Search results for "Spectral"
showing 10 items of 3116 documents
Excited State Dynamics in Recombinant Water-Soluble Chlorophyll Proteins (WSCP) from Cauliflower Investigated by Transient Fluorescence Spectroscopy
2008
The present study describes the fluorescence emission properties of recombinant water-soluble chlorophyll (Chl) protein (WSCP) complexes reconstituted with either Chl a or Chl b alone (Chl a only or Chl b only WSCP, respectively) or mixtures of both pigments at different stoichiometrical ratios. Detailed investigations were performed with time and space correlated ps fluorescence spectroscopy within the temperature range from 10 to 295 K. The following points were found: (a) The emission spectra at room temperature (295 K) are well characterized by bands with a dominating Lorentzian profile broadened due to phonon scattering and peak positions located at 677, 684 and 693 nm in the case of C…
Protein dynamics observed by tunable mid-IR quantum cascade lasers across the time range from 10 ns to 1 s
2017
We have developed a spectrometer based on tunable quantum cascade lasers (QCLs) for recording time-resolved absorption spectra of proteins in the mid-infrared range. We illustrate its performance by recording time-resolved difference spectra of bacteriorhodopsin in the carboxylic range (1800–1700 cm− 1) and on the CO rebinding reaction of myoglobin (1960–1840 cm− 1), at a spectral resolution of 1 cm− 1. The spectrometric setup covers the time range from 4 ns to nearly a second with a response time of 10–15 ns. Absorption changes as low as 1 × 10− 4 are detected in single-shot experiments at t > 1 μs, and of 5 × 10− 6 in kinetics obtained after averaging 100 shots. While previous time-res…
Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?
2009
International audience; We present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) state observed in transient absorption.
Fractional viscoelastic behaviour under stochastic temperature process
2018
Abstract This paper deals with the mechanical behaviour of a linear viscoelastic material modelled by a fractional Maxwell model and subject to a Gaussian stochastic temperature process. Two methods are introduced to evaluate the response in terms of strain of a material under a deterministic stress and subjected to a varying temperature. In the first approach the response is determined making the material parameters change at each time step, due to the temperature variation. The second method, takes advantage of the Time–Temperature Superposition Principle to lighten the calculations. In this regard, a stochastic characterisation for the Time–Temperature Superposition Principle method is p…
Comparison of transflection and transmission FTIR imaging measurements performed on differentially fixed tissue sections
2015
The widespread and cost-effective use of transflection substrates in Fourier transform infrared (FTIR) imaging of clinical samples is affected by the presence of artefacts including the electric field standing wave (EFSW) and contributions from light dispersion. For IR-based diagnostics, the manifestation of undesirable artifacts can distort the spectra and lead to erroneous diagnosis. Nevertheless, there is no clear consensus in the literature about the degree of influence of these effects. The aim of this work is to contribute to this discussion by comparing transflection and transmission images of the same tissue. For this purpose two adjacent sections of the same tissue (lymphoma sample…
Optical Properties of Irradiated Topaz Crystals
2015
The results of an investigation of UV-Visible absorption and photoluminescence spectra of colorless topaz before and after neutron irradiation, natural blue topaz from Ukraine, and yellow topaz are presented. We assume that the absorption band ~ 620 nm and broad emission band 300-700 nm in topaz crystals are associated with exchange interaction between a radiation defect (anion vacancies, which capture one or two electrons) and impurity ions Cr 3+ , Fe 3+ and Mn 2+ .
Total absorption spectroscopy of fission fragments relevant for reactor antineutrino spectra
2016
International audience; The accurate determination of reactor antineutrino spectra remains a very active research topic for which new methods of study have emerged in recent years. Indeed, following the long-recognized reactor anomaly (measured antineutrino deficit in short baseline reactor experiments when compared with spectral predictions), the three international reactor neutrino experiments Double Chooz, Daya Bay and Reno have recently demonstrated the existence of spectral distortions in their measurements with respect to the same predictions. These spectral predictions were obtained through the conversion of integral beta-energy spectra obtained at the ILL research reactor. Several s…
A Time-Domain Approach Based on the IEEE Std 1459-2000 for the detection of Loads Producing Harmonic Distortion
2008
This paper presents a novel strategy for the detection of harmonic sources in power systems for both the single-phase and the three-phase systems. It is based on the IEEE Std. 1459-2000 approach and it is based only on the separation of the fundamental components from the harmonic content of voltage and current. The proposed strategy do not require any spectral analysis of voltages and currents and it can be entirely implemented in the time domain. In the paper, the formulation of the novel approach is given and some simulation results are presented.
Clarkson-McCarthy inequalities with unitary and isometry orbits
2020
Abstract A refinement of a trace inequality of McCarthy establishing the uniform convexity of the Schatten p-classes for p > 2 is proved: if A , B are two n-by-n matrices, then there exists some pair of n-by-n unitary matrices U , V such that U | A + B 2 | p U ⁎ + V | A − B 2 | p V ⁎ ≤ | A | p + | B | p 2 . A similar statement holds for compact Hilbert space operators. Another improvement of McCarthy's inequality is given via the new operator parallelogramm law, | A + B | 2 ⊕ | A − B | 2 = U 0 ( | A | 2 + | B | 2 ) U 0 ⁎ + V 0 ( | A | 2 + | B | 2 ) V 0 ⁎ for some pair of 2n-by-n isometry matrices U 0 , V 0 .
Towards to deep neural network application with limited training data: synthesis of melanoma's diffuse reflectance spectral images
2019
The goal of our study is to train artificial neural networks (ANN) using multispectral images of melanoma. Since the number of multispectral images of melanomas is limited, we offer to synthesize them from multispectral images of benign skin lesions. We used the previously created melanoma diagnostic criterion p'. This criterion is calculated from multispectral images of skin lesions captured under 526nm, 663nm, and 964nm LED illumination. We synthesize these three images from multispectral images of nevus so that the p' map matches the melanoma criteria (the values in the lesion area is >1, respectively). Demonstrated results show that by transforming multispectral images of benign nevus i…