Search results for "Solar cells"
showing 10 items of 178 documents
Fabrication and Photoelectrochemical Behavior of Ordered CIGS Nanowire Arrays for Application in Solar Cells
2010
In this work, we report some preliminary results concerning the fabrication of quaternary copper, indium, gallium, and selenium CIGS nanowires that were grown inside the channels of an anodic alumina membrane by one-step potentiostatic deposition at different applied potentials and room temperature. A tunable nanowire composition was achieved through a manipulation of the applied potential and electrolyte composition. X-ray diffraction analysis showed that nanowires, whose chemical composition was determined by energy-dispersive spectroscopy analysis, were amorphous. A composition of Cu0.203In0.153Ga0.131Se0.513, very close to the stoichiometric value, was obtained. These nanostructures wer…
Optical Optimization of the TiO2 Mesoporous Layer in Perovskite Solar Cells by the Addition of SiO2 Nanoparticles
2018
In this work, SiO2 nanoparticles (NPs) were integrated into the mesoporous TiO2 layer of a perovskite solar cell to investigate their effect on cell performance. Different concentrations of SiO2/ethanol have been combined in TiO2/ethanol to prepare pastes for the fabrication of the mesoporous layer with which perovskite solar cells have been fabricated. Addition of SiO2 NPs of 50 and 100 nm sizes produces an enhancement of cell performance mainly because of an improvement of the photocurrent. This increment is in good agreement with the theoretical predictions based on light scattering induced by dielectric SiO2 NPs. The samples using modified scaffolds with NPs also present a significant l…
Advances in Perovskite Solar Cells.
2015
Organolead halide perovskite materials possess a combination of remarkable optoelectronic properties, such as steep optical absorption edge and high absorption coefficients, long charge carrier diffusion lengths and lifetimes. Taken together with the ability for low temperature preparation, also from solution, perovskite-based devices, especially photovoltaic (PV) cells have been studied intensively, with remarkable progress in performance, over the past few years. The combination of high efficiency, low cost and additional (non-PV) applications provides great potential for commercialization. Performance and applications of perovskite solar cells often correlate with their device structures…
Online Meetings in Times of Global Crisis: Toward Sustainable Conferencing
2020
International conferences are an essential component of the timely exchange of ideas and results in the scientific community, where scientists present their results, gain new insights, and meet colleagues and collaborators. In early 2020, a global pandemic caused by a coronavirus (SARS-CoV-2) and the corresponding disease (covid-19) resulted in a number of conferences being canceled or postponed. (1) To foster scientific exchange despite the restrictions, a range of initiatives were launched across the globe to move international conferences online. (2−8) [...]
Enhanced efficiency in plastic planar heterojunction solar cells by AuNPs positioned at donor-acceptor interfaces
2018
A new class of copolymers containing oligothiophene moieties with different length and fullerene units have been designed and prepared by an easy and inexpensive one-step synthetic approach. The incorporation of small quantities of these copolymers into bulk heterojunction (BHJ) solar cells with donor regioregular polythiophene (P3HT) and acceptor fullerene derivate (PCBM) results in a good control of the phase separation process without further affecting the BHJ optoelectronic properties. Indeed, these copolymers allow modulating under thermal annealing the growth of domains whose size depends on the length of the copolymer repetitive units. Domain size on the same length scale of the P3HT…
Fluorescence Quenching in Hybrid Solar Cells Based on Electrodeposited ZnO
2013
A study about fluorescence phenomena in hybrid donor-acceptor interfaces based on electrodeposited zinc oxide (e-ZnO) having different architectures is performed. In particular ITO/ZnO/P3HT and ITO/ZnO/P3HT:PCBM are investigated and their photoluminescence responses are compared with those of ITO/P3HT and ITO/P3HT:PCBM. As expected, ITO/ZnO/P3HT:PCBM and ITO/P3HT:PCBM present higher exciton quenching than ITO/ZnO/P3HT and ITO/P3HT respectively. Furthermore, the hybrid configuration ITO/ZnO/P3HT:PCBM displays a higher quenching percentage in a wider wavelength range than ITO/P3HT:PCBM, indicating a better photo-induced charge separation in e-ZnO based hybrid devices.
Integrazione di celle solari di terza generazione nel vetromattone per la realizzazione di pannelli traslucidi fotovoltaici. Analisi prestazione e st…
2013
L’articolo illustra i primi risultati ottenuti nell’ambito dell’analisi prestazionale del vetromattone fotovoltaico, un prodotto edilizio innovativo derivato dall’integrazione di celle fotovoltaiche di terza generazione (DSSC) nel vetromattone, ideato per la realizzazione di involucri traslucidi energeticamente effi cienti ed “attivi”, in grado di ridurre i consumi energetici degli edifi ci e di produrre, al contempo, energia verde. L’analisi è stata condotta su quattro differenti ipotesi di integrazione. Attraverso simulazioni numeriche si è effettuata una valutazione dell’energia assorbita dagli strati attivi oltre che delle prestazioni ottiche complessive del dispositivo. Lo studio anali…
Intriguing Photochemistry of the Additives in the Dye-Sensitized Solar Cells
2016
Over the years numerous mixes of chemical compounds have been tried in the electrolytes of dye-sensitized solar cells in efforts to improve their efficiency. How these chemicals interact with each other and the photoelectrode has received surprisingly little attention. Here we report results from a systematic study of two I–/I3– electrolytes and their additives using infrared and Raman spectroscopy together with quantum chemical calculations. In the LiI electrolyte competing interactions between lithium cation and the solvent MPN and the additives TBP, NMBI, and GuSCN were identified. These interactions could inhibit the interaction of lithium ions with the TiO2 surface. It was found that u…
Fabrication and electro-optical characterization of Ruthenium-based Dye-Sensitized Solar Cells
2015
In this paper, we measure the main photoelectrical parameters of Dye Sensitized Solar Cells (DSSCs) based on ruthenium complexes at different irradiance levels, incident wavelengths, temperatures and hours of light soaking
Experimental characterization of Ruthenium-based Dye Sensitized Solar Cells and study of light-soaking effect impact on performance
2016
In this paper, we present an experimental investigation on the performance of Ruthenium-based Dye Sensitized Solar Cells (DSSCs) at different irradiance levels, incident wavelengths and hours of illumination. In particular, the measurements have been aimed at studying the performance variation due to light soaking effect since this phenomenon has noteworthy practical implications, such as stability tests of DSSCs. Our results show that the short circuit current density, the open circuit voltage and the conversion efficiency η increase with the hours of light soaking. Finally, the observed phenomenon is reversible, and thus the performance decreases again when the cell is kept in the dark.