Search results for "Spectrometry"
showing 10 items of 3206 documents
Agronomical and chemical characterisation of Thymbra capitata (L.) Cav. biotypes from Sicily, Italy
2015
In this study the agromomical and chemical characterization of 13 sicilian biotypes of Thymbra capitata (L.) Cav. (or Thymus capitatus Hoff. et Link.) collected from different areas of Sicily (Italy) and grown under the same agricultural and environmental condition are reported. The main morpho-productive parameters and quali-quantitative profile of essential oils were determined . Essential oils were extracts from the aerial parts of the plants by hydrodistillation. The essential oils were analyzed by GC-FID and GC-MS. Hierarchical Cluster Analysis and Principal Component Analysis statistical methods were used to group biotypes according to the essential oils chemical composition. The esse…
Different sample treatment approaches for the analysis of T-2 and HT-2 toxins from oats-based media.
2010
A LC-DAD method is proposed for the determination of the T-2 and HT-2 toxins in cultures of Fusarium langsethiae in oat-based and other in vitro media. Test media consisted of freshly prepared milled oats to which T-2 and HT-2 toxin stock solutions were added. Different mixtures of extraction solvent (acetonitrile:water and methanol water), extraction times (30', 60' or 90') and drying methods were investigated. Results showed that extraction with methanol: water (80:20, v/v) for 90 min, drying with N-2 and subsequent analysis by LC-DAD was the fastest and most user friendly method for detecting HT-2 and T-2 toxins production by F. langsethiae strains grown on oat-based media at levels of 0…
Gas chromatography/mass spectrometry characterization of historical varnishes of ancient Italian lutes and violin
2007
The organic constituents of historical vanishes from two ancient Italian lutes and a Stradivari violin, kept in the Musée de la musique in Paris, have been characterized using gas chromatography-mass spectrometry. Results have been compared with the chromatograms and mass spectra of recent as well as old naturally aged reference materials. The three historical varnishes analyzed have been shown to be oil varnishes, probably mixtures of linseed oil with resins. Identification of diterpenoids and triterpenoids compounds, and of the resins that may have been ingredients of the varnishes, are discussed in this paper.
Observation of the rare B(s)(0) + decay from the combined analysis of CMS and LHCb data.
2015
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 Unported licence.-- et al.
Measurement of long-lived radionuclide activity induced in target components of a cyclotron used for [18F ]-[FDG] production
2019
The evaluation of high activity induced in target components in using a medical cyclotron to produce positron-emitting radionuclides for PET (Positron Emission Tomography) diagnostic studies is one of important issue and involves radiation protection concepts when operators are engaged in maintenance and/or substitution of a target or its components. Most of replaced target components are generally classified and stored in a Pb-shielded container in order to wait for their radioactive decay. However, after some years, it can be necessary to start with the removal of the oldest parts, for a temporary storage of the fresh activated ones. The feasibility of these operations and the waste final…
Coincidence-Summing corrections in high resolution gamma-ray spectrometry: simplified analytical expressions
2010
Simplified expressions to determine the coincidence-summing correction factors by using a matrix representation of a decay scheme are reported. Expressions can be used directly for point sources, with the introduction of full-energy-peak and total efficiencies, while for extended sources a more complex procedure, though approximate, is suggested.
On the feasibility of dating the age of a nuclear incidental event by gamma-ray spectrometry of environmental samples
2019
The dating of a nuclear incidental event is an important element for the assessment of its enviromental impact and radiation protection implications on the involved population. In this framework, a procedure has already been proposed to determine the age of a nuclear event by measuring through a gamma-ray spectrometric analysis the activity of two fission products in a small sample of uranium irradiated for a short time in a nuclear reactor [1,2]. However, It may be useful to extend the application of the above mentioned procedure for assessing the “timing of occurrence” of an incidental event considering other samples and in particular, by sampling and measuring environmental samples. The …
Volatile flavour components of ocimum basilicum var. hispidum (lam.) Chiov.
1991
The volatile components obtained by steam-distillation ofOcimum basilicum var. hispidum (Lam.) Chiov. (Labiatae) were analysed by gas chromatography (GC) and gas chromatography—mass spectrometry (GC-MS). A total of 21 compounds, representing ca 90% of the total oil, were identified. The identity of the main component (82%), dihydrotagetone, was confirmed by 1H- and 13C-NMR spectroscopy. This is the first report of this compound in the genus Ocimum.
Determination of 60 Migrant Substances in Plastic Food Contact Materials by Vortex-Assisted Liquid-Liquid Extraction and GC-Q-Orbitrap HRMS
2021
A GC-HRMS analytical method for the determination of 60 migrant substances, including aldehydes, ketones, phthalates and other plasticizers, phenol derivatives, acrylates, and methacrylates, in plastic food contact materials (FCM) has been developed and validated. The proposed method includes migration tests, according to Commission Regulation (EU) 10/2011, using four food simulants (A, B, C, and D1), followed by vortex-assisted liquid–liquid extraction (VA-LLE) and GC-Q-Orbitrap HRMS analysis in selected ion monitoring (SIM) mode, with a resolving power of 30,000 FWHM and a mass accuracy ≤5 ppm. The method was validated, showing satisfactory linearity (R2 ≥ 0.98 from 40 to 400 …
Antibodies to alpha B-crystallin, vimentin, and heat shock protein 70 in aqueous humor of patients with normal tension glaucoma and IgG antibody patt…
2007
To show the existence of IgG antibodies against retinal antigens in aqueous humor of normal tension glaucoma patients.Forty-two patients were included in this study. Aqueous humor was collected from control subjects (CO; n = 21) and patients with normal tension glaucoma (NTG; n = 21). Western blot methods against bovine retinal antigens were used to detect the IgG antibody patterns. The complex antibody repertoires were analyzed by multivariate statistical techniques. Mass spectrometry was used to identify the most important antigens.Very complex IgG antibody patterns against retinal antigens were found in all analyzed aqueous humor samples. Our multivariate approach could quantify differen…