Search results for "Shear viscosity"

Computing bulk and shear viscosities from simulations of fluids with dissipative and stochastic interactions

2016

Exact values for bulk and shear viscosity are important to characterize a fluid and they are a necessary input for a continuum description. Here we present two novel methods to compute bulk viscosities by non-equilibrium molecular dynamics (NEMD) simulations of steady-state systems with periodic boundary conditions -- one based on frequent particle displacements and one based on the application of external bulk forces with an inhomogeneous force profile. In equilibrium simulations, viscosities can be determined from the stress tensor fluctuations via Green-Kubo relations; however, the correct incorporation of random and dissipative forces is not obvious. We discuss different expressions pro…

Thermodynamic formalism for transport coefficients with an application to the shear modulus and shear viscosity.

2016

We discuss Onsager's thermodynamic formalism for transport coefficients and apply it to the calculation of the shear modulus and shear viscosity of a monodisperse system of repulsive particles. We focus on the concept of extensive "distance" and intensive "field" conjugated via a Fenchel-Legendre transform involving a thermodynamic(-like) potential, which allows to switch ensembles. Employing Brownian dynamics, we calculate both the shear modulus and the shear viscosity from strain fluctuations and show that they agree with direct calculations from strained and non-equilibrium simulations, respectively. We find a dependence of the fluctuations on the coupling strength to the strain reservoi…

Temperature dependence of η/s : uncertainties from the equation of state

2018

We perform a global model-to-data comparison on Au+Au collisions at $\sqrt{s_{NN}}=200$ GeV and Pb+Pb collisions at $2.76$ TeV and $5.02$ TeV, using a 2+1D hydrodynamics model with the EKRT initial state and a shear viscosity over entropy density ratio $(\eta/s)(T)$ with a linear $T$ dependence. To quantify the amount of uncertainty due to the choice of the equation of state (EoS), we compare analysis results based on four different EoSs: the well known $s95p$ parametrisation, an updated parametrisation based on the same list of particles in hadron resonance gas, but using recent lattice results for the partonic part of the EoS, and two new parametrisations based on the Particle Data Group …

Rheological and Flocculation Analysis of Microfibrillated Cellulose Suspension Using Optical Coherence Tomography

2018

A sub-micron resolution optical coherence tomography device was used together with a pipe rheometer to analyze the rheology and flocculation dynamics of a 0.5% microfibrillated cellulose (MFC) suspension. The bulk behavior of the MFC suspension showed typical shear thinning (power-law) behavior. This was reflected in a monotonously decreasing floc size when the shear stress exceeded the yield stress of the suspension. The quantitative viscous behavior of the MFC suspension changed abruptly at the wall shear stress of 10 Pa, which was reflected in a simultaneous abrupt drop of the floc size. The flocs were strongly elongated with low shear stresses. With the highest shear stresses, the flocs…

Healon®5: A New Viscoadaptive Formulation

2000

To relate the practical relevance of our study results, specific requirement profiles for individual procedures have been correlated to the desired physicochemical characteristics. Healon®5 demonstrated the statistically significant highest zero shear viscosity of all OVD and a long relaxation time (Dick et al., 2000). It therefore most effectively creates and maintains a deep anterior chamber in order to facilitate safe surgical maneuvers (e.g., in case of vitreous pressure). Additionally, the high viscosity of Healon®5 exhibits a dynamic frequency dependence, which has not been observed in any pure hyaluronic acid formulation before. Healon®5’s properties change in response to surgical ma…

Publisher's Note: "Thermodynamic formalism for transport coefficients with an application to the shear modulus and shear viscosity" [J. Chem. Phys. 1…

2017

Testing of a constitutive equation for entangled networks by elongational and shear data of polymer melts

1973

An entangled network such as a polymer melt or a concentrated solution is here described by a set of two simultaneous equations. One of them is a balance of entanglements, the other gives the stress in the classical form of aMaxwell equation.

Melt Strength and Extensibility of High-Density Polyethylene

1984

The extensional flow of polymer melts has been extensively studied because of its importance in many technological processing operations and, from a more fundamental point of view, because the tensile properties of the polymer melts cannot be correlated directly with shear viscosity behavior.1–5