Search results for "Setti"
showing 10 items of 362 documents
Curing of an epoxy resin modified with nanoclay monitored by dielectric spectroscopy and rheological measurements
2006
Dielectric and rheological measurements have been performed in “real-time” to follow curing reaction on blends of a diglycidyl ether of bisphenol-A epoxy resin with 4,4-methylene bis(2,6-diethylaniline) hardener and different amounts of organically modified nanoclay (Nanofil 919) as modifier. The effect of the modifier and its amount on the curing reaction, as well as that of the curing temperature has been studied. Changes in molecular mobility in the reaction mixture have been investigated by dielectric relaxation spectroscopy. Evolutions of ionic conductivity and main relaxation have been analyzed and vitrification times have been obtained and compared with those obtained by rheological …
The effect of a liquid CTBN rubber modifier on the thermo-kinetic parameters of an epoxy resin during a pultrusion process
2003
Abstract Rheo-kinetic behaviour of an epoxy resin, coupled with an anhydride hardener, with different CTBN liquid rubber concentration (0–15 phr), used in fibre reinforced plastics, was analysed comparing experimental data with theoretical models. The modelling of technological pultrusion process for thermoset matrix composites, developed through a numerical code realised with MATLAB, is reported, too. The model includes conduction and cure heat, degree of cure and viscosity evolution during the curing within the die. Considerable differences in process condition, using different rubber amount, are obtained. The numerical modelling of process conditions shows that the CTBN rubber presence i…
Fracture Toughness of Hydrothermally Aged Epoxy Systems with Different Crosslink Density
2015
Abstract The present work investigates the fracture toughness behaviour of Single Edge Notched Bending (SENB) samples of epoxy systems subject to water uptake aging. Two epoxy systems with a significantly different Glass Transition Temperature, T g , are in particular considered: a typical commercial non-aeronautical grade resin matrix for composite applications, reaching a T g of 90 °C, and a DGEBA+DDS epoxy system achieving a T g of 230 °C.The materials have been conditioned by hydrothermal aging in a thermal bath at the temperature of 50 °C. TransmissionPhotoelastic Stress Analysisis carried outon SENB samples during water aging, monitoring the presence and evolution of swelling stresses…
Thermomechanical properties of radiation-modified blends of polyethylene with liquid crystalline copolyester
1999
The results of investigation of gamma irradiated blends of high-density polyethylene (PE) with thermotropic polymer liquid crystal (PLC) are presented. The PLC used was a copolyester of 40% poly(ethylene terephthalate) with 60% p-(hydroxy-benzoic acid). The PLC content in the blends was 0, 5, and 10 wt%. The constituents were blended with the use of a single screw extruder. The specimens were prepared by compression molding. The irradiation of the samples was performed by a Co 60 γ-radiation source in inert atmosphere (argon) up to absorbed relatively low doses (up to 200 kGy: 1 Mrad = 10 kGy). The morphological, thermal, and mechanical properties were investigated for irradiated and unirra…
Study and comparison of interaction parameters and phase behavior of epoxy/polystyrene and epoxies copolymer polystyrene-b-poly(methyl methacrylate) …
2008
Thermodynamic studies in terms of phase separation behavior and interaction parameters, in mixtures of epoxy resins (thermoset materials) with thermoplastic additives, consisting of polystyrene (PS) or polystyrene-b-poly(methyl methacrylate) P(S-MMA) (with small proportion of MMA), have been carried out. It can be confirmed that the solubility of P(S-MMA) is an improvement on that of PS, with the prepolymer epoxy resins. Moreover, the interaction parameters are positive at temperatures in which phase separation is observed, but negative at temperatures in which the phase separation window disappears, in the corresponding phase diagram. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engine…
Thermosetting composites based on bronze particles for archaeological and artistic metal heritage cloning
2018
peer-reviewed Artificial Metals are polymeric semi-metallic composites obtained by combining thermosetting resins with atomized metal powders in order to achieve composite materials capable of reproducing metals, even in a rusty or corroded condition. These composites provide a solution for the reproduction of archaeological artefacts, sculptures, and ornaments for the purpose of conservation. This work explores mechanical properties of three different resins bronze composites loaded with two different proportions of metal filler. The degree of conversion of the samples was measured by differential scanning calorimetry (DSC) and flexural tests were carried out to determine their mechanical …
Toward high performance renewable agave reinforced biocomposites: Optimization of fiber performance and fiber-matrix adhesion analysis
2017
Abstract The increasing sensitivity toward the environmental pollution and the recent laws on the environmental protection, have led to an increasing attention to the so called biocomposites, i.e. to ecofriendly or renewable composite materials, obtained from biopolymers reinforced by natural fibers. Although the contribution of various works reported in literature, focused on biocomposites reinforced by agave fibers, such materials are still exclusively used in the automotive industry for non-structural applications, and the implementation of high performance biocomposites for semi-structural and structural applications, is an expected, but not yet reached objective. Therefore, the present…
Salt-fog spray aging of jute-basalt reinforced hybrid structures. Flexural and low velocity impact response
2017
Abstract In this work, a study on the aging resistance of jute and jute-basalt interply hybrid laminates exposed to salt-fog is presented with the aim to investigate the possibility to enhance the durability of natural fiber reinforced composites for marine application by a ply-substitution approach. In particular, jute and basalt/jute reinforced composite plates were manufactured by vacuum assisted resin infusion in two different staking sequences (i.e., intercalated and sandwich-like basalt-jute) and aged under salt fog conditions. The effects of the accelerated aging at increasing times on the mechanical response of laminates were assessed in both quasi static (three point bending) and d…
Assessing the competence learning to learn: a methodological proposal
2012
En este artículo se presenta un procedimiento para diseñar instrumentos para evaluar la competencia de Aprender a Aprender. Analizamos la secuencia de trabajo y los conceptos implicados. Se trata de una línea de trabajo que pretende diseñar instrumentos de evaluación referidos a estándares, para evaluar las competencias básicas en la educación obligatoria, y las genéricas o transversales en las titulaciones de grado universitarias (el sistema de instrumentos para universitarios se denomina ESCOGE). Se ilustra la reflexión acerca de esta propuesta con la definición teórica realizada para el diseño de instrumentos que permitan evaluar esta competencia en egresados universitarios del área de C…
Under What Conditions Do the News Media Influence Corporate Reputation? The Roles of Media Dependency and Need for Orientation
2010
Previous research has assumed uniform effects of the news media's influence on corporate reputation. This study uses theories of media system dependency and ‘need for orientation’ to examine contingent conditions affecting the degree of the media influence. Our integrated measurement approach gauging media coverage and stakeholder evaluations on the same dimensions of reputation furthered the methodological approach to this research area. We found that stakeholders depend more on the news media to learn about reputation dimensions that are difficult to directly experience or observe and for which the news media are the main source of information.