Search results for "Spect"

showing 10 items of 28650 documents

Optical hybrid nanocomposite sensors for selective explosive detection

2022

Durant l'última dècada, la detecció d'artefactes explosius improvisats (IEDs) tant en l'àmbit militar com civil s'ha convertit en una prioritat estratègica en la seguretat nacional a causa de la creixent amenaça terrorista. Encara que les tècniques convencionals, com la cromatografia de gasos acoblada a espectrometria de masses o la difracció de raigs X mostren notables avantatges degut a la seua elevada sensibilitat i selectivitat, una gran part d’aquestes presenten inconvenients, com per exemple processos de mesura lents, instrumentació cara, complexa i voluminosa, que limiten el mostreig en continu i en temps real. Per aquesta raó, existeix una recerca constant per trobar una plataforma …

silver nanoparticlesUNESCO::QUÍMICA::Química analítica::Espectroscopía de infrarrojosnanocompositeperovskite nanocrystalsUNESCO::QUÍMICA::Química inorgánicatemplate moleculequantum dotsmolecularly imprinted polymergas sensor3-nitrotoluenemultichannelsensorexplosive taggantlsprfluorescenceUNESCO::QUÍMICA::Química analítica::Análisis cromatográficoUNESCO::QUÍMICA::Química analítica::Espectroscopía de emisiónUNESCO::QUÍMICA::Química analítica::Análisis de polímeros
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Design and Characterization of Effective Ag, Pt and AgPt Nanoparticles to H2O2 Electrosensing from Scrapped Printed Electrodes

2019

The use of disposable screen-printed electrodes (SPEs) has extraordinarily grown in the last years. In this paper, conductive inks from scrapped SPEs were removed by acid leaching, providing high value feedstocks suitable for the electrochemical deposition of Ag, Pt and Ag core-Pt shell-like bimetallic (AgPt) nanoparticles, onto screen-printed carbon electrodes (ML@SPCEs, M = Ag, Pt or AgPt, L = metal nanoparticles from leaching solutions). ML@SPCEs were characterized by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The results were compared to those obtained when metal nanoparticles were synthesised using standard solutions of metal salts (MS@…

silver nanoparticleshydrogen peroxide sensorMaterials sciencechemistry.chemical_element02 engineering and technologyScreen-printed electrodeslcsh:Chemical technologyElectrochemistryPlatinum nanoparticles01 natural sciencesBiochemistrySilver nanoparticleAnalytical Chemistryscreen-printed electrodesHydrogen peroxide sensorPlatinum nanoparticleslcsh:TP1-1185Química FísicaElectrical and Electronic EngineeringInstrumentationBimetallic nanoparticlesConductive inksbimetallic nanoparticlesMetals recovery010401 analytical chemistry021001 nanoscience & nanotechnologyconductive inksAtomic and Molecular Physics and Optics0104 chemical sciencesElectrochemical gas sensorDielectric spectroscopymetals recoverychemistryLeaching (metallurgy)Cyclic voltammetrySilver nanoparticles0210 nano-technologyPlatinumplatinum nanoparticlesNuclear chemistry
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Application of 3D printed scavengers for improving the accuracy of single-particle inductively coupled plasma mass spectrometry analyses of silver na…

2023

The determination of silver nanoparticles (Ag NPs) with single-particle inductively coupled plasma mass spectrometry can be severely interfered with coexisting dissolved silver causing high background signals, which can lead to inaccurate quantification of NP size and particle concentration. In this paper, chemically active and reusable 3D printed scavengers are applied for highly efficient dissolved silver removal in Ag NP dispersions, allowing more accurate determination of particle concentration and size. Selective laser sintering was used for constructing the porous 3D scavengers constituting of polystyrene used as a supporting material and ion-exchange material SiliaBond Tosic acid (TA…

silver nanoparticlesmassaspektrometriaSP-ICP-MSfunctional 3D scavengershopeadispersiot (seokset)3D printingAtomic and Molecular Physics and OpticsAnalytical Chemistryerotusmenetelmätdissolved silver interference3D-tulostusnanohiukkasetInstrumentationSpectroscopySpectrochimica Acta Part B: Atomic Spectroscopy
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Projet SOFT

2020

Le projet SOFT, sobriété énergétique par les formes urbaines et le transport, a abordé la question de la stratégieénergétique d’un territoire à l’aide d’un concept d’aménagement multi-échelle utilisant la géométrie fractale. Eneffet, les gains d’efficience classique (rénovation du bâti, performance des modes de transport, production localed’énergie) ne suffisent pas aujourd’hui pour assurer aux territoires une trajectoire carbone appropriée. Il estnécessaire de s’appuyer sur la sobriété énergétique, approche qui consiste à assurer la même qualité de vie auxhabitants, mais avec une baisse des consommations énergétiques qui peut s’accompagner d’une évolution despratiques. L’approche de la sob…

simulation LUTIurbanisme[SHS.GEO] Humanities and Social Sciences/Geographyformes urbainesFractalesprospectiveperformance énergétique
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Time resolved emission at 1.3 μm of a single InAs quantum dot by using a tunable fibre Bragg grating

