Search results for "Silicic"
showing 10 items of 95 documents
Chemistry and mineralogy of outcrops at Meridiani Planum
2005
Analyses of outcrops created by the impact craters Endurance, Fram and Eagle reveal the broad lateral continuity of chemical sediments at the Meridiani Planum exploration site on Mars. Approximately ten mineralogical components are implied in these salt-rich silicic sediments, from measurements by instruments on the Opportunity rover. Compositional trends in an apparently intact vertical stratigraphic sequence at the Karatepe West ingress point at Endurance crater are consistent with non-uniform deposition or with subsequent migration of mobile salt components, dominated by sulfates of magnesium. Striking variations in Cl and enrichments of Br, combined with diversity in sulfate species, pr…
Provenance and diagenesis of the evaporite-bearing Burns formation, Meridiani Planum, Mars
2005
Abstract Impure reworked evaporitic sandstones, preserved on Meridiani Planum, Mars, are mixtures of roughly equal amounts of altered siliciclastic debris, of basaltic provenance (40 ± 10% by mass), and chemical constituents, dominated by evaporitic minerals (jarosite, Mg-, Ca-sulfates ± chlorides ± Fe-, Na-sulfates), hematite and possibly secondary silica (60 ± 10%). These chemical constituents and their relative abundances are not an equilibrium evaporite assemblage and to a substantial degree have been reworked by aeolian and subaqueous transport. Ultimately they formed by evaporation of acidic waters derived from interaction with olivine-bearing basalts and subsequent diagenetic alterat…
Silicic acid competes for dimethylarsinic acid (DMA) immobilization by the iron hydroxide plaque mineral goethite.
2015
Abstract A surface complexation modeling approach was used to extend the knowledge about processes that affect the availability of dimethylarsinic acid (DMA) in the soil rhizosphere in presence of a strong sorbent, e.g., Fe plaques on rice roots. Published spectroscopic and molecular modeling information suggest for the organoarsenical agent to form bidentate-binuclear inner-sphere surface complexes with Fe hydroxides similar to the inorganic As oxyanions. However, since also the ubiquitous silicic acid oxyanion form the same bidentate binuclear surface complexes, our hypothesis was that it may have an effect on the adsorption of DMA by Fe hydroxides in soil. Our experimental batch equilibr…
An evaluation of the antireflux properties of sodium alginate by means of combined multichannel intraluminal impedance and pH-metry.
2005
Summary Background : Alginate-based preparations act as mechanical antireflux barrier, which can reduce both acid and non-acid reflux events and limit the proximal migration of oesophageal refluxate. Aim : To evaluate all the above features with a novel technique, multichannel electrical impedance and pH-metry. Methods : Ten reflux patients underwent stationary impedancemetry and pH-metry after eating a refluxogenic meal. They were studied 1 h in basal conditions and 1 h after taking 10 mL of Gaviscon Advance. In both sessions, measurements were obtained in right lateral and supine decubitus. Results : Alginate preparation was able to decrease significantly (P < 0.05) the number of acid ref…
Unravelling textural heterogeneity in obsidian:shear-induced outgassing in the Rocche Rosse flow
2016
Obsidian flow emplacement is a complex and understudied aspect of silicic volcanism. Of particular importance is the question of how highly viscous magma can lose sufficient gas in order to erupt effusively as a lava flow. Using an array of methods we study the extreme textural heterogeneity of the Rocche Rosse obsidian flow in Lipari, a 2. km long, 100. m thick, ~. 800. year old lava flow, with respect to outgassing and emplacement mechanisms. 2D and 3D vesicle analyses and density measurements are used to classify the lava into four textural types: 'glassy' obsidian (<. 15% vesicles), 'pumiceous' lava (>. 40% vesicles), high aspect ratio, 'shear banded' lava (20-40% vesicles) and lo…
Cooling and crystallization recorded in trachytic enclaves hosted in pantelleritic magmas (Pantelleria, Italy): Implications for pantellerite petroge…
