Search results for "Spect"
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Classroom discussions: Possibilities and limitations for democratic classroom practices
2017
Are students offered possibilities to experience democratic practice in classrooms? Using an analysis of empirical data from classroom discussions in lower secondary school, this article identifies and explores two different types of classroom discussions which give students different positions: a conversation in which students are positioned as ‘poll respondents’, and a more deliberative conversation which positions students as learning debaters. The two forms of classroom discussions are discussed due to the way they give different meaning to democracy, and due to whether the student positions in the classrooms imply contribution to the subject matter and what is considered valuable knowl…
Orientare nella scuola alla scelta formativo-professionale post-diploma con la metodologia «SeCo»
2017
È stata effettuata un’indagine pilota ispirata alla teoria di Pennebaker e ai principi della scuola rogersiana di counseling. 88 studenti del quinto anno di un liceo di Enna hanno partecipato, tra il mese di novembre 2015 e il mese di maggio 2016, a un progetto di orientamento che ha previsto la sperimentazione della metodologia educativa «SeCo» (Scrittura espressiva e Colloquio di orientamento) per la costruzione del loro progetto di vita professionale. L’applicazione di questa metodologia ha implicato lo svolgimento di due attività formative: tre sessioni di scrittura espressivo-prospettica e tre colloqui individuali di orientamento. Si è voluto verificare se la partecipazione a queste at…
Wyjątkowość zapisana w przeszłości - wizerunek wyjątkowego nauczyciela we wspomnieniach
2018
Wszyscy z czasem powracamy pamięcią do czasów szkolnych, wspominając różnorakie sytuacje i wydarzenia, w których integralną częścią był nauczyciel. Zapisane w pamięci indywidualne wspomnienia, doświadczenia i refleksje, niejednokrotnie niosą ze sobą emocje - oddziałujące na nasze decyzje, postawy i zachowania - pomimo upływu lat. W artykule skoncentrowano się na poznaniu uwarunkowań i znaczeń pozytywnego wizerunku wyjątkowych nauczycieli, utrwalonego w pamięci przyszłych nauczycieli i pedagogów. Z uwagi na podejmowaną tematykę badawczą zdecydowano się na badania retrospektywne w strategii mieszanej, wśród studentów studiów pedagogicznych. Obraz wyjątkowo lubianego nauczyciela, ujawniający s…
Studies in organic mass spectrometry. Part 23. Role of the aroyl group on the competitive fragmentation reactions of the molecular ion of aroylanilid…
1999
The 70 eV and mass-analysed ion kinetic energy (MIKE) spectra of some thiophenecarboxanilides and benzoylanilides (1–10) have been compared in order to investigate the role of the aroyl (or heteroaroyl) moiety on the abundance of the competitive fragmentation reactions occurring in their molecular ions (amide–bond cleavage and phenol radical ion formation). It has been shown that the electron ionisation induced decompositions with high (70 eV) and low (MIKE) internal energy excess are qualitatively similar, but remarkable quantitative differences have been observed that can be accounted for in terms of the different effectiveness in the transmission of electronic effects of substituents in …
Titanocene Selenide Sulfides Revisited: Formation, Stabilities, and NMR Spectroscopic Properties
2019
[TiCp2S5] (phase A), [TiCp2Se5] (phase F), and five solid solutions of mixed titanocene selenide sulfides [TiCp2SexS5−x] (Cp = C5H5−) with the initial Se:S ranging from 1:4 to 4:1 (phases B–E) were prepared by reduction of elemental sulfur or selenium or their mixtures by lithium triethylhydridoborate in thf followed by the treatment with titanocene dichloride [TiCp2Cl2]. Their 77Se and 13C NMR spectra were recorded from the CS2 solution. The definite assignment of the 77Se NMR spectra was based on the PBE0/def2-TZVPP calculations of the 77Se chemical shifts and is supported by 13C NMR spectra of the samples. The following complexes in varying ratios were identified in the CS2 solutions of …
Spherical Top Theory and Molecular Spectra
2011
In this article, we present an overview of the present state of the art of the theory of high-resolution spherical-top spectra in the framework of the effective Hamiltonian approach. We describe the specific features of this class of molecules to explain the basic concepts of the theoretical methods used for the analysis (line positions and intensities) and the simulation of absorption (including pure rotation) and Raman spectra of such species. The non conventional formalism that we use is essentially based on irreducible tensor methods and is especially adapted to computational treatments and global analyses of complex interacting band systems. We give examples concerning mainly methane (…
The structure of coronal plasma in active stellar coronae from density measurements
2005
We have analyzed high-resolution X-ray spectra of a sample of 22 active stars observed with the High Energy Transmission Grating Spectrometer (HETGS) on Chandra in order to investigate their coronal plasma density, using the lines of the He-like ions O VII, Mg XI, and Si XIII. Si XII lines in all stars of the sample axe compatible with the low-density limit (i.e. n(e) = 10(30) erg/s); O VII lines yield much lower densities of a few 10(10) cm(-3). Our results indicate that the "hot" and "cool" plasma resides in physically different structures. Our findings imply remarkably compact coronal structures, especially for the hotter (similar to 7 MK) plasma emitting the Mg xi lines characterized by…
Skin surveillance attitudes and behaviors in relation to skin checks for early signs of skin cancer in a sample of secondary school students and teac…
2012
<p><strong>Background</strong>: Malignant melanoma (MM) can be readily treated in its earliest stages: survival rate, when detected early, is up to 95,0%. This justifies investigations on contributive factors and measures for precocious detection of skin tumors to improve early detection and to increase survival rates. The purpose of this survey was to collect information about knowledge, attitudes and behaviors on prevention in relation to skin checks for early signs of skin cancer on a sample of secondary school students and teachers.</p><p><strong>Methods</strong>: A sample of secondary school students and teachers from Palermo, was recruited usi…
1H NMR Urinary Metabolomic Analysis in Older Adults after Hip Fracture Surgery May Provide Valuable Information for Patient Profiling : A Preliminary…
2022
In these times of precision and personalized medicine, profiling patients to identify their needs is crucial to providing the best and most cost-effective treatment. In this study, we used urine metabolomics to explore the characterization of older adults with hip fractures and to explore the forecasting of patient outcomes. Overnight urine specimens were collected from 33 patients (mean age 80 ± 8 years) after hip fracture surgery during their stay at a rehabilitation hospital. The specimens were analyzed with 1H NMR spectroscopy. We performed a metabolomics study regarding assessments of frailty status, Functional Independence Measure (FIM), and Short Physical Performance Battery (SPPB). …
Motives for competitive sports participation in masters track and field athletes : Impact of sociodemographic factors and competitive background
2022
Objectives Masters athletes due to their lifelong engagement in sport represent a unique group to study motivation for regular physical activity, but there is less scientific data on the sport motives in masters athletes. Therefore, the aim of this study was to evaluate the association of age, sex, education, nationality, competitive background and training amount with sport motives of masters track and field athletes. Methods 811 (254 women) athletes aged 35–89 years participated in European Veterans Athletics Championships in the year of 2000. Sport motives were assessed with a questionnaire and categorized into1) well-being, 2) competitive and performance 3) health and fitness motives. R…