Search results for "Spectroscopic."
showing 10 items of 115 documents
Stress-induced cytological and chemical adaptations in Cupressus plants from an urban area of Palermo (Italy)
2004
We studied stress-induced cytological and chemical adaptations in Cupressus pollens and needles from the area of Palermo (Sicily, Italy), in polluted and control sites (unpolluted) of urban and suburban areas. Pollen and needle chemical composition were investigated to provide an indicator of contamination of the trees, which were also examined structurally throughout one year. The concentration of particulate with lead was found to be significantly higher in plants at the polluted traffic site. Lead is one of the worst particulate pollutants in cities, especially in the winter season. In trees from the polluted site, all structural analysis revealed displasies. Structural changes, observed…
Comprehensive Study on the Performance of Waste HDPE and LDPE Modified Asphalt Binders for Construction of Asphalt Pavements Application
2022
This research is aimed at investigating the mechanical behavior of the bitumen by the addition of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) obtained from waste plastic bottles and bags. Polymers (HDPE and LDPE) with percentages of 0%, 2%, 4%, and 6% in shredded form by weight of bitumen were used to evaluate the spectroscopic, structural, morphological, and rheological properties of polymer-modified binders. The rheological properties for different factors; viscosity (ἠ) from Rotational Viscometer (RV), rutting factor G*/Sin (δ), fatigue characteristics G*. Sin (δ), for the modified binder from dynamic shear rheometer (DSR), Short and long-term a…
Multi-commutation in spectrometry
2009
We review recent developments in manifold components and the introduction of light-emitting-diode technology in spectroscopic detection in order to evaluate the tremendous possibilities offered by multi-commutation for in-field and in-situ measurements, based on the use of multi-pumping and low-voltage, portable batteries, which make possible a dramatic reduction in size, weight and power requirements of spectrometric devices.
The HITRAN2016 molecular spectroscopic database
2017
This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of …
Accretion in young stars: measure of the stream velocity of TW Hya from the X-ray Doppler shift
2015
High-resolution X-ray spectra are a unique tool to investigate the accretion process in young stars. In fact X-rays allow to investigate the accretion-shock region, where the infalling material is heated by strong shocks due to the impact with the denser stellar atmosphere. Here we show for the first time that it is possible to constrain the velocity of the accretion stream by measuring the Doppler shift of the emitted X-rays. To this aim we analyzed the deep Chandra/HETGS observation of the accreting young star TW Hya. We selected a sample of emission lines free from significant blends, fitted them with gaussian profiles, computed the radial velocity corresponding to each line, and average…
High Resolution X-ray Spectroscopy of Pre-Main-Sequence Stars: TWA 5 and PZ Tel
2004
We report on the analysis of high resolution X-ray spectra of two pre-main-sequence stars: TWA 5 (observed with XMM-Newton) and PZ Telescopii (observed with Chandra/HETGS). TWA 5 is a classical T Tauri star in the TW Hydrae association while PZ Tel is a rapidly rotating weak-lined T Tauri star in the beta-Pictoris moving group. For both stars we have reconstructed the emission measure distribution and derived the coronal abundances to check for possible patterns of the abundances related to the first ionization potential of the various elements. We have also derived estimates of the plasma density from the analysis of the He-like triplets. We compare the characteristics of our targets with …
Correcting the effect of stellar spots on ARIEL transmission spectra – II. The limb-darkening effect
2021
This paper is part of an effort to correct the transmission spectra of a transiting planet orbiting an active star. In Paper I (Cracchiolo et al. 2020) we have demonstrated a methodology to minimize the potential bias induced by unocculted star spots on the transmission spectrum, assuming a spot model parameterized by filling factor and temperature. In this work we introduce the limb darkening effect, therefore the position of the spot in the stellar disk and the impact parameter of the transiting planet now play a key role. The method is tested on simulations of planetary transits of three representative kinds of planetary systems, at ARIEL resolution. We find that a realistic treatment of…
The Gaia-ESO survey: Discovery of a spatially extended low-mass population in the Vela OB2 association
2015
The nearby (distance~350-400 pc), rich Vela OB2 association, includes $\gamma^2$ Velorum, one of the most massive binaries in the solar neighbourhood and an excellent laboratory for investigating the formation and early evolution of young clusters. Recent Gaia-ESO survey observations have led to the discovery of two kinematically distinct populations in the young (10-15 Myr) cluster immediately surrounding $\gamma^2$ Velorum. Here we analyse the results of Gaia-ESO survey observations of NGC 2547, a 35 Myr cluster located two degrees south of $\gamma^2$ Velorum. The radial velocity distribution of lithium-rich pre-main sequence stars shows a secondary population that is kinematically distin…
Clerodane diterpenoids from Salvia splendens.
2006
Four new clerodane diterpenoids, salvisplendins A-D (1-4), have been isolated from an acetone extract of the flowers of SalVia splendens, together with an artifact (5), arising from salvisplendin D (4) by addition of diazomethane, and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and, in the case of salvisplendin A (1), by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6), not published hitherto, are also reported.
La pittura vascolare attica a fondo bianco: la prospettiva archeologica, l'apporto dell'indagine scientifica
2017
Il presente contributo intende offrire nuovi spunti di ricerca sui vasi attici a fondo bianco e sulla relativa tecnica pittorica. In particolare, è stato selezionato come caso di studio il cratere del Pittore della Phiale (450-440 a.C.) con il mito di Perseo e Andromeda, esposto nel Museo Archeologico di Agrigento. La prima parte del lavoro si concentra sugli aspetti archeologici e storico-artistici, cercando di ricostruire il ruolo di questa tecnica nella produzione figurativa dell’artigiano e il rapporto tra il cratere di Agrigento e gli altri prodotti del Pittore della Phiale. Inoltre, viene considerata la connessione tra tecnica e con- testo di utilizzo e acquirenti o “committenti”, la…