2013

Photoluminescence and time resolved photoluminescence from single metamorphic InAs/GaAs quantum dots (QDs) emitting at 1.3 mu m have been measured by means of a novel fibre-based characterization set-up. We demonstrate that the use of a wavelength tunable fibre Bragg grating filter increases the light collection efficiency by more than one order of magnitude as compared to a conventional grating monochromator. We identified single charged exciton and neutral biexciton transitions in the framework of a random population model. The QD recombination dynamics under pulsed excitation can be understood under the weak quantum confinement potential limit and the interaction between carriers at the …

single quantum dot time resolved spectroscopy fibre Bragg grating excitonsPhotoluminescenceMaterials scienceexcitonsExcitonfibre Bragg gratingPhysics::OpticsBioengineeringGratinglaw.inventionCondensed Matter::Materials ScienceFiber Bragg gratinglawGeneral Materials ScienceElectrical and Electronic EngineeringBiexcitonMonochromatorWetting layerCondensed Matter::Quantum Gasesbusiness.industryCondensed Matter::OtherMechanical EngineeringGeneral ChemistryCondensed Matter::Mesoscopic Systems and Quantum Hall Effectsingle quantum dottime resolved spectroscopyMechanics of MaterialsQuantum dotOptoelectronicsbusiness
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Adoption and Adoption Interests of Self-Tracking Technologies : Single and Multiple Technology Perspectives

2016

During the past few decades, different forms of technology based self-tracking have become increasingly common but received little attention in academic research. In this study, we aim to address this gap by examining the adoption and adoption interests of four different self-tracking technologies: exercise, activity, sleep, and nutrition tracking. The examination is conducted from both single and multiple technology perspectives and by concentrating particularly on the potential gender and age dependencies in the adoption rates and adoption patterns of the technologies. By analysing the responses collected from 824 consumers through an online survey, the results of the study are able to re…

single technology perspectiveadoptioself-tracking technolgiesadoption interestsmultiple technology perspective
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Psychotherapy Integration: A main Obstacle and Challenge

2018

Abstract Psychotherapy integration is a key trend in psychotherapy nowadays. This paper offers a critical perspective on a main obstacle and challenge for psychotherapy integration. Psychotherapy integration should be treated more as a process than as a product. For psychotherapy integration to contribute to the future of psychotherapy, it should not forget its original Exploratory spirit, avoiding and being cautious about Established approaches, and being, therefore, more a process than a product. This assumption should be related first with the core spirit of psychotherapy integration, an ongoing process of respect for different psychotherapeutic models, and an attitude of work in progres…

single-orientationpsychotherapyCritical perspectivePsychotherapistProcess (engineering)ObstaclePerspective (graphical)Product (category theory)psychotherapy integrationWork in processPsychologyintegrative modelsTerapia psicológica
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Electronic Structures and Molecular Properties of Chalcogen Nitrides Se2N2 and SeSN2

2006

The electronic structures and molecular properties of S2N2 as well as the currently unknown chalcogen nitrides Se2N2 and SeSN2 have been studied using various ab initio and density functional methods. All molecules share a qualitatively similar electronic structure and can be primarily described as 2π-electron aromatics having minor singlet diradical character of 6−8% that can be attributed solely to the nitrogen atoms. This diradical character is manifested in the prediction of their molecular properties, in which coupled cluster and multiconfigurational approaches, as well as density functional methods, show the best performance. The conventional ab initio methods RHF and MP2 completely f…

singletti diradikaaliChemistryDiradicalChemical shiftAb initioE2N2General MedicineElectronic structureMolecular physicssinglet diradicalsymbols.namesakeCoupled clusterChemical physicssymbolsMoleculeSinglet statePhysical and Theoretical ChemistryRaman spectroscopy
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Singular (p, q)-equations with superlinear reaction and concave boundary condition

2020

We consider a parametric nonlinear elliptic problem driven by the sum of a p-Laplacian and of a q-Laplacian (a (Formula presented.) -equation) with a singular and (Formula presented.) -superlinear reaction and a Robin boundary condition with (Formula presented.) -sublinear boundary term (Formula presented.). So, the problem has the combined effects of singular, concave and convex terms. We look for positive solutions and prove a bifurcation-type theorem describing the changes in the set of positive solutions as the parameter varies.

singular termConcave and convex nonlinearitiesnonlinear maximum principleApplied Mathematics010102 general mathematicsMathematical analysisSingular termBoundary (topology)Mathematics::Spectral Theory01 natural sciences010101 applied mathematicscomparison principlesNonlinear systemSettore MAT/05 - Analisi Matematicanonlinear regularity theoryBoundary value problem0101 mathematicstruncation (pq)-LaplacianAnalysisParametric statisticsMathematicsApplicable Analysis
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Los sistemas alternativos y aumentativos de comunicación (SAAC) como instrumento para disminuir conductas desafiantes en el alumnado con TEA: estudio…

2017

Resumen Se describe una intervención, basada en el Programa de Habla Signada de Benson Schaeffer, para dotar de un Sistema Alternativo y Aumentativo de Comunicación (SAAC) a una niña de ocho años diagnosticada con trastorno del espectro autista (TEA). Se pretende que la alumna, mediante la utilización de signos, pueda expresar sus necesidades y disminuir las conductas desafiantes que propicia, ya que se estima que estas tienen una clara intención comunicativa. Se utiliza una metodología cualitativa de estudio de caso único y por objetivos. El programa se desarrolló en el aula de comunicación y lenguaje (CyL) de un centro público de educación infantil y primaria (CEIP) de la Comunidad Valenc…

sistema alternativo y aumentativo de comunicación.Language classroommedia_common.quotation_subjectComunicació oralPrimary educationcomunicaciónGeneral Medicinelcsh:Social Scienceslcsh:Hlcsh:H1-99Trastorno del espectro autistaGirllcsh:Social sciences (General)AutismePsychologyHumanitiesconductas desafiantesAugmentativemedia_common
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