Search results for "Shape"
showing 10 items of 585 documents
Fluorescence excitation and emission spectroscopy on single MEH-PPV chains at low temperature.
2008
Fluorescence emission and excitation spectra of single MEH-PPV polymer molecules dispersed in thin PMMA films have been recorded at 1.2 and 20 K. We observe single as well as multichromophore emission in single chain emission spectra, whereby the relative fractions depend on the two different molecular weights (50 and 350 kDa) studied. The molecular weight also affects the distribution of peak emission maxima, which is monomodal (bimodal) for the low (high) molecular weight. The appearance of an additional "red" subpopulation for the high molecular weight sample is attributed to interactions of multiple chromophores from a sufficiently flexible single chain. The comparison of emission spect…
Crystal structure and Hirshfeld surface analysis of poly[[bis[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]nickel(II)tetrapotassium]…
2021
The complex nickel(II) anion comprises a pseudomacrocyclic hydrazide-based ligand with an L shape. In the crystal, such anions are connected with the potassium cations and the water solvent molecules, forming a three-dimensional polymeric framework, which is stabilized by an extensive system of hydrogen bonds.
A second solvatomorph of poly[[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]nickel(II)dipotassium] : crystal structure, Hirshfeld su…
2021
The title compound, poly[triaquabis[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]dinickel(II)tetrapotassium], [K4Ni2(C7H6N4O7)2(H2O)3] n , is a second solvatomorph of poly[(μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)nickel(II)dipotassium] reported previously [Plutenko et al. (2021). Acta Cryst. E77, 298–304]. The asymmetric unit of the title compound includes two structurally independent complex anions [Ni(C7H6N4O7)]2−, which exhibit an L-shaped geometry and consist of two almost flat fragments perpendicular to one another: the 1,3,5-oxadiazinane fragment and the fragment including other atoms of the anion. The central Ni atom is in a square-planar N2O2 co…
Species–area relationships in continuous vegetation: Evidence from Palaearctic grasslands
2019
Aim Species-area relationships (SARs) are fundamental scaling laws in ecology although their shape is still disputed. At larger areas, power laws best represent SARs. Yet, it remains unclear whether SARs follow other shapes at finer spatial grains in continuous vegetation. We asked which function describes SARs best at small grains and explored how sampling methodology or the environment influence SAR shape. Location Palaearctic grasslands and other non-forested habitats. Taxa Vascular plants, bryophytes and lichens. Methods We used the GrassPlot database, containing standardized vegetation-plot data from vascular plants, bryophytes and lichens spanning a wide range of grassland types throu…
A propósito de la localización de una pintura sobre tabla de ?La Virgen de la Leche?, del siglo XIV, atribuida a Bernabé de Módena, que perteneció al…
2020
The castle's Hermitage of Yecla (Region of Murcia) constituted during the 13th to 16th centuries the first parish of the population, hosting a triptych-shaped altarpiece presided over by a tempera painting on wood of Our Lady of Humility or "Virgo Lactans", dated around 1370 and attributed to the painter Barnaba da Modena, which was the titular image of the mentioned temple under the title of Our Lady of the Incarnation, until at the end of the 18th century it changed ownership for the Conception of Our Lady. The table at averages of the eight hundred was placed in an a loft, appropriating it at the beginning of the 20th century by the retired military Pascual Spuche y Lacy, who sold it aro…
Beta-spectrum shapes of forbidden β decays
2018
The neutrinoless [Formula: see text] decay of atomic nuclei continues to attract fervent interest due to its potential to confirm the possible Majorana nature of the neutrino, and thus the nonconservation of the lepton number. At the same time, the direct dark matter experiments are looking for weakly interacting massive particles (WIMPs) through their scattering on nuclei. The neutrino-oscillation experiments on reactor antineutrinos base their analyses on speculations of [Formula: see text]-spectrum shapes of nuclear decays, thus leading to the notorious “reactor antineutrino anomaly.” In all these experimental efforts, one encounters the problem of [Formula: see text]-spectrum shapes of…
Kinetic Solutions for Responsive and Communicative Building Skin
2018
Theskinof buildings represents the first level of communication between construction, man and environment. In this relationship, the concept of communication acquires different values, because it can be applied both to the architectural field in relation to the shape, and to the perceptive and communicative sphere, aimed to transmission of messages or even to the interaction of the architectural envelope with the user and the environment. This brings us back to the energy and sustainability aspects, since the primary role as a separation and filter layer of the building façades is that of shielding. The solution with a kinetic façade constitutes not only a possibility of climatic mediation …
The size and shape of shells used by hermit crabs: A multivariate analysis of Clibanarius erythropus
2009
Shell attributes such as weight and shape affect the reproduction, growth, predator avoidance and behaviour of several hermit crab species. Although the importance of these attributes has been extensively investigated, it is still difficult to assess the relative role of size and shape. Multivariate techniques allow concise and efficient quantitative analysis of these multidimensional properties, and this paper aims to understand their role in determining patterns of hermit crab shell use. To this end, a multivariate approach based on a combination of size-unconstrained (shape) PCA and RDA ordination was used to model the biometrics of southern Mediterranean Clibanarius erythropus populatio…
Modeling of female human body shapes for apparel design based on cross mean sets
2014
This paper is concerned with a method to build prototypes of human bodies that can be used for apparel design. One of the most important issues in the apparel development process is to define a sizing system to provide a good fitting for the majority of the population. Since anthropometric measures do not present the same linear growth with size in each dimension, it is very important to find a prototype that represents as accurately as possible each class in the sizing system. In this paper we propose a method based on the concept of random compact mean set to define prototypes in apparel design. From a cloud of 3D points obtained with a 3D scanner a solid that represents the human body is…
The unusual hydrodynamical behaviour of freshwater oncolites
1997
Algal concretions are frequent in calcareous environments, occuring as individual particles (oncolites) that are easily transported during floods. Several parameters have been measured and calculated for a population of 127 particles from French streams. These oncolites have a high porosity (mean 42.7%) and a low density (mean 1.65), in respect to quartz and calcite. Oncolites have a settling velocity 1.5 times lower than that of quartz grains with the same nominal diameter. The computation of multiple correlations results in a classification in terms of decreasing efficiency: shape coefficients (Corey, ψ, and SI of Sneed and Folk), nominal diameter, density, edge sharpness and roughness. A…