Search results for "Spectrometer"
showing 10 items of 751 documents
Mass spectrometry strategies for mycotoxins analysis in European beers
2013
In this work, an existent solid-phase extraction (SPE) procedure was used to study the occurrence of mycotoxins in different European beers. HPLC-QqQ-MS/MS and ultra high resolution mass analyser have been optimized for the analysis of 18 mycotoxins: the methods were validated according to the EU Commission Decision 2002/657/EC guidelines. In this sense, matrix-matched calibration was performed for each type of beer, obtaining an effective quantification. The recoveries ranged from 63 to 91% and repeatability and reproducibility expressed as relative standard deviation (RSD%) were lower than 17%. On one hand, HPLC-LTQ-Orbitrap ® was used for unambiguous identification of target mycotoxins, …
The miniaturised Mössbauer spectrometer MIMOS IIA: Increased sensitivity and new capability for elemental analysis
2010
The Miniaturised Mossbauer Spectrometers MIMOS II on board the two Mars Exploration Rovers (MER) have now been collecting valuable scientific data for more than five years. Mossbauer Spectrometers are part of two future missions: Phobos Grunt (Russian Space Agency) and a joint ESA—NASA Rover in 2018. The new advanced MIMOS IIA instrument described in this paper uses Silicon Drift Detectors (SDD) allowing also X-ray fluorescence chemical analysis (XRF) simultaneously to Mossbauer acquisitions. This paper highlights the features and technological improvements of the new spectrometer MIMOS IIA.
Calibration of the RPC charge readout in the ARGO-YBJ experiment
2012
""The charge readout of Resistive Plate Chambers (RPCs) is implemented in the ARGO-YBJ experiment to measure the charged particle density of the shower front up to 10^4\\\/m^2, enabling the study of the primary cosmic rays with energies in the ''knee'' region. As the first time for RPCs being used this way, a telescope with RPCs and scintillation detectors is setup to calibrate the number of charged particles hitting a RPC versus its charge readout. Air shower particles are taken as the calibration beam. The telescope was tested at sea level and then moved to the ARGO-YBJ site for coincident operation with the ARGO-YBJ experiment. The charge readout shows good linearity with the particle de…
Comparison of the Ultraviolet Light Filtering across Different Intraocular Lenses.
2018
SIGNIFICANCE We have analyzed the ultraviolet transmittance of some commercial intraocular lenses (IOLs). The results show differences of wavelength cutoff among them. PURPOSE The purpose of this study was to measure and compare the ultraviolet light transmittance of different IOLs made out of acrylic hydrophobic, hydrophilic, and hydrophilic with hydrophobic surface materials from different manufacturers. METHODS The spectral transmission curves of eight monofocal IOLs with the same dioptric power of +20.0 diopters were measured using a PerkinElmer Lambda 35 ultraviolet/visible spectrometer. Two IOLs of each type were tested three times. The ultraviolet cutoff wavelength at 10% transmissio…
Photoprotection and photoreception of intraocular lenses under xenon and white LED illumination.
2016
Objective. To analyze the photoprotection and phototransmission that various intraocular lenses (10Ls) provide under the illumination of a xenon (Xe) lamp and white LEDs (light emitting diode). Methods. The spectral transmission curves of six representative 10Ls were measured using a Perkin-Elmer Lambda 35 UV/VIS spectrometer. Various filtering simulations were performed using a Xe lamp and white LEDs. The spectral emissions of these lamps were measured with an ILT-950 spectroradiometer. Results. The 10Ls analyzed primarily show transmission of nearly 100% in the visible spectrum. In the ultraviolet (UV) region, the filters incorporated in the various 10Ls did not filter equally, and some o…
Scene-based spectral calibration assessment of high spectral resolution imaging spectrometers
2009
An accurate knowledge of the spectral calibration of imaging spectrometers is required for optimum data processing and interpretation. The scene-based spectral characterization of imaging spectrometers is frequently necessary to update or replace the pre-flight laboratory-based spectral characterization supplied by the data provider. An automatic method for the estimation of spectral calibration parameters (channel position and bandwidth) at atmospheric absorption regions from high spectral resolution imaging spectrometers (spectral sampling interval below 5 nm) is presented in this contribution. The method has been tested on two commercial instruments with spectral sampling intervals below…
Stratospheric sulfur and its implications for radiative forcing simulated by the chemistry climate model EMAC
2015
Multiyear simulations with the atmospheric chemistry general circulation model EMAC with a microphysical modal aerosol module at high vertical resolution demonstrate that the sulfur gases COS and SO2, the latter from low-latitude and midlatitude volcanic eruptions, predominantly control the formation of stratospheric aerosol. Marine dimethyl sulfide (DMS) and other SO2 sources, including strong anthropogenic emissions in China, are found to play a minor role except in the lowermost stratosphere. Estimates of volcanic SO2 emissions are based on satellite observations using Total Ozone Mapping Spectrometer and Ozone Monitoring Instrument for total injected mass and Michelson Interferometer fo…
In situ analysis with portable Raman and ED-XRF spectrometers for the diagnosis of the formation of efflorescence on walls and wall paintings of the …
2014
This work presents the results of field Raman analyses, assisted by a hand-held energy dispersive X-ray fluorescence spectrometer, for the experimental determination of efflorescence from walls and wall paintings of two Pompeian houses, one with many luxurious decorative elements (House of Marcus Lucretius, Regio IX, Insula 3, House 5/24) and a more modest building (Regio IX, Insula 3, House 1-2). Both exposed and protected rooms were measured in different year seasons, spring (May 2010) and summer (September 2011 and 2012) and considering different orientations. Chemical attacks of acid gases (CO2, SO2 and NOx) on the original compounds of the mortars, biominerals formed by the biological …
Field Raman analysis to diagnose the conservation state of excavated walls and wall paintings in the archaeological site of Pompeii (Italy)
2012
This work presents the results of field Raman analyses, assisted by a hand-held energy dispersive-X-ray fluorescence spectrometer, to experimentally determine the composition of compounds present in the walls and wall paintings of two Pompeian houses, one with many luxurious decorative elements (the House of Marcus Lucretius, Regio IX, Insula 3, House 5/24) and a more modest building (Regio IX, Insula 3, House 1–2). These houses were excavated 150 years ago, and the majority of the rooms have been exposed outdoors. The chemical attacks of the acid gases and the biological colonisation can be considered the most serious problems of the archaeological remains from Insula IX 3 of Pompeii. The …
Measurement of the p(e,e′π+)n reaction close to threshold and at low Q2
2017
The cross section of the $p(e,e'\pi^+)n$ reaction has been measured for five kinematic settings at an invariant mass of $W = 1094$ MeV and for a four-momentum transfer of $Q^2 = 0.078$ (GeV/$c$)$^2$. The measurement has been performed at MAMI using a new short-orbit spectrometer (SOS) of the A1 collaboration, intended for detection of low-energy pions. The transverse and longitudinal cross section terms were separated using the Rosenbluth method and the transverse-longitudinal interference term has been determined from the left-right asymmetry. The experimental cross section terms are compared with the calculations of three models: DMT2001, MAID2007 and $\chi$MAID. The results show that we …