Search results for "Solutions"
showing 10 items of 757 documents
Billion-Fold Enhancement in Sensitivity of Nuclear Magnetic Resonance Spectroscopy for Magnesium Ions in Solution
2014
Beta-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. Beta-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. In this work, beta-NMR is applied, for the first time, to record an NMR spectrum for a species in solution. 31Mg b-NMR spectra are measured for as few as 10^7 magnesium ions in ionic liquid (EMIM-Ac) within minutes, as a prototypical test case. Resonances are observed at 3882.9 and 3887.2 kHz in an external field of 0.3 T. The key achievement of the current work is to demonstrate that beta-NMR is applicable for the…
Inhibitoren der Korrosion (14). pH-Wert-Änderungen in Suspensionen von Eisen in 0, 2 m NaCl-Lösungen unter den Bedingungen der Sauerstoffkorrosion
1971
In einer geeigneten Apparatur werden in Suspensionen von Eisen bei unterschiedlichen Reaktionsbedingungen die pH-Werte laufend bestimmt. Es wurden folgende Ergebnisse erhalten: 1 In einer Suspension van 25 g Carbonyleisenpulver in 100 m reinem Wasser andert sich weder unter N2 nach unter O2 der PH-Wert. 2 Schuttelt man 25 g Carbonyleisenpulver unter 100ml 0,2 m NaCl-Losung, so steigt innerhalb von drei bis acht Minuten der PH-Wert van 6,60 auf 9,4-9,6 an. 3 Durch Bestimmung der Menge an gelostem Fe(OH)2 und Umrechnung in pH-Einheiten kann gezeigt werden, das der pH-Wert-Anstieg zuruckgeht. Corrosion inhibitors (14) pH variations in suspensions of iron in 0.2 m NaCl solutions under condition…
Theoretical study of phosphodiester hydrolysis in nucleotide pyrophosphatase/phosphodiesterase. Environmental effects on the reaction mechanism.
2010
We here present a theoretical study of the alkaline hydrolysis of methyl p-nitrophenyl phosphate (MpNPP(-)) in aqueous solution and in the active site of nucleotide pyrophosphatase/phosphodiesterase (NPP). The analysis of our simulations, carried out by means of hybrid quantum mechanics/molecular mechanics (QM/MM) methods, shows that the reaction takes place through different reaction mechanisms depending on the environment. Thus, while in aqueous solution the reaction occurs by means of an A(N)D(N) mechanism, the enzymatic process takes place through a D(N)A(N) mechanism. In the first case, we found associative transition-state (TS) structures, while in the enzyme TS structures have dissoc…
LINKING TEACHER PROFESSIONAL DEVELOPMENT NEEDS WITH APPROPRIATE SOLUTIONS: INSIGHTS FROM AN INIATIVE IN LATVIA
2021
International surveys have stated that each year teachers spend, on average, more than 10 days engaged in different professional development activities. The purpose for this investment in teacher professional development (TPD) is clear: teachers’ competence must develop according to changes in curriculum and 21st century requirements. In previous research we have developed a theoretical teacher competence framework, implemented it to identify teacher (N=263) groups competence gaps and professional development needs. The goal of this research is to link identified professional development needs related to the instruction of 21st century skills (criteria - instructional design, learning goals…
Superlinear Robin Problems with Indefinite Linear Part
2018
We consider a semilinear Robin problem with an indefinite linear part and a superlinear reaction term, which does not satisfy the usual in such cases AR condition. Using variational methods, together with truncation–perturbation techniques and Morse theory (critical groups), we establish the existence of three nontrivial solutions. Our result extends in different ways the multiplicity theorem of Wang.
A novel numerical meshless approach for electric potential estimation in transcranial stimulation
2015
In this paper, a first application of the method of fundamental solutions in estimating the electric potential and the spatial current density distribution in the brain due to transcranial stimulation, is presented. The coupled boundary value p roblems for the electric potential are solved in a meshless way, so avoiding the use of grid based numerical methods. A multi-spherical geometry is considered and numerical results are discussed.
Jute bioblanket as a soil rehabilitation strategy in Sorocaba, Brazil: Soil chemistry and SWOT approaches
2019
Made available in DSpace on 2022-04-29T08:28:27Z (GMT). No. of bitstreams: 0 Previous issue date: 2019-09-01 Soil erosion and the invasion of exotic plant species are major constraints to achieve sustainable development around the world. Currently, we find few products devoted concomitantly to combatting soil erosion as well as the establishment of unwanted exotic plants. In this paper, we introduce a new product, called herein a bioblanket, that protects the soil and impedes the establishment of exotic plant species. This product is of simple design, and to manufacture it, we use two biodegradable materials: jute tissue and grass wastes. We designed this product to combat soil erosion and …
Green infrastructures for the energetic and environmental sustainability of cities
2019
The inexorable extension of urbanization is consuming huge amounts of soil drastically reducing natural vegetation, replacing it with buildings and low albedo surfaces. The changes due to the different thermal properties of surface materials and the lack of evapotranspiration in urban areas lead to a phenomenon known as "urban heat island effect". By reintroducing the vegetation back into the urban landscape, a partnership between nature and cities should be strengthened to create a new sustainable urban environment. Since the outer surfaces of building offer a great amount of space for vegetation, planting on roofs and walls has become one of the most innovative way to provide several envi…
Application of reverse electrodialysis to site-specific types of saline solutions: A techno-economic assessment
2019
Abstract Salinity gradients are a non-conventional source of renewable energy based on the recovery of the Gibbs free energy related to the mixing of solutions at different concentrations. Reverse Electrodialysis is a promising and innovative technology able to convert this energy directly into electric current. The worldwide availability of salinity gradients is limited to those locations where water bodies at different salinity levels are present. The present work analyses a number of different scenarios worldwide, in locations where salinity gradients are naturally available or generated by anthropogenic activities. A techno-economic model of the Reverse Electrodialysis process is presen…
Renormalized solutions for degenerate elliptic–parabolic problems with nonlinear dynamical boundary conditions and L1-data
2008
Abstract We consider a degenerate elliptic–parabolic problem with nonlinear dynamical boundary conditions. Assuming L 1 -data, we prove existence and uniqueness in the framework of renormalized solutions. Particular instances of this problem appear in various phenomena with changes of phase like multiphase Stefan problems and in the weak formulation of the mathematical model of the so-called Hele–Shaw problem. Also, the problem with non-homogeneous Neumann boundary condition is included.