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RESEARCH PRODUCT
Billion-Fold Enhancement in Sensitivity of Nuclear Magnetic Resonance Spectroscopy for Magnesium Ions in Solution
A. GottbergPeter W. ThulstrupKlaus BlaumMark BissellMonika StachuraMonika StachuraLars HemmingsenAlexander HelmkeK. KreimKarl JohnstonMagdalena KowalskaGerda NeyensDeyan T. YordanovRonald Fernando Garcia RuizDániel SzunyoghRainer NeugartFlemming H. LarsenVaida Arcisauskaitesubject
RadioisotopesMagnetic Resonance SpectroscopyChemistryCarbon-13 NMR satelliteIonic liquid (EMIM-Ac)Analytical chemistryIonic Liquids31MgNuclear magnetic resonance spectroscopyFluorine-19 NMRNuclear magnetic resonance crystallographyCarbon-13 NMRAtomic and Molecular Physics and OpticsSolutionsnucelar magnetci resonanceSolid-state nuclear magnetic resonanceMagnesiumPräzisionsexperimente - Abteilung BlaumPhysical and Theoretical ChemistryTwo-dimensional nuclear magnetic resonance spectroscopyEarth's field NMRdescription
Beta-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. Beta-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. In this work, beta-NMR is applied, for the first time, to record an NMR spectrum for a species in solution. 31Mg b-NMR spectra are measured for as few as 10^7 magnesium ions in ionic liquid (EMIM-Ac) within minutes, as a prototypical test case. Resonances are observed at 3882.9 and 3887.2 kHz in an external field of 0.3 T. The key achievement of the current work is to demonstrate that beta-NMR is applicable for the analysis of species in solution, and thus represents a novel spectroscopic technique for use in general chemistry and potentially in biochemistry. ispartof: ChemPhysChem vol:15 issue:18 pages:3929-3932 ispartof: location:Germany status: published
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-10-09 |