Search results for "Solid"
showing 10 items of 3575 documents
Flash microwave synthesis and sintering of nanosized La0.75Sr0.25Cr0.93Ru0.07o3–δ for fuel cell application.
2009
International audience; Perovskite-oxide nanocrystals of La0.75Sr0.25Cr0.93Ru0.07O3–δ with a mean size around 10 nm were prepared by microwave flash synthesis. This reaction was performed in alcoholic solution using metallic salts, sodium ethoxide and microwave autoclave. The obtained powder was characterised after purification by energy dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), BET adsorption technique, photon correlation spectroscopy (PCS) and transmission electron microscopy (TEM). The results show that integrated perovskite-type phase and uniform particle size were obtained in the microwave treated samples. At last the synthesised powder was directly used in a sin…
Monitoring a Mechanochemical Reaction Reveals the Formation of a New ACC Defect Variant Containing the HCO 3 – Anion Encapsulated by an Amorphous Mat…
2020
Crystal growth & design 20(10), 6831 - 6846 (2020). doi:10.1021/acs.cgd.0c00912
Polarization angle dependence of the breathing modes in confined one-dimensional dipolar bosons
2021
Probing the radial collective oscillation of a trapped quantum system is an accurate experimental tool to investigate interactions and dimensionality effects. We consider a fully polarized quasi-one dimensional dipolar quantum gas of bosonic dysprosium atoms in a parabolic trap at zero temperature. We model the dipolar gas with an effective quasi-one dimensional Hamiltonian in the single-mode approximation, and derive the equation of state using a variational approximation based on the Lieb-Liniger gas Bethe Ansatz wavefunction or perturbation theory. We calculate the breathing mode frequencies while varying polarization angles by a sum-rule approach, and find them in good agreement with re…
Méthodes de lagrangien et de Nitsche pour l'approximation numérique des conditions de contact avec frottement
2021
L'objectif de ce chapitre est de faire une présentation détaillée de développements récents sur l'approximation des conditions de contact des solides déformables en petites et grandes déformations. Les principes de base des méthodes de lagrangien, lagrangien augmenté, lagrangien stabilisé, de pénalité et de Nitsche sont exposés. Les liens étroits existants entre la méthode de Nitsche, le lagrangien stabilisé et le lagrangien augmenté sont alors analysés.
Modélisation numérique avec apport de matière du soudo-brasage des assemblages hétérogènes acier/aluminium
2007
This study deals with the numerical simulation of heterogeneous brazing of steel / aluminium alloy sheets by CMT process. The difference between the linear expansion coefficients of these materials generates high deformations and residual stress. The addiction of brazing material is simulated. A validation the model is made in the simplest case of a sheet of aluminium alloy with a brazing bead. Comparisons are made between numerical and experimental results on out-of-plane displacements of steel / aluminium assembly.
Mécanique du Solide (Cours, exercices et problèmes corrigés)
2001
Propagation non-linéaire d'impulsions femtosecondes dans une fibre optique à bande interdite à cœur solide
2009
National audience; Nous décrivons une étude expérimentale et numérique de l'évolution non-linéaire d'impulsions ultrabrèves se propageant dans une fibre optique à bande interdite à coeur solide. Suivant le mécanisme de guidage employé, des dynamiques significativement différentes sont mises en évidence.
Towards enhanced durability of electrochromic WO3 interfaced with liquid or ceramic sodium-based electrolytes
2020
Abstract The reversible intercalation of sodium ion into tungsten oxide WO3 appears as an interesting alternative to hydrogen or lithium ion reduction in order to get the characteristic transition from clear transparent to bluish coloration in electrochromic devices, but it has been comparatively less considered. In order to address further viable all-ceramic devices based on sodium ion intercalation and overcome the issue of WO3 degradation in aqueous media, three configurations of WO3 thin film-based electrochromic half-cells were tested, namely in (i) aqueous acidified Na2SO4 electrolyte, (ii) room temperature ionic liquid BEPipTFSI electrolyte and (iii) aqueous acidified Na2SO4 electrol…
Morphological and chemical dynamics upon electrochemical cyclic sodiation of electrochromic tungsten oxide coatings extracted by in situ ellipsometry.
2020
The sodiation–desodiation process of sputtered amorphous electrochromic tungsten oxide coatings in an aqueous-based medium was simultaneously monitored over 99 cycles by cyclic voltammetry and in situ spectroscopic ellipsometry. This allowed extracting the evolution of optical and geometrical parameters upon cycling. The resulting electrochemical coloring-bleaching process was dynamically fitted in the 1.8–2.8 eV optical range with a four-phase model including a constrained spline parametrization of the dielectric function. This allows real time access to thickness, surface roughness, and dielectric function of N a x W O 3 . The temporal evolution of the latter in the fully colored state wa…
Impact de l'épandage des boues sur le phosphore dissous et particulaire des écoulements de surface
2003
Abstract The aim of this study was to assess the effect of land application of sewage sludge on phosphorus (P) losses during intense rainfall. Three rainfall simulations (40 mm h−1 of 30 min duration) were conducted on a field amended with sewage sludge. The overland flow water (OFW) was monitored and sampled every minute. The suspended solid, the dissolved and total phosphorus (respectively SS, TP and DP) concentrations were analysed. The forms of particulate bound P (PP) were investigated. Several results stem from this experiment: (a) sludge application induced a large increase in the DP content of the OFW; the concentrations obtained (0.15–0.57 mg l−1) were shown to result from desorpti…