Search results for "Sorption"
showing 10 items of 4623 documents
Volcanic CO_2 detection with a DFM/OPA-based lidar
2015
The DFM/OPA-based lidar BILLI was used to investigate the volcanic plume released by the hydrothermal vent of Pisciarelli, in the Campi Flegrei volcano. BILLI remotely measured CO2 concentrations in cross-sections of the nearvent plume using the differential absorption technique. To our knowledge, this is the first example of lidar-based measurement of volcanic CO2 . The spatial resolution was 1.5 m and the temporal resolution 20 s. © 2015 Optical Society of America.
Fast tracking of wind speed with a differential absorption LiDAR system: First results of an experimental campaign at Stromboli volcano
2017
Carbon dioxide ( CO 2 ) is considered a precursor gas of volcanic eruptions by volcanologists. Monitoring the anomalous release of this parameter, we can retrieve useful information for the mitigation of volcanic hazards, such as for air traffic security. From a dataset collected during the Stromboli volcano field campaign, an assessment of the wind speed, in both horizontal and vertical paths, performing a fast tracking of this parameter was retrieved. This was determined with a newly designed shot-per-shot differential absorption LiDAR system operated in the near-infrared spectral region due to the simultaneous reconstruction of CO 2 concentrations and wind speeds, using the same sample o…
Scattering and absorption imaging of a highly fractured fluid-filled seismogenetic volume in a region of slow deformation
2020
Regions of slow strain often produce swarm-like sequences, characterized by the lack of a clear mainshock-aftershock pattern. The comprehension of their underlying physical mechanisms is challenging and still debated. We used seismic recordings from the last Pollino swarm (2010–2014) and nearby to separate and map seismic scattering (from P peak-delays) and absorption (from late-time coda-wave attenuation) at different frequencies in the Pollino range and surroundings. High-scattering and high-absorption anomalies are markers of a fluid-filled fracture volume extending from SE to NW (1.5–6 Hz) across the range. With increasing frequency, these anomalies approximately cover the area where t…
Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo
2017
Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variati…
Speciation and interactions of plutonium with humic substances and kaolinite in aquifer systems
2007
Abstract The speciation of plutonium (Pu) in contact with humic substances (HS) and kaolinite has been performed in aquifer systems. Mainly the redox behavior, complexation, and sorption of plutonium are discussed here. The redox behavior of Pu(VI) in contact with HS was studied and it was found that Pu(VI) is reduced to Pu(III) and Pu(IV) within a couple of weeks. The complexation constants (log β LC ) of Pu(III) and Pu(IV) with HS have been determined by means of the ultrafiltration method. Furthermore, the sorption of Pu(III) and Pu(IV) onto kaolinite has been investigated as a function of pH by batch experiments under aerobic and anaerobic conditions.
Measurements of volcanic SO2 and CO2 fluxes by combined DOAS, Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes
2014
Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO2 emissions. However, measurements of CO2 emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO2 emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO2 emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO2/SO2 ratios of exc…
Multicopter measurements of volcanic gas emissions at Masaya (Nicaragua), Turrialba (Costa Rica) and Stromboli (Italy) volcanoes: Applications for vo…
2017
Abstract. Volcanoes are a natural source of several reactive gases (e.g. sulfur and halogen containing species), as well as non-reactive gases (e.g. carbon dioxide). Besides that, halogen chemistry in volcanic plumes might have important impacts on atmospheric chemistry, carbon to sulfur ratios and sulfur dioxide fluxes are important established parameters to gain information on subsurface processes. In this study we demonstrate the successful deployment of a multirotor UAV (quadcopter) system with custom-made lightweight payloads on board for the compositional analysis and gas flux estimation of volcanic plumes. The various applications and their potential with such new measurement strateg…
The aquatic geochemistry of arsenic in volcanic groundwaters from southern Italy
2003
Abstract This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 μg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at …
Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy
2014
Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…
Translocation of Cations During Sorption of Copper in the System Solution - Algae (Spirogyra sp.)/Translokacja Kationów Podczas Procesu Sorpcji Miedz…
2014
Zbadano kinetykę procesu sorpcji kationów miedzi w glonach Spirogyra sp. oraz towarzyszące mu procesy sorpcji kationów wodorowych i procesy uwalniania do roztworu kationów związanych w glonach: Na+, Mg2+, K+ i Ca2+. Stwierdzono, że w układzie statycznym, przy stałym stosunku masy glonów do objętości roztworu, procesy te zachodzą równocześnie, przy czym należy przypuszczać, że ilość uwalnianych soli ma wpływ na parametry heterofazowej równowagi wymiany jonowej. W warunkach prowadzenia eksperymentu ilość uwolnionych kationów była blisko 10-krotnie większa niż ilość kationów sorbowanych. Porównano parametry równowagi wyznaczone z modelu reakcji pseudo-drugiego rzędu z parametrami uzyskanymi po…