Search results for "Solid-state"
showing 10 items of 530 documents
Factors Influencing Bonding Mechanics in FSW of AA5754
2011
Solid state bonding recurs in several manufacturing processes, as extrusion of hollow profiles and solid welding processes. Among the latter, Friction Stir Welding (FSW) is nowadays of particular industrial interest because of the specific advantages with respect to the classic welding technologies. Proper conditions of pressure, temperature, strain and strain rate are needed in order to get the final effective bonding. In the paper the authors compare different solid state bonding conditions obtained at the varying of the main process parameters in FSW of butt joints of AA5754 aluminum alloys. The experimental results are compared with the numerical ones from a FEM model previously develop…
Multi-gigahertz repetition-rate-selectable passive harmonic mode locking of a fiber laser
2013
We demonstrate a passive harmonically mode-locked erbium-doped fiber laser that operates at selectable harmonics spanning from the 6th to the 928th, which corresponds to repetition rates ranging from 153 MHz to 22.2 GHz. The noteworthy laser output stability is attested by supermode suppression levels as large as 41 dB. The influence of a continuous wave background on harmonics stability is tested.
Ion production from solid state laser ion sources.
2010
Laser ion sources based on resonant excitation and ionization of atoms are well-established tools for selective and efficient production of radioactive ion beams. Recent developments are focused on the use of the state-of-the-art all solid-state laser systems. To date, 35 elements of the periodic table are available from laser ion sources based on tunable Ti:sapphire lasers. Recent progress in this field regarding the establishment of suitable optical excitation schemes for Ti:sapphire lasers are reported.
A new fixture for FSW processes of titanium alloys
2010
FSW of titanium alloys is nowadays one of the most challenging welding operations, even with a solid state process, due to the thermo-mechanical and thermo-chemical characteristics of such materials. Due to the relevant application of titanium alloys in the aeronautic and aerospace industries, in the recent years few attempts were carried out to develop FSW processes aimed to maximize the mechanical performances of the welded parts. In the paper a new fixture is presented allowing obtaining effective FSW joints of titanium blanks, which were investigated through mechanical and metallurgical tests highlighting the peculiarities of FSW of titanium alloys.
Grain growth in Na 0.5 Bi 0.5 TiO 3 -based solid solutions
2019
This paper discusses effects of different dopants, sintering technique and parameters on microstructure and properties of pure and Yb, Er-doped Na0.5Bi0.5TiO3 (NBT). All stoichiometric compositions follow the abnormal grain growth mechanism (AGG) and exhibit a bimodal grain size distribution. Bi over-stoichiometry, two step sintering and hot pressing are effective inhibitors of AGG. Microstructure of sintered NBT greatly influences such properties as dielectric permittivity and depolarization temperature.
Solid state NMR analysis of peptides in membranes: Influence of dynamics and labeling scheme.
2010
The functional state of a membrane-active peptide is often defined by its conformation, molecular orientation, and its oligomeric state in the lipid bilayer. These "static" structural properties can be routinely studied by solid state NMR using isotope-labeled peptides. In the highly dynamic environment of a liquid crystalline biomembrane, however, the whole-body fluctuations of a peptide are also of paramount importance, although difficult to address and most often ignored. Yet it turns out that disregarding such motional averaging in calculating the molecular alignment from orientational NMR-constraints may give a misleading, if not false picture of the system. Here, we demonstrate that t…
Crystallization, spectral, crystallographical, and thermoanalytical studies of succinobucol polymorphism.
2011
Four different polymorphs, A, C, D, and E, of succinobucol were isolated and characterized by means of solid-state nuclear magnetic resonance spectroscopy, single crystal and powder X-ray diffraction, differential scanning calorimetry, thermogravimetry, and attenuated total reflection–infrared spectroscopy. From a number of experiments, the same polymorphs (C, D, and E) and an equilibrium phase mixture B consisting of polymorphs C and D were repeatedly gained using different solvents or their mixtures. Although polymorph A was obtained directly from recrystallization only on few occasions, polymorphs C, D, and E proved to be metastable kinetic polymorphs, which slowly transform to a thermod…
Hydrogen-bond-mediated self-assembly of 26-membered diaza tetraester crowns of 3,5-disubstituted 1 h -pyrazole. Dimerization study in the solid state…
2011
By using an improved synthetic method reported earlier, the cyclic stannoxanes obtained from RN-diethanolamine (R = Me, Bu) and dibutyltin oxide have been reacted with 1H-pyrazole-3,5-dicarbonyl dichloride to afford 26-membered diaza tetraester crowns (1, R = Me; 3, R = Bu) and 39-membered triaza hexaester crowns (2, R = Me; 4, R = Bu). The new structures were identified from their analytical and spectroscopic (1H and 13C NMR, FAB-MS, and/or ESI-MS) data. Both diaza tetraester crowns (1 and 3), containing two 1H-pyrazole units, self-assemble into dimeric species through the formation of four hydrogen bonds involving the two NH pyrazole groups and the two tertiary amine groups of both crowns…
Solid-state NMR and computational investigation of solvent molecule arrangement and dynamics in isostructural solvates of droperidol.
2015
(13)C, (15)N and (2)H solid-state NMR spectroscopy have been used to rationalize arrangement and dynamics of solvent molecules in a set of isostructural solvates of droperidol. The solvent molecules are determined to be dynamically disordered in the methanol and ethanol solvates, while they are ordered in the acetonitrile and nitromethane solvates. (2)H NMR spectra of deuterium-labelled samples allowed the characterization of the solvent molecule dynamics in the alcohol solvates and the non-stoichiometric hydrate. The likely motion of the alcohol molecules is rapid libration within a site, plus occasional exchange into an equivalent site related by the inversion symmetry, while the water mo…
Identifying three-way DNA junction-specific small-molecules
2012
Three-way junction DNA (TWJ-DNA, also known as 3WJ-DNA) is an alternative secondary DNA structure comprised of three duplex-DNAs that converge towards a single point, termed the branch point. This point is characterized by unique geometrical properties that make its specific targeting by synthetic small-molecules possible. Such a targeting has already been demonstrated in the solid state but not thoroughly biophysically investigated in solution. Herein, a set of simple biophysical assays has been developed to identify TWJ-specific small-molecule ligands; these assays, inspired by the considerable body of work that has been reported to characterize the interactions between small-molecules an…