2015
Abstract This study focuses on the comenditic trachyte enclaves hosted in pantelleritic lava and pumices emplaced during one of the most recent eruptive events at Pantelleria (~ 6 ka). Enclaves range from mm-sized fragments to dm-sized blocks with spheroidal to amoeboid shapes and characteristic globular surfaces; they are crystal-rich with ~ 30 vol% large anorthoclase, less abundant Fe-rich olivine, clinopyroxene and Fe–Ti oxides. Vesicles ranging from a few mm to 1–2 cm in size are distributed throughout the enclave and are commonly filled with microlite-free vesicular glass. The groundmass presents spectacular textures, including fine to coarse spherulites and hopper and skeletal microli…
Stratigraphic and structural relationships between Meso-Cenozoic Lagonegro basin and coeval carbonate platforms in southern Apennines, Italy
1999
Abstract Stratigraphic studies and facies analysis integrated with a new geological and structural survey of the Meso-Cenozoic units outcropping in the Campania–Lucania Apennines, southern Italy, allowed us to restore the palaeogeographic pattern and the tectonic evolution of the chain during Oligo-Miocene times. The southern Apennines are a N150°-striking and NE-verging fold-and-thrust belt mainly derived from the deformation of the African–Apulian passive margin. Four wide belts with different features have been recognized in the chain area. From east to west the following units outcrop: (a) successions characterized by basinal to marginal facies, ranging in age from Cretaceous to Miocene…
Tectono-sedimentary evolution of the Pliocene to Lower Pleistocene succession of the Apricena-Lesina-Poggio Imperiale quarrying district (western Gar…
2010
The post-Miocene marine succession of the «Apricena horst» is described with the purpose to verify the chronostratigraphic constraints for the type-locality of the Pirro Nord Faunal Unit. The stratigraphic succession has been subdivided in four units bounded by ubiquitous unconformities with evidence of subaerial exposure. The two basal units (dated late Zanclean to at most early Piacenzian) are formally grouped in the Lago di Varano Fm. that on the whole consists of sediments ranging from lagoonal to circalittoral environments. Within the lowermost unit, a megabreccia is interpreted as the product of a tsunami event. The third unit, Gelasian in age, is informally cited as Calcari a Briozoi…
Multifactorial control of sedimentation patterns in an ocean marginal basin: the Lusitanian Basin (Portugal) during the Kimmeridgian and Tithonian
1987
The Mesozoic Lusitanian Basin developed as a part of the North Atlantic rift system. Tectonic rifting activity was rejuvenated during the Upper Jurassic, leading to intensive differentiation of facies development. Kimmeridgian and Lower Tithonian calcareous and siliciclastic sediments represent basinal and slope, shallow marine, and terrestrial environments. The lithostratigraphic arrangement of facies units is demonstrated. Sediment character, distribution and thicknesses are mainly controlled by synsedimentary faulting, with a partial overprint by uprise of salt diapirs. Eustatic sea level fluctuations, exogenic and biogenic factors resulted in additional control on facies development.
Mass mortality or exceptional fossilization ? The case of the early and middle Toarcian fossiliferous beds from the Digne-Les-Bains area (southeaster…
2003
Abstract The latest Domerian to late Toarcian sedimentary series (from −190 Ma up to −180 Ma) from the « Réserve Géologique de Haute-Provence » (southeastern France) yields two kinds of remarkable fossiliferous beds. The greatest interest of the early Toarcian type is the occurrence of ichtyosaur remains (at least in six sites) among many other fossils such as ammonites, belemnites, bivalves, wood. The middle Toarcian type is specifically rich in ammonites and nautiluses. Litho- and biostratigraphical, palaeontological, sedimentological and geochemical analyses allow us to determine whether these fossiliferous beds are the results of mass mortalities, linked or not to biological crisis, o…