Search results for "Spectrometer"
showing 10 items of 751 documents
Field-portable Mössbauer spectroscopy on Earth, the Moon, Mars, and beyond
2011
ABSTRACT Iron occurs naturally as Fe 2+ , Fe 3+ , and, to a lesser extent, as Fe 0 . Many fundamental (bio)geochemical processes are based on redox cycling between these oxidation states. Mossbauer spectroscopy provides quantitative information about the distribution of Fe among its oxidation states, identification of Fe-bearing phases, and relative distribution of Fe among those phases. Portable, miniaturised Mossbauer spectrometers were developed for NASA9s Mars Exploration Rovers (in operation since 2004) and provide a means for non-destructive, in-situ field investigations. On Mars, these instruments provided evidence for aqueous activity with implications for habitability, were applied…
Elastic neutron scattering of dry and rehydrated trehalose coated carboxy-myoglobin
2008
We report here a comparison between the hydrogen atoms mean square displacements measured by elastic neutron scattering on trehalose coated carboxy-myoglobin, at ILL on the backscattering spectrometers IN13 and IN16. An inconsistency is observed when comparing the mean square displacements measured on the two spectrometer, on samples of identical composition, since they resulted of larger amplitude on IN13 (either in condition of drought or after overnight rehydration under 75% D2O atmosphere), notwithstanding the lower time window accessible on this instrument with respect to IN16. Such inconsistency disappears when the data obtained on this last spectrometer are analyzed in two separate r…
Laser-Induced Breakdown Spectroscopy for Rapid Elemental Analysis of Drillcore
2013
Abstract The elemental and mineralogical contents of rock drillcore can be analyzed using a variety of methods. For efficient exploration the characterization of the drillcore should be performed rapidly, so that the further drillings can be better planned and unnecessary costs can be reduced. In this paper, laser-induced breakdown spectroscopy (LIBS) is studied as a potential rapid on-line method for automated elemental analysis of drillcore. The method is based on a pulsed laser beam that transforms a small volume of the sample into plasma. Individual elements in the plasma have characteristic emission patterns detectable by a spectrometer. Based on the measured spectra the amount of diff…
Coupled retrieval of aerosol optical thickness, columnar water vapor and surface reflectance maps from ENVISAT/MERIS data over land
2008
An algorithm for the derivation of atmospheric parameters and surface reflectance data from MEdium Resolution Imaging Specrometer Instrument (MERIS) on board ENVIronmental SATellite (ENVISAT) images has been developed. Geo-rectified aerosol optical thickness (AOT), columnar water vapor (CWV) and spectral surface reflectance maps are generated from MERIS Level-1b data over land. The algorithm has been implemented so that AOT, CWV and reflectance products are provided on an operational manner, making no use of ancillary parameters apart from those attached to MERIS products. For this reason, it has been named Self-Contained Atmospheric Parameters Estimation from MERIS data (SCAPE-M). The fund…
Spectral calibration and atmospheric correction of ultra-fine spectral and spatial resolution remote sensing data. Application to CASI-1500 data
2007
Imaging spectrometers operating in the solar spectrum measure the upwelling reflected solar radiation, and are an important tool in the bio/geochemical characterization of the Earth system. Surface reflectance is usually the starting point for the retrieval of biophysical parameters from remote measurements. Reliable radiometric and spectral calibrations and accurate atmospheric correction are mandatory in the interpretation of the surface reflectance. A complete surface reflectance retrieval scheme specifically designed for ultra-fine spectral resolution (bandwidth from 10 to 2 nm) and spatial resolution (pixel size less than 10 m) imaging spectrometers is presented in this work. The asses…
Reduction of Convective Low-Frequency Noise in Thermal Lens Spectrometry
1990
The construction and optimization of a thermal lens spectrometer with coaxial pump/probe configuration is reported. The low-frequency noise of convective origin is studied in detail, and it is demonstrated that a horizontal slit, instead of a pinhole, can be used as a simple way of reducing the noise to a negligible level without losing sensitivity.
New sunphotometer for network operation.
1983
A handheld sunphotometer has been developed and is described. It operates for 9 wavelengths in the visible and near infrared. The sensitivity range is rather broad, so it can be used in turbid as well as clear atmospheres. The operation is simple, and a digital readout helps prevent operator biases. The instrument is sun powered and suitable for network operations. Determination of the atmospheric turbidity due to aerosol and the column content of O3, NO2, H2O is possible.
Resonance ionization mass spectroscopy for trace determination of plutonium in environmental samples
1997
Resonance ionization mass spectroscopy (RIMS) is a sensitive and isotope selective method and well suited for trace analysis of plutonium in the environment. After the chemical isolation of plutonium from soil, air filters or urine, e.g., it is electrolytically deposited as hydroxide on a tantalum backing and covered with a thin titanium layer. By heating such a sandwich filament in the RIMS-apparatus under vacuum an atomic beam of plutonium is produced. The atoms are ionized by a three-step resonant excitation using pulsed dye lasers, and the ions are mass-selectively detected with a time-of-flight (TOF) spectrometer and a multi channel plate detector. RIMS yields a low detection limit of …
Vicarious calibration of MERIS over dark waters in the near infrared
2005
Abstract We propose to evaluate the calibration of MERIS (MEdium Resolution Imaging Spectrometer) over dark waters in the near infrared. We work with 5 months of data, from July to November 2003, over five world sites: Venice and Lampedusa in Italy, El Arenosillo in Spain, MOBY/Lanai and CalCOFI/San Nicolas in the United States. The sites are all equipped with a CIMEL station that forms part of the AERONET network. The basic idea is to associate CIMEL sky radiance measurements with MERIS level-1b data in a twin geometry which corresponds to the same scattering angle. This vicarious calibration relies on an accurate description of the atmospheric scattering based on the CIMEL measurements. A…
Routine application using single quadrupole liquid chromatography-mass spectrometry to pesticides analysis in citrus fruits.
2005
Abstract A rapid and sensitive liquid chromatography–electrospray ionization–mass spectrometry method has been developed for the routine analysis of buprofezin, bupirimate, hexaflumuron, tebufenpyrad, fluvalinate and pyriproxyfen in citrus fruits. Extracts were obtained by matrix solid-phase dispersion (MSPD) using C 18 as dispersant and dichloromethane-methanol (80:20, v/v) as eluent. Matrix effects were tested for all matrices by addition of standard to sample blank extracts (samples containing no detectable residues). Mean recoveries obtained at fortification levels between 0.01 and 5 mg kg −1 were 57–97% with relative standard deviations (RSDs) from 5 to 19%. The limits of quantificatio…