Search results for "Sky"
showing 10 items of 1603 documents
Defining “National Treasures” in the European Union. Is the Sky Really the Limit?
2019
The main objective of this article is to analyse the scope of EU Member States’ right to determine national treasures for the purpose of Directive 2014/60/EU on the return of cultural objects. While investigating the issue at the EU, human rights, and constitutional levels, the authors argue that the right to define what constitutes national treasures is not an absolute right. The definition of this particular category of cultural objects cannot be used to circumvent the rules on the free movement of goods and to hamper this freedom in an unjustifiable and arbitrary manner. On the human rights and constitutional levels, Member States’ right cannot interfere with the right to enjoy one’s pos…
Relationship between lower limb neuromuscular performance and bone strength in postmenopausal women with mild knee osteoarthritis.
2014
Objectives: To investigate whether neuromuscular performance predicts lower limb bone strength in different lower limb sites in postmenopausal women with mild knee osteoarthritis (OA). Methods: Neuromuscular performance of 139 volunteer women aged 50-68 with mild knee OA was measured using maximal counter movement jump test, isometric knee flexion and extension force and figure-of-eight-running test. Femoral neck section modulus (Z, mm³) was determined by data obtained from dualenergy X-ray absorptiometry. Data obtained using peripheral quantitative computed tomography was used to asses distal tibia compressive (BSId, g2/cm4) and tibial mid-shaft bending (SSImaxmid, mm3) strength indices. R…
The 2020 skyrmionics roadmap
2020
The notion of non-trivial topological winding in condensed matter systems represents a major area of present-day theoretical and experimental research. Magnetic materials offer a versatile platform that is particularly amenable for the exploration of topological spin solitons in real space such as skyrmions. First identified in non-centrosymmetric bulk materials, the rapidly growing zoology of materials systems hosting skyrmions and related topological spin solitons includes bulk compounds, surfaces, thin films, heterostructures, nano-wires and nano-dots. This underscores an exceptional potential for major breakthroughs ranging from fundamental questions to applications as driven by an inte…
Global Atmospheric Profiles from Reanalysis Information (GAPRI): a new database for earth surface temperature retrieval
2015
This paper presents the Global Atmospheric Profiles derived from Reanalysis Information GAPRI database, which was designed for earth surface temperature retrieval. GAPRI is a comprehensive compilation of selected atmospheric vertical profiles at global scale which can be used for radiative transfer simulation in order to obtain generalized algorithms to estimate land surface temperature LST. GAPRI includes information on geopotential height, atmospheric pressure, air temperature, and relative humidity derived from the European Centre for Medium-Range Weather Forecasts Re-Analysis data from year 2011. The atmospheric profiles are structured for 29 vertical levels and extracted from a global …
On the relationship between the sky view factor and the land surface temperature derived by Landsat-8 images in Bari, Italy
2015
This study investigates the impact of landscape composition and urban morphology on land surface temperature LST in the city of Bari, Italy. For this purpose, correlation between sky view factor SVF and LST was done assigning weights to the output results and moreover expressing the latter according to the four main surface classes of the Corine land cover CLC classification method. To do this, several daytime Landsat 8 and night-time Landsat 7 ETM+ images acquired during different months of the year were used to retrieve LST by using the radiative transfer equation. The results show a positive relationship between LST and SVF, and this trend is emphasized particularly in the more dense urb…
Development of a general model to estimate the instantaneous, daily, and daytime net radiation with satellite data on clear-sky days
2015
Net radiation is a key variable in computing evapotranspiration and is a driving force in many other physical and biological processes. Remote sensing techniques provide an unparalleled spatial and temporal coverage of land-surface attributes, and thus several studies have attempted to estimate net radiation by combining remote sensing observations with surface and atmospheric data. However, remote sensing provides instantaneous data, when many applications and models need information at other temporal scales. In this work, a new general methodology is proposed to estimate daily and daytime net radiation and to retrieve the diurnal cycle of net radiation. Four images were acquired on differ…
Cholesky decomposition-based definition of atomic subsystems in electronic structure calculations
2010
Decomposing the Hartree-Fock one-electron density matrix and a virtual pseudodensity matrix, we obtain an orthogonal set of normalized molecular orbitals with local character to be used in post-Hartree-Fock calculations. The applicability of the procedure is illustrated by calculating CCSD(T) energies and CCSD molecular properties in reduced active spaces. © 2010 American Institute of Physics.
Multi-level coupled cluster theory
2014
We present a general formalism where different levels of coupled cluster theory can be applied to different parts of the molecular system. The system is partitioned into subsystems by Cholesky decomposition of the one-electron Hartree-Fock density matrix. In this way the system can be divided across chemical bonds without discontinuities arising. The coupled cluster wave function is defined in terms of cluster operators for each part and these are determined from a set of coupled equations. The total wave function fulfills the Pauli-principle across all borders and levels of electron correlation. We develop the associated response theory for this multi-level coupled cluster theory and prese…
Fast noniterative orbital localization for large molecules
2006
We use Cholesky decomposition of the density matrix in atomic orbital basis to define a new set of occupied molecular orbital coefficients. Analysis of the resulting orbitals ("Cholesky molecular orbitals") demonstrates their localized character inherited from the sparsity of the density matrix. Comparison with the results of traditional iterative localization schemes shows minor differences with respect to a number of suitable measures of locality, particularly the scaling with system size of orbital pair domains used in local correlation methods. The Cholesky procedure for generating orthonormal localized orbitals is noniterative and may be made linear scaling. Although our present implem…
The catalytic effects of a thiazolium salt in the oxa-Diels–Alder reaction between benzaldehyde and Danishefsky's diene: a molecular electron density…
2021
The oxa-Diels–Alder (ODA) reaction of benzaldehyde with Danishefsky's diene in the presence of a [thiazolium][Cl] salt, as a model of an ionic liquid, has been studied within Molecular Electron Density Theory (MEDT) at the M06-2X/6-311G(d,p) computational level. The formation of two hydrogen bonds (HBs) between the thiazolium cation and the carbonyl oxygen of benzaldehyde modifies neither the electrophilic character of benzaldehyde nor its electronic structure substantially but accelerates the reaction considerably. This ODA reaction presents an activation energy of 4.5 kcal mol−1; the formation of the only observed dihydropyranone is strongly exothermic by −28.8 kcal mol−1. The presence of…