Search results for "Solid"

Segregation and co-occurrence of larval cestodes in freshwater fishes in the Bothnian Bay, Finland

1992

SUMMARYTwo autogenic (Triaenophorus crassus and T. nodulosus) and four allogenic (Diphyllobothrium latum, D. dendriticum, D. ditremum and Schistocephalus solidus) larval cestode species were found in 13 out of 31 fish species studied from the Bothnian Bay, NE Baltic. Gasterosteus aculeatus was the most heavily infected fish with 4 larval cestode species; for two of them (D. ditremum and S. solidus) the three-spined stickleback was found to be the required fish intermediate host. Among allogenic cestode species, those restricted to different definitive host species segregated their larval population in relation to the fish host, while, for example, D. ditremum and S. solidus, both maturing i…

Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium(III) complex

2007

A new, but archetypal compound [ Ir( ppy- F-2) (2)Me(4)phen] PF6, where ppy- F2 is 2-(2',4'- fluorophenyl) pyridine and Me(4)phen is 3,4,7,8- tetramethyl- 1,10- phenanthroline, was synthesized and used to prepare a solid-state light-emitting electrochemical cell (LEEC). This complex emits blue light with a maximum at 476 nm when photoexcited in a thin film, with a photoluminescence quantum yield of 52%. It yields an efficient single-component solid-state electroluminescence device with a current efficiency reaching 5.5 cd A(-1) and a maximum power efficiency of 5.8 Lm Watt(-1). However, the electroluminescence spectrum is shifted with respect to the photoluminescence spectrum by 80 nm resul…

Eco-efficiency assessment of municipal solid waste services: Influence of exogenous variables.

2020

Abstract Improving the eco-efficiency of municipalities in the provision of municipal solid waste (MSW) services is fundamental in the context of a circular economy. This study evaluates the eco-efficiency of a sample of Spanish municipalities, integrating the total cost as input, recyclable waste as desirable output, and unsorted waste as undesirable output. Following a pioneering approach, the weighted Russell directional distance model (a non-radial data envelopment analysis model) was employed, which allowed us to obtain a global inefficiency score and individual inefficiency scores for each variable integrated in the model. In the second stage of analysis, the potential factors affecti…

Chalcogen‐Bonding Interactions in Telluroether Heterocycles [Te(CH2)m]n (n=1-4; m=3-7)

2020

The Te…Te secondary bonding interactions (SBI) in solid heterocyclic telluroethers were explored by preparing and structurally characterizing a series of [Te(CH2)m]n (n = 1‐4; m = 3‐7) species. The SBIs in 1,7‐Te2(CH2)10, 1,8‐Te2(CH2)12, 1,5,9‐Te3(CH2)9, 1,8,15‐Te3(CH2)18, 1,7,13,19‐Te4(CH2)20, 1,8,15,22‐Te4(CH2)24, and 1,9,17,25‐Te4(CH2)28 led to the tubular packing of the molecules, as has been observed previously for related thio‐ and selenoether rings. The nature of the intermolecular interactions was explored by solid‐state PBE0‐D3/pob‐TZVP calculations involving periodic boundary conditions. The packing of molecules in 1,7,13,19‐Te4(CH2)20, 1,8,15,22‐Te4(CH2)24, and 1,9,17,25‐Te4(CH2)…

Glacigēno nogulumu veidošanās apstākļu ietekme uz grunts saspiežamības parametriem

2018

Maģistra darbā “Glacigēno nogulumu veidošanās apstākļu ietekme uz grunts saspiežamības parametriem’’ ir veikts pētījums par glacigēno nogulumu subglaciālo apstākļu veidošanās ietekmi uz glacigēno grunšu saspiežamības parametriem. Inženierģeoloģiskajos pētījumos Latvijā līdz šim nav vērsta pietiekama uzmanība glacigēno grunšu izpētes metodikas problemātikai, ko rada šo grunšu neviendabīgums. Maģistra darbā ir detalizēti izpētīti divi no saspiežamības parametriem – pirmskonsolidācijas spriegums un pārkonsolidācijas koeficients OCR, kas ir nozīmīgi rādītāji grunts mehānikā klasificējot gruntis un prognozējot grunts masīva sēšanos vertikālā spiediena pieauguma rezultātā. No laboratoriskajiem gr…

A Crystalline 1D Dynamic Covalent Polymer

2022

The synthesis of crystalline one-dimensional polymers provides a fundamental understanding about the structure??? property relationship in polymeric materials and allows the preparation of materials with enhanced thermal, mechanical, and conducting properties. However, the synthesis of crystalline one-dimensional polymers remains a challenge because polymers tend to adopt amorphous or semicrystalline phases. Herein, we report the synthesis of a crystalline one-dimensional polymer in solution by dynamic covalent chemistry. The structure of the polymer has been unambiguously confirmed by microcrystal electron diffraction that together with charge transport studies and theoretical calculations…

Segregation in Drying Binary Colloidal Droplets

2019

When a colloidal suspension droplet evaporates from a solid surface, it leaves a characteristic deposit in the contact region. These deposits are common and important for many applications in printing, coating, or washing. By the use of superamphiphobic surfaces as a substrate, the contact area can be reduced so that evaporation is almost radially symmetric. While drying, the droplets maintain a nearly perfect spherical shape. Here, we exploit this phenomenon to fabricate supraparticles from bidisperse colloidal aqueous suspensions. The supraparticles have a core-shell morphology. The outer region is predominantly occupied by small colloids, forming a close-packed crystalline structure. Tow…

Sustainable greenhouse horticulture in Europe

2012

Partition of volatile compounds in pea globulin–maltodextrin aqueous two-phase system

2014

International audience; This study is based on the assumption that the off-flavour of pea proteins might be decreased using the retention of volatile compounds by a mixture with another biopolymer. The partition of volatile compounds in an aqueous system containing pea protein and maltodextrins was followed under thermodynamic incompatibility conditions. Firstly, the phase diagram of the system was established. Then, the partition of aroma compounds between the phase rich in protein and the phase rich in maltodextrin was measured by SPME–GC–MS. There was a transfer of volatile compounds during phase separation. Variations of pH were also used to vary the retention of volatile compounds by p…

Microwave-Assisted Esterification of Tall Oil Fatty Acids with Methanol Using Lignin-Based Solid Catalyst

2016

During alkaline pulping significant amounts of lignin, carbohydrates (mostly hemicelluloses), and extractives (tall oil soap and turpentine) are removed from wood feedstock. In this study, the catalytic esterification of fatty acids in tall oil with methanol to produce fatty acid methyl esters under microwave irradiation was performed at 100 °C for 10–60 min. A novel heterogeneous acid catalyst tested for this purpose was synthesized from the hardwood alkali lignin that was precipitated by acidification from the black liquor from soda-AQ pulping. The comparative reaction data were obtained by using other solid catalysts, Amberlyst 15, and p-toluenesulfonic acid. The results showed the highe…