Search results for "Sido"
showing 10 items of 522 documents
Encapsulation and solid state sequestration of gases by calix[6]arene-based molecular containers
2017
Two calix[6]arene-based molecular containers were synthesized in high yields. These containers can encapsulate small guests through a unique "rotating door" complexation process. The sequestration of greenhouse gases is clearly demonstrated. They can be stored in the solid state for long periods and released via dissolution of the inclusion complex.
Halogen bonds in 2,5-dihalopyridine-copper(II) chloride complexes
2018
Ten coordination complexes obtained through a facile reaction between 2,5-dihalopyridines and copper(II) chloride (CuCl2) are characterized using single crystal X-ray diffraction. Two series of dihalopyridine complexes based on 2-chloro-5-X-pyridine and 2-bromo-5-X-pyridine (X = F, Cl, Br and I) were prepared to analyze the C–X2/X5⋯Cl–Cu halogen bonds (XB). The influence of X2- and X5-substituents on the respective interactions was examined by comparing them to the X2/X3⋯Cl–Cu XBs found in mono-substituted halopyridine complexes, (n-X-pyridine)2·CuCl2 (n = 2, 3 and X = Cl, Br and I). Varying the X5-halogens in (2,5-dihalopyridine)2·CuCl2, the C5–X5⋯Cl–Cu XBs follow the order F5 1 and they c…
Reversible O–H bond activation by an intramolecular frustrated Lewis pair
2019
The interactions of the O-H bonds in alcohols, water and phenol with dimethylxanthene-derived frustrated Lewis pairs (FLPs) have been probed. Within the constraints of this backbone framework, the preference for adduct formation or O-H bond cleavage to give the corresponding zwitterion is largely determined by pKa considerations. In the case of the PPh2/B(C6F5)2 system and p-tBuC6H4OH, an equilibrium is established between the two isomeric forms which allows the thermodynamic parameters associated with zwitterion formation via O-H bond cleavage to be probed.
Letter to the editor regarding the article “Taking advantage of seagrass recovery potential to develop novel and effective meadow rehabilitation meth…
2020
Alagna et al. (2019) suggest new transplantation methods for Posidonia oceanica (Linnaeus) Delile, inspired by its natural recovery process after disturbance due to dredging operations for gas-pipelines. They observe that P. oceanica vegetative fragments naturally settled only on loose calcareous stones deployed to fill the trenches of the gas-pipeline. No recovery was noted on dead matte, sand and large calcarenitic boulders. Following a new pilot restoration project currently ongoing in the same area, we demonstrate that natural recovery also occurs on dead matte. After examining other alternative transplantation methods for P. oceanica, the Authors suggest using their "habitat enhancemen…
The mapping of the Posidonia oceanica (L.) Delile barrier reef meadow in the southeastern Gulf of Tunis (Tunisia)
2016
Abstract Barrier reefs are among the most important ecomorphosis for Posidonia oceanica meadows and have long been subjected to anthropic pressures. The authors mapped the entire Sidi Rais (northeastern Tunisia) Posidonia oceanica barrier reef by means of remote sensing based on processing a satellite image acquired via Google Earth © software, coupled with field observations obtained by snorkeling. The map thus produced represents the P. oceanica barrier reef in its current state, covering a total area of 156.77 ha, the reef being divided into three distinct sections separated by reverse flows with each section subject to varied anthropic factors and disturbances.
Methanotrophs are core members of the diazotroph community in decaying Norway spruce logs
2018
Dead wood is initially a nitrogen (N) poor substrate, where the N content increases with decay, partly due to biological N2 fixation, but the drivers of the N accumulation are poorly known. We quantified the rate of N2 fixation in decaying Norway spruce logs of different decay stages and studied the potential regulators of the N2-fixation activity. The average rate for acetylene reduction in the decaying wood was 7.5 nmol ethylene g−1d−1, which corresponds to 52.9 μg N kg−1d−1. The number of nifH copies (g−1 dry matter) was higher at the later decay stages, but no correlation between the copy number and the in vitro N2 fixation rate was found. All recovered nifH sequences were assigned to t…
Root hair anatomy and morphology in Posidonia oceanica (L.) Delile and substratum typology: First observations of a spiral form
2018
Abstract The morpho-anatomical root hair features of P. oceanica ramets collected in meadows settled on different substrata (sand, matte and rock) were analysed. On each substratum, nine plagiothropic rhizomes each one composed by 3–6 interconnected short shoots were collected between April and May 2016 at 10 m of depth. On sand and on rock, the adventitious roots showed two distinct tubular and spiral-shaped hairs, clustered in yellowish-gray gelatinous pads. Tubular root hair tips were dactiliform and generally attached to grains of rock fragments. Moreover, a sub-circular swelling zone occurred. On matte , root hairs did not form gelatinous pads, were very short and had a simple distal p…
Sustainable Mixed Cropping Systems for the Boreal-Nemoral Region
2020
Mixed cropping, including intercropping, is the oldest form of systemized agricultural production and involves the growing of two or more species or cultivars of the same species simultaneously in the same field. However, mixed cropping has been little by little replaced by sole crop systems, especially in developed countries. Some of the advantages of mixed cropping are, for example, resource use efficiency and yield stability, but there are also several challenges, such as weed management and competition. The boreal-nemoral region lies within the region 55° to 70° N. In this area, for example in Finland, the length of the thermal growing season varies from less than 105 to over 185 days. …
Ecological function of phenolic compounds from mediterranean fucoid algae and seagrasses: An overview on the genus Cystoseira sensu lato and Posidoni…
2020
Biodiversity is undergoing rapid and worrying changes, partially driven by anthropogenic activities. Human impacts and climate change (e.g., increasing temperature and ocean acidification), which act at different spatial scales, represent the most serious threats to biodiversity and ecosystem structure and function. In the Mediterranean Sea, complex systems such as fucoid algae and seagrasses, characterized by a high associated biodiversity, are regularly exposed to natural and anthropogenic pressures. These systems, particularly sensitive to a variety of stressors, evolved several physiological and biochemical traits as a response to the different pressures which they are subjected to. For…
Seagrasses along the Sicilian coasts
2010
All seagrass species known from the Mediterranean basin have been recorded along the Sicilian coast, where studies have been carried out at a very local scale and information is fragmented or confined to the grey literature. The objective of this article is to summarise and evaluate current knowledge on seagrass species on the Sicilian coasts, providing an overview of species distribution, genetic diversity, biology and ecology, based on the literature and unpublished data. Most literature studies have been carried out on Posidonia oceanica meadows because of their wide distribution, complexity and ecological importance. In this study, the analyses carried out on P. oceanica structural and …