Search results for "Solid"

Structural organization of silanol and silicon hydride groups in the amorphous silicon dioxide network

2011

We present a study on the effects of an isothermal annealing treatment on a-SiO 2 having a significant content of silanol hydride groups (Si-H). We examined the properties of the IR absorption bands of silanol (Si-OH) and silicon hydride groups as a function of the duration of the thermal treatment. We showed that the Si-OH and Si-H groups contents decrease in a linearly correlated way. The annealing dynamics suggest that the two species are close to each other in the amorphous network. We showed that the profile of the silanol groups absorption band is the same as that observed in other commercial a-SiO 2 materials, irrespectively of the concomitant presence of nearby Si-H groups, and, mor…

Ferulic Acid-Loaded Lipid Nanostructures as Drug Delivery Systems for Alzheimers Disease: Preparation, Characterization and Cytotoxicity Studies

2009

Grain growth in Na 0.5 Bi 0.5 TiO 3 -based solid solutions

2019

This paper discusses effects of different dopants, sintering technique and parameters on microstructure and properties of pure and Yb, Er-doped Na0.5Bi0.5TiO3 (NBT). All stoichiometric compositions follow the abnormal grain growth mechanism (AGG) and exhibit a bimodal grain size distribution. Bi over-stoichiometry, two step sintering and hot pressing are effective inhibitors of AGG. Microstructure of sintered NBT greatly influences such properties as dielectric permittivity and depolarization temperature.

Influence of titanium-substrate roughness on Ca–P–O thin films grown by atomic layer deposition

2013

Abstract Amorphous Ca–P–O films were deposited on titanium substrates using atomic layer deposition, while maintaining a uniform Ca/P pulsing ratio of 6/1 with varying number of atomic layer deposition cycles starting from 10 up to 208. Prior to film deposition the titanium substrates were mechanically abraded using SiC abrasive paper of 600, 1200, 2000 grit size and polished with 3 μm diamond paste to obtain surface roughness R rms values of 0.31 μm, 0.26 μm, 0.16 μm, and 0.10 μm, respectively. The composition and film thickness of as-deposited amorphous films were studied using Time-Of-Flight Elastic Recoil Detection Analysis. The results showed that uniform films could be deposited on ro…

Structure and dynamics in amorphous tellurium and Te-n clusters: A density functional study

2012

Density functional/molecular dynamics simulations have been performed on amorphous tellurium (a melt-quenched sample of 343 atoms at 300 K) and on Te clusters with up to 16 atoms. The former extend our calculations on liquid Te at 560, 625, 722, and 970 K [Phys. Rev. B 81, 094202 (2010)]. We discuss trends in structures (including those of other group-16 elements), electronic densities of states, and vibration frequencies. Chain structures are common in S and Se, but the chains in amorphous Te are short, and branching sites with threefold-coordinated atoms are common. The energy difference between two- and threefold local coordination depends sensitively on the exchange-correlation function…

Atomic force microscopy and Raman investigation on the sintering process of amorphous SiO2 nanoparticles

2010

We report an experimental investigation on the sintering process induced in fumed silica powders by isochronal thermal treatments at T=1270 K. Three types of fumed silica are considered, consisting of amorphous SiO2 (a-SiO2) particles with mean diameters 7, 14, and 40 nm. The study is performed by atomic force microscopy (AFM), to follow the morphological changes, and by Raman scattering, to obtain information on the concomitant structural modifications. The former method indicates that the sintering process proceeds by aggregation of single particles into larger grains, whose sizes increase with the thermal treatment duration. Furthermore, for each fumed silica type considered, the quantit…

A star product on the spherical harmonics

1996

We explicitly define a star product on the spherical harmonics using the Moyal star product on ℝ6, and a polarization equation allowing its restriction on S2.

Spherical Harmonics Expansion of Fundamental Solutions and Their Derivatives for Homogeneous Elliptic Operators

2017

In this work, a unified scheme for computing the fundamental solutions of a three-dimensional homogeneous elliptic partial differential operator is presented. The scheme is based on the Rayleigh expansion and on the Fourier representation of a homogeneous function. The scheme has the advantage of expressing the fundamental solutions and their derivatives up to the desired order without any term-by-term differentiation. Moreover, the coefficients of the series need to be computed only once, thus making the presented scheme attractive for numerical implementation. The scheme is employed to compute the fundamental solution of isotropic elasticity showing that the spherical harmonics expansion…

Evaluation of a Multidimensional Solid-Phase Extraction Platform for Highly Selective On-Line Cleanup and High-Throughput LC−MS Analysis of Triazines…

2001

A novel highly selective sample cleanup procedure based on the use of molecularly imprinted polymers (MIPs) as solid-phase extraction materials has been evaluated with respect to its applicability and routine use in environmental analysis. The method comprises the combination of a restricted access material (RAM) and a MIP allowing a selective sample preparation to be achieved in the online mode. This combination is called the size-selective sample separation and solvent switch (six-SPE). The RAM column combines size exclusion and adsorption chromatography, reducing the concentration of matrix molecules by a cutoff of 15 kDa. The MIP column selectively retains the triazine analytes whereas …

Solid phase techniques in the extraction of pesticides and related compounds from foods and soils

1994

The application of SPE technology to the isolation of pesticides and related compounds from food and soils has grown enormously in the last decade. Much of this growth has been due to the relative ease of sample handling and the wide range of solid supports currently available for a variety of applications. The aim of this review is to present the methods for solid phase extraction (SPE) of pesticide residues from soils and foods. There are three main areas according to the type of approach used to handle the sample: solid phase extraction, solid phase clean-up (SPC), and matrix solid phase dispersion (MSPD). This review covers milk products, fatty foods, fruits, vegetables, and soils. Soli…