepiolite (Pangel B40) and thermally cured using two different curing agents: an aliphatic diamine (Jeffamine D230, D230) and a cycloaliphatic diamine (3DCM). The morphology of the cured materials was established by scanning and transmission electron microscopy analysis. The thermal stability, thermo-mechanical properties, and flexural behaviour of the sepiolite-modified matrices were evaluated and compared with the corresponding neat matrix. The initial thermal decomposition temperature did not change with the addition of sepiolite. The flexural modulus of the epoxy matrix slightly increases by the incorporation o…

Low temperature conversion of levulinic acid into γ-valerolactone using Zn to generate hydrogen from water and nickel catalysts supported on sepiolite

2020

1 scheme, 2 tables, 7 figures.-- Supplementary material available.

Porous materials as delivery and protective agents for Vitamin A

2016

The suitability of porous materials to immobilize and release under control bioactive molecules prompted us to design and study delivery systems of Vitamin A (VitA). This molecule, relevant in several physiological functions, is easily oxidized. Commercial VitA was immobilized in two different clays, montmorillonite K-10 (MMT) and sepiolite (SEP), and in MCM-41, by impregnation. Characterization of the resulting hybrid materials by XRD, FTIR and 13C and 29Si (MAS) NMR spectroscopies revealed its presence. The photo-stability tests showed decreased degradation of VitA in the clays, compared to MCM-41 and the pure VitA, while thermostability is observed until ∼100 °C. The kinetics of the rele…

X-ray diffraction line broadening on vibrating dry-milled Two Crows sepiolite

2006

A reference sample of sepiolite and products of its comminution by vibrating dry-milling have been studied using X-ray diffraction (XRD) line-broadening analysis, complementary field emission scanning electron microscopy (FESEM) images and surface area measurements. The apparent crystallite sizes determined via XRD are in agreement with observations on FESEM images. The sepiolite aggregates consist of lath-shaped agglutinations of prisms and pinacoids elongated along [001], each lath including several crystallites in that direction. The surface area magnitudes are in the range of previous experimental measurements of other sepiolites. The results obtained show the effectiveness of vibro-mil…

Crystalline microstructure of sepiolite influenced by grinding

2005

The crystalline microstructure of ground sepiolite has been investigated. A reference sample of sepiolite and products of its comminution by dry grinding were studied through X-ray diffraction pattern analysis, specific surface measurements by nitrogen adsorption and complementary analysis of field emission scanning electron microscope images. A statistical model of polycrystals was applied to describe and determine the crystalline microstructure of the studied specimens. The model parameters characterizing the microstructure were prevalent crystallite shape, volume-weighted crystallite size distribution and second-order crystalline lattice strain distribution, and they were determined for …

On the interpretation of the Raman spectra of Maya Blue: a review on the literature data

2011

The Raman spectroscopy of Maya Blue (MB), a nanostructured organic–inorganic hybrid material, has received considerable attention. A re-evaluation of the Raman literature data for indigo dye, genuine MB samples and model specimens obtained by the binding of indigo to phyllosilicate clays, such as palygorskite and sepiolite, using chemometric analysis of normalised spectra is reported. Available data present features in support of the following ideas: (1) dehydroindigo accompanies indigo in MB; (2) different topological isomers, i.e. dye molecules attached to different coordinative sites of the palygorskite framework, are involved in MB; and (3) different procedures were probably used for pr…

Phosphorylation triggered growth of metal phosphate on halloysite and sepiolite nanoparticles: preparation, entrapment in chitosan hydrogels and appl…

2020

The rational design of porous, biomass-derived eco-friendly adsorbents instead of costly synthetic, petroleum-based resins stands as a promising approach to resolving the thorny issue of sewage treatment (for example, by supplying safe water for drinking and irrigation). Herein we explore a straightforward transformation of abundant clay and polysaccharides into highly-reactive water-cleaning adsorbents. Surface-functionalization of sepiolite and halloysite by phosphoryl chloride triggered metal dissolution from the framework (inside of the lumen for halloysite and on the external surface for sepiolite) and the concomitant growth of well-truncated crystalline metal phosphates. These unprece…

Float glass colouring by ion exchange

2008

Abstract Back in the Middle Ages, glass artists used to produce yellowish colorations in soda-lime glasses using mixtures that contained silver salts, clay composites and natural oils. The resulting colour was a characteristic pale yellow known as silver-stain. This coloration is mainly caused by the extinction – absorption and, to a lesser extent, scattering – of light occasioned by silver nanoparticles formed inside the glass. This colouring technique comprises a heat treatment divided in two stages: in the first one, an ion exchange between the silver ions in the mixture and the alkali ions in the glass takes place. This process is called nucleation of silver nanoparticles. The second st…

Salt extraction from lime-based mortars: An experimental study using different poultice formulations

2020

Abstract The extractive capability of soluble salts in poultices treatments currently used in mortar conservation (ArbocelTM plus sepiolite; ArbocelTM, sepiolite and sand; Westox-Cocoon®) were tested to evaluate their efficiency and compatibility with specific mortar substrate. The pore size distribution of the experimental mortar substrate and of the blank dried poultices were preliminarily accomplished by mercury intrusion porosimetry (MIP). Desalination tests were carried out on specifically-formulated mortars after capillary absorption of Na2SO4 0.3 M solution. The efficiency of salt extraction was measured by means of electrical conductivity meter and ion chromatography. Among the test…