Search results for "Silver"
showing 10 items of 697 documents
Photochemical preparation of polyaminocyclodextrin-capped silver nanocomposites: mechanistic insights
2016
Photoreduction of silver salts in the presence of three polyaminocyclodextrin derivatives (AmCD, Figure 1) constitutes a simple and straightforward route to obtain stable Ag nanoparticles. These systems have been suitably characterized (UV-vis, FT-IR, TEM, Figure 2) and tested for their antimicrobial activity.1 We observed that Ag photoreduction is effectively induced by irradiation with green light (513 nm); however, best performances are achieved with the use of a light source having at the same time a significant emission in the near-infrared (NIR) region. On the grounds of analytical and kinetic evidences, we hypothesized a multi-step mechanism for nanoparticle formation. In particular,…
Convenient Photochemical Synthesis of Silver-Polyaminocyclodextrin Nanocomposites: The Role of the Light Source from a Mechanistic Viewpoint
2018
An investigation on the light-driven reduction of the [Ag(NH3)2]+complex in the presence of polyaminocyclodextrins was carried out, in order to clarify the mechanism of the process. The role of the organic auxiliary as both the sacrificial reductant and the capping agent was positively assessed. Moreover, particular attention was paid to the role of the irradiation source. Experimental results indicate that a complex mechanism is involved in the formation of the nanocomposite, with a primary photoinduced single-electron-transfer process promoted by irradiation with green light, followed by a secondary chemical reduction process activated by NIR. Representative composites were characterized …
Experimental dissociation energies of metal cluster dications and their interpretation in a liquid-drop model with empirical corrections
1999
The dissociation energies of doubly charged silver cluster ions in the size range $9l~nl~25$ are measured by multiple collision induced dissociation. They are compared to the dissociation energies of singly charged clusters. To this end, the latter are used to calculate shell corrections in a macroscopic-microscopic model. Good agreement between the resulting predictions of the dissociation energies of the doubly charged systems and the experimental values is found, which indicates the strong influence of electronic effects on the stability of small silver clusters.
Light trapping by plasmonic nanoparticles
2020
Abstract Metallic nanoparticles sustaining localized surface plasmon resonances are of great interest for enhancing light trapping in thin film photovoltaics. In this chapter, we explore the correlation between the structural and optical properties of self-assembled silver nanostructures fabricated by a solid-state dewetting process on various substrates relevant for silicon photovoltaics and later integrated into plasmonic back reflectors. Our study allows us to optimize the performance of nanostructures by identifying the fabrication conditions in which desirable circular and uniformly spaced nanoparticles are obtained. Second, we introduce a novel optoelectronic spectroscopic method that…
C3N4/reduced graphene oxide photocatalysts loaded with Ag or Ag/Pt for H2 evolution from aqueous solution of triethanolamine
2023
Composites of C3N4/reduced graphene oxide have been used as photocatalysts for triethanolamine photo- reforming with H2 generation in aqueous solution. The rate of H2 production over the Ag loaded best per- forming photocatalyst reached 525 μmol⋅h
NOR regions of polychaete worms of the genus Ophryotrocha studied by chromosome banding techniques and FISH.
2000
This article reports the results of cytogenetic analyses carried out on 10 species of polychaete worms belonging to the genus Ophryotrocha (Dorvilleidae). Nucleolar organizer regions (NORs) were characterized by Ag staining, C-banding, CMA3 staining, and ribosomal fluorescent in situ hybridization (rDNA FISH). Extensive intraspecific variation in NOR number and distribution were observed in O. costlowi, O. sp. macrovifera, O. notoglandulata, O.l. labronica, O. l. pacifica (2n = 6), O. p. puerilis, O. diadema (2n = 8), O. hartmanni, O. gracilis (2n = 10). In O. sp. robusta (2n = 10), Ag-NORs were always located on a single chromosome pair. CMA3 staining suggests a possible trend toward a GC-…
Supramolecular silver polyoxometalate architectures direct the growth of composite semiconducting nanostructures.
2009
Nanosilver on a string: Crystalline silver polyoxovanadate supramolecular architectures are employed as precursors for the synthesis of composite nanowires (see scheme). The nanostructures are composed of semiconducting vanadium oxide which forms wires with high aspect ratios, and are embedded with metallic silver nanoparticles. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
Phase behaviour of Ag2CrO4 under compression: Structural, vibrational, and optical properties
2013
We have performed an experimental study of the crystal structure, lattice dynamics, and optical properties of silver chromate (Ag2CrO4) at ambient temperature and high pressures. In particular, the crystal structure, Raman-active phonons, and electronic band gap have been accurately determined. When the initial orthorhombic Pnma Ag2CrO4 structure (phase I) is compressed up to 4.5 GPa, a previously undetected phase (phase II) has been observed with a 0.95% volume collapse. The structure of phase II can be indexed to a similar orthorhombic cell as phase I, and the transition can be considered to be an isostructural transition. This collapse is mainly due to the drastic contraction of the a ax…
Synthesis and characterization of new polyamino-cyclodextrin materials.
2011
With the aim of the synthesis of chemically modified cyclodextrins bearing polyamine pendant groups, potentially useful as capping agents for the preparation of nanosized metal systems or as auxiliaries for gene transfection, the reaction between the heptakis-(6-iodo)-(6-deoxy)-b-cyclodextrin and various polyamines has been explored. This synthetic approach allows obtaining materials constituted by mixtures of cyclodextrins, having different degrees of substitution, which were satisfactorily characterized by means of various complementary techniques (ESI-MS, NMR, potentiometric titration). The products obtained were successfully subjected to preliminary tests for their binding abilities tow…
Characterization of pre-treatments on wood chips prior to delignification by near infrared spectroscopy
2017
A near infrared (NIR) spectroscopy-based method for predicting yields and lignin contents of differently pre-treated silver/white birch (Betula pendula/B. pubescens) and Scots pine (Pinus sylvestris) chips was developed. The approach was to create multivariate calibration models from the NIR data by the partial least squares (PLS) method. Both parameters are important factors when adjusting adequate conditions for pre-treatments either with hot-water (HW) as such and slightly acidified HW (collectively referred to as autohydrolysis) or dilute alkaline aqueous solutions prior to alkaline pulping. Pre-treatment conditions were varied with respect to temperature (130 °C and 150 °C) and treatme…