Search results for "Single step"
showing 8 items of 18 documents
Cyclopentadienylmolybdenum(VI) and molybdenum(V) oxo chemistry: New synthetic and structural features
2002
International audience; Convenient syntheses for Cp, Cp*, and related cyclopentadienyl derivatives (4Cp = C5HiPr4; Cp′′′ = C5H2tBu3-1,2,4) of formula [(Ring)2Mo2O5] are described. Compound [Cp2Mo2O5] was produced in good yields by the rapid oxidation of red [CpMoO2]4 with PhIO in CH2Cl2. [Cp*2Mo2O5] was obtained by CH3COOH acidification of aqueous solutions of [Cp*MoO3]−Na+, the latter being generated in a single step from [Cp*MoCl4] and more than 5 equiv. of aqueous NaOH in air. Minor quantities of [Cp*MoO2]2 were also isolated from this reaction, although the formation of this by-product may be reduced by using a two-step basic hydrolysis procedure. Extension of the latter strategy also a…
Static output-feedback control for vehicle suspensions: a single-step linear matrix inequality approach
2013
In this paper, a new strategy to design static output-feedback controllers for a class of vehicle suspension systems is presented. A theoretical background on recent advances in output-feedback control is first provided, which makes possible an effective synthesis of static output-feedback controllers by solving a single linear matrix inequality optimization problem. Next, a simplified model of a quarter-car suspension system is proposed, taking the ride comfort, suspension stroke, road holding ability, and control effort as the main performance criteria in the vehicle suspension design. The new approach is then used to design a static output-feedbackH∞controller that only uses the suspensi…
Single-step link from yrast SD band in 143Eu
1997
A discrete γ-ray transition from the yrast SD band to the region of near-yrast discrete normal-deformed states has been identified in 143Eu. It has an energy of 3360.6 keV and an intensity corresponding to 3.2% of the full intensity of the SD band and feeds a nearly-spherical state above spin 352(+) and Ex=4947 keV. This agrees well with the picture of the decay out of the SD band gained previously from two-step links. The angular distribution analysis favours a stretched dipole character for the transition. Due to the complicated structure of the level scheme in the region of interest it has not been possible to place the transition exactly.
Statistical Characterization of Self-Assembled Colloidal Crystals by Single-Step Vertical Deposition
2014
Abstract We have statistically characterized the self-assembly of multi-layer polystyrene colloidal crystals, using the technique of vertical deposition, with parameters chosen to produce thick layers of self-assembled crystals in one deposition step. The size distribution of domains produced with this technique was seen to follow a log-normal distribution, hinting that aggregation or fragmentation phenomena play a role. In addition, using a lithographically directed self-assembly method, we have shown that the size of multi-layer, continuous crack-free domains in lithographically defined areas can be many times larger than in the surrounding areas. In a single deposition step, we have prod…
Dissociation energies of silver clusters Agn+, n=14, 15, 16, 18
2003
A recently developed method to determine dissociation energies has been applied to positively charged silver clusters of size n=14, 15, 16 and 18. The method uses a combination of sequential and single step decays. It requires an uncalibrated thermometer which here is provided by the evaporation rate constants of the product clusters. For this purpose, earlier measurements [J. Chem. Phys. 57 (1998) 2786] are reanalyzed with the new method. The resulting dissociation energies are compared with the liquid drop values and the measured decay rate constants with expected rate constants from detailed balance theory.
3D structural modeling and restoration of the Apennine-Maghrebian chain in Sicily: Application for non-cylindrical fold-and-thrust belts
2019
International audience; Thirteen seismic reflection profiles and field observations have been used to build a three-dimensional watertight geological model of the sub-surface architecture of the Trapanese carbonate platform unit of the Apennine-Maghrebian chain in the Mt. Kumeta and Mt. Rocca Busambra (NW Sicily, Italy). Either a single step or a two-step thrust-fault deformation model is acceptable on the basis of seismic interpretation but the integration of 3D model reconstruction and 3D geomechanical restoration, validates only the scenario with a single stage of deformation.The 3D model highlights along strike variations of the structural style for the Trapanese unit where pre-existing…
Manufacturing and characterization of single cell intermediate-temperature solid oxide fuel cells for APU in transportation application
2014
The fabrications of large area IT-SOFC planar cell by new simple and cost effective process were explained. The optimization of the new process with respect to pore formers, thickness of layers, sintering temperature were performed. The electrochemical results of 10cm2 performed in Fiaxell open flange set up were detailed with respect to different configuration. Long term ageing performance tests of single cells were conducted in Fiaxell device and results are discussed. Preparation of new test bench and stacking process performed till now were briefed.
ChemInform Abstract: Synthesis of Fluorinated Allylic Amines: Reaction of 2-(Trimethylsilyl)ethyl Sulfones and Sulfoxides with Fluorinated Imines.
2008
A new synthesis of fluorinated allylamines through the reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides (as vinyl anion equivalents) with imines and imino esters has been described. The process includes a TBAF-mediated fragmentation of 2-(trimethylsilyl)ethyl sulfones to afford the desired allylic amines. When the reaction is performed with the corresponding sulfoxides, the fragmentation takes place under the addition conditions, affording the final products in a single step.