Search results for "Solid-state"
showing 10 items of 530 documents
Magnetic breakdown and charge density wave formation: a quantum oscillation study of the rare-earth tritellurides
2020
The rare-earth tritellurides ($R$Te$_3$, where $R$ = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Y) form a charge density wave state consisting of a single unidirectional charge density wave for lighter $R$, with a second unidirectional charge density wave, perpendicular and in addition to the first, also present at low temperatures for heavier $R$. We present a quantum oscillation study in magnetic fields up to 65T that compares the single charge density wave state with the double charge density wave state both above and below the magnetic breakdown field of the second charge density wave. In the double charge density wave state it is observed that there remain several small, light pockets…
Magnetic-field-induced reentrance of Fermi-liquid behavior and spin-lattice relaxation rates in
2009
Abstract A strong departure from Landau–Fermi liquid (LFL) behavior have been recently revealed in observed anomalies in both the magnetic susceptibility χ and the muon and 63Cu nuclear spin-lattice relaxation rates 1 / T 1 of YbCu 5 − x Au x ( x = 0.6 ). We show that the above anomalies along with magnetic-field-induced reentrance of LFL properties are indeed determined by the dependence of the quasiparticle effective mass M ∗ on magnetic field B and temperature T and demonstrate that violations of the Korringa law also come from M ∗ ( B , T ) dependence. We obtain this dependence theoretically utilizing our approach based on fermion condensation quantum phase transition (FCQPT) notion. Ou…
Energy scales and magnetoresistance at a quantum critical point
2009
The magnetoresistance (MR) of CeCoIn_5 is notably different from that in many conventional metals. We show that a pronounced crossover from negative to positive MR at elevated temperatures and fixed magnetic fields is determined by the scaling behavior of quasiparticle effective mass. At a quantum critical point (QCP) this dependence generates kinks (crossover points from fast to slow growth) in thermodynamic characteristics (like specific heat, magnetization etc) at some temperatures when a strongly correlated electron system transits from the magnetic field induced Landau Fermi liquid (LFL) regime to the non-Fermi liquid (NFL) one taking place at rising temperatures. We show that the abov…
Fermi Liquid with Fermion Condensate
2014
Here we discuss the general properties of FCQPT leading to the emergence of FC. We present a microscopic derivation of the main equations of FC, and show that Fermi systems with FC form an entirely new class of Fermi liquids with its own topological structure, protecting the FC state. We construct the phase diagram, and explore the order parameter of these systems. We show that the fermion condensate has a strong impact on the observable physical properties of systems, where it is realized, up to relatively high temperatures of a few tens kelvin. Two different scenarios of the quantum critical point (QCP), a zero-temperature instability of the Landau state, related to the divergence of the …
Stability of dark matter from the D4×Z2f flavor group
2011
Abstract We study a model based on the dihedral group D 4 in which the dark matter is stabilized by the interplay between a remnant Z 2 symmetry, of the same spontaneously broken non-abelian group, and an auxiliary Z 2 f introduced to eliminate unwanted couplings in the scalar potential. In the lepton sector the model is compatible with normal hierarchy only and predicts a vanishing reactor mixing angle, θ 13 = 0 . Since m ν 1 = 0 , we also have a simple prediction for the effective mass in terms of the solar angle: | m β β | = | m ν 2 | sin 2 θ ⊙ ∼ 10 − 3 eV . There also exists a large portion of the model parameter space where the upper bounds on lepton flavor violating processes are not …
Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning
2015
Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design. Herein, we unambiguously show that one of these characteristic features, namely high directionality, renders halogen bonding the interaction of choice when developing azobenzene-containing supramolecular polymers for light-induced surface patterning. The study is conducted by using an extensive library of azobenzene molecules that differ only in terms of the bond-donor unit. We introduce a new tetrafluorophenol-containing azobenzene photoswitch capable of forming strong hydrogen bonds, and show that an io…
Structural investigation of e-beam cured epoxy resins through solid state NMR
2012
Abstract In this paper the network structure of e-beam cured DGEBF based epoxy resins is investigated. Two epoxy systems, having different reactivity and cured in different process conditions, were analyzed through solid state NMR spectroscopy. The analysis shows that the more reactive system has higher cross-linking density and higher uniformity of network distribution. Similar information were obtained, in a previous work, on the same systems through dynamic mechanical thermal analysis. It is worth noting that unlike DMTA tests, which interfere with the molecular structure of the analyzed material, due to the heating during the analysis itself, more reliable information, without any artef…
Billion-Fold Enhancement in Sensitivity of Nuclear Magnetic Resonance Spectroscopy for Magnesium Ions in Solution
2014
Beta-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. Beta-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. In this work, beta-NMR is applied, for the first time, to record an NMR spectrum for a species in solution. 31Mg b-NMR spectra are measured for as few as 10^7 magnesium ions in ionic liquid (EMIM-Ac) within minutes, as a prototypical test case. Resonances are observed at 3882.9 and 3887.2 kHz in an external field of 0.3 T. The key achievement of the current work is to demonstrate that beta-NMR is applicable for the…
Structural properties of the range-II- and range-III order in amorphous-SiO2 probed by electron paramagnetic resonance and Raman spectroscopy
2010
In the present work we report an experimental investigation by electron paramagnetic resonance spectroscopy on the hyperfine structure of the E. point defect, probing the local arrangement of the network (range-II order), and by Raman spectroscopy on the D 1 and D 2 lines, probing mean features of the network (range-III order). Our studies, performed on a-SiO 2 samples thermally treated at 1000 °C in air for different time durations, show that changes of the hyperfine structure and of the D 1 and D 2 lines occur in a correlated way. These results give strong evidence that the range-II and range-III order properties are intimately related to each other and that these properties are determine…
Hydrogen-bonded liquid crystals with broad-range blue phases
2019
We report a modular supramolecular approach for the investigation of chirality induction in hydrogen-bonded liquid crystals. An exceptionally broad blue phase with a temperature range of 25 °C was found, which enabled its structural investigation by solid state 19F-NMR studies and allowed us to report order parameters of the blue phase I for the first time.