Search results for "Sieve"
showing 10 items of 76 documents
Spherical ordered mesoporous silicas and silica monoliths as stationary phases for liquid chromatography
2006
Ordered mesoporous silicas such as micelle-templated silicas (MTS) feature unique textural properties in addition to their high surface area (approximately 1000 m2/g): narrow mesopore size distributions and controlled pore connectivity. These characteristics are highly relevant to chromatographic applications for resistance to mass transfer, which has never been studied in chromatography because of the absence of model materials such as MTS. Their synthesis is based on unique self-assembly processes between surfactants and silica. In order to take advantage of the perfectly adjustable texture of MTS in chromatographic applications, their particle morphology has to be tailored at the microme…
Aluminum-27 double-rotation NMR investigations of SAPO-5 with variable silicon content
1995
Summary Double-rotation NMR (DOR) studies of 27 Al species in SAPO-5, a silicon aluminophosphate molecular sieve with a one dimensional channel system, have revealed a minimum of three aluminum sites resulting from the synthesis. The DOR technique was used specifically to increase the spectral resolution by removing the broadening influences from second-order quadrupolar interactions associated with the spin 5/2 27 Al nuclei. The DOR investigations of SAPO-5 crystals with variable Si/Al ratios resulted in the identification of three aluminum species, two consistent with the reported isotropic shift values for AlPO 4 -5; however, these two resonances are only observable when small quantities…
Selective mono-de-O-acetylation of the per-O-acetylated brasilicardin carbohydrate side chain
2021
Abstract Methanol dried over powdered 4 A molecular sieves can be used for a selective mono-de-O-acetylation of the phenolic acetyl group of the per-O-acetyl protected brasilicardin A carbohydrate side chain. This reaction opens a practical procedure for a synthetic access to derivates of the immunosuppressive and cytotoxic natural product brasilicardin A.
Characterization of Nd-MCM41 obtained by impregnation
2008
Abstract Silica mesoporous molecular sieves (MCM-41), prepared by using micelles as template, were functionalized by means of incipient wetness method. Evidence for the neodymium presence in the silica matrix was obtained by means of EDX. SEM micrographs showed that impregnation does not change significantly MCM-41 morphology. The maintenance of the hexagonal structure was confirmed by XRD pattern analysis. However, the observed loss of long-range ordering, the cell parameter increase and the surface area decrease, observed by gas adsorption technique, were attributed to the introduction of neodymium oxide inside the MCM-41 mesochannels. By FT-IR and Raman spectra it was found that the main…
PFG n.m.r. study of diffusion anisotropy in oriented ZSM-5 type zeolite crystallites
1991
ZSM-5 zeolite crystallites are oriented by introducing them into a system of parallel capillaries. In this way, by applying pulsed-field gradient (PFG) n.m.r., a direct measurement of the orientation dependence of diffusion in ZSM-5 crystals has become possible. Using methane as a diffusant, the ratio D xy /D z between the diffusivities in the xy plane and in the z direction has been found to be of the order of 4.5. This value is in satisfactory agreement with the behavior expected from both MD calculations and a random walk model of molecular propagation in the two-channel network of ZSM-5-type zeolites.
Lacunar fractal photon sieves
2007
We present a new family of diffractive lenses whose structure is based on the combination of two concepts: photon sieve and fractal zone plates with variable lacunarity. The focusing properties of different members of this family are examined. It is shown that the sieves provide a smoothing effect on the higher order foci of a conventional lacunar fractal zone plate. However, the characteristic self-similar axial response of the fractal zone plates is always preserved.
Cantor Dust Zone Plates
2013
In this paper we use the Cantor Dust to design zone plates based on a two-dimensional fractal for the first time. The pupil function that defines the coined Cantor Dust Zone Plates (CDZPs) can be written as a combination of rectangle functions. Thus CDZPs can be considered as photon sieves with rectangular holes. The axial irradiances produced by CDZPs of different fractal orders are obtained analitically and experimentally, analyzing the influence of the fractality. The transverse irradiance patterns generated by this kind of zone plates has been also investigated.
Monte Carlo calculation of dose rate distributions around the Walstam CDC.K-type137Cs sources
2001
Basic dosimetric data for the Walstam CDC.K-type low dose rate 137Cs sources in water have been calculated using Monte Carlo techniques. These sources, CDC.K1 -K3 and CDC.K4, are widely used in a range of applicators and moulds for the treatment of intracavitary and superficial cancers. Our purpose is to improve existing data about these sources using the Monte Carlo simulation code GEANT3. Absolute dose rate distributions in water have been calculated around these sources and are presented as conventional 2D Cartesian look-up tables. Also the AAPM Task Group 43 formalism for dose calculation has been applied. The calculated dose rate constant for the CDC.K1-K3 source is A = 1.106 +/- 0.001…
A Monte Carlo investigation of the dosimetric characteristics of the CSM11 137Cs source from CIS
2000
The purpose of this study is to calculate basic dosimetry data for a CSM11 low dose rate 137Cs source in water. This source is widely used in afterloadable dome cylinders designed to homogeneously irradiate the vaginal cuff alone or additional areas of the vagina in hysterectomized patients. In this study, the Monte Carlo simulation code GEANT, incorporating in detail source geometry, is used to investigate the dosimetric characteristics of the source. The calculated data were analyzed using a fitting procedure that is described in detail. Absolute dose rate distributions in water were calculated around this source and are presented as conventional 2D Cartesian lookup tables (classically al…
Structural incorporation of nitrogen into zeolites, and alpos: ab initio molecular orbital calculations on stability and basicity
1998
Ab initio molecular orbital calculations (HF/6-31G*) are used to obtain thermodynamical information on the possibility to form NH-bridging or NH2-terminal groups in amorphous and crystalline materials containing Si–O–Si and Al–O–P structures, such as for instance, zeolites and aluminophosphates. We have employed dimeric model clusters Si–O–Si and Al–O–P which contain NH2-terminal groups or an oxygen atom substituted by a NH bridging unit. The Bronsted basicity and the softness–hardness of these structures have been determined using the proton affinity and the HOMO energy, respectively. The obtained results indicate that for both Si–O–Si and Al–O–P linkages and from a thermodynamic standpoin…