Search results for "Spectroscopy"

Optimisation algorithms in the case of mineral detection using Raman Analysis

2013

Abstract Raman analysis can be used to analyse the existence of minerals in an ore sample. Especially the interest here is to analyse given ore sample rapidly, to find out what minerals it contains. Rapid analysis would enable more rapid exploration of minerals as analysis could be carried out on-site. For this study, ore samples were collected from two mines in Northern Finland, Kittila and Kevitsa. An optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum from an ore sample. The reference spectra were collected from a public source. It was found that solving for an optimal summation of reference spectra can be a …

Methods for the vibrational spectroscopy analysis of beers

2009

The main possibilities and drawbacks of vibrational spectroscopy techniques, infrared (both in the middle and near infrared ranges) and Raman, for the analysis of beers have been reviewed taking into consideration methods proposed in the scientific literature for the determination of as many as possible compounds and parameters of beers. Details about the procedures available and comments on the future developments in this field have been based on the experience of authors and extended checking of the characteristics of the procedures published till now.

ChemInform Abstract: Cyclic SiS2: A New Perspective on the Walsh Rules.

2012

Cyclic SiS2 is detected in the low-current dc discharge products of a mixture of SiH4 and H2S by Fourier transform microwave spectroscopy.

High-resolution spectroscopy and analysis of the ν4 band of 80SeF6

2001

Abstract The Fourier-transform spectrum of the ν4 bending region of 80 SeF 6 around 435 cm −1 has been recorded at a temperature of 217 K with a resolution of 2.3×10 −3 cm −1 . This fundamental has been analyzed using the set of programs called highly spherical top data system (HTDS). Altogether 958 transitions were assigned and fitted with an rms of 0.0003 cm −1 . The effective Hamiltonian was developed up to the fourth order. Parameters and simulations are presented. The ν4 band center is located at 435.099 cm −1 .

High Resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) Of O 2 And CO 2

1988

With the help of high spectral quality (linewidth , 6 MHz) injection-locked flashlamp-pumped dye lasers, high resolution Coherent Anti-Stokes Raman Spectroscopy (CARS) has been applied to the study of the Q-branches of 0 2 and CO 2 . The Q-branch linewidths of 02 were obtained from the first nine transitions (J 2 = 1 to 17) recorded at pressures from 0.094 to 1 atm at room temperature. A least squares program was employed to fit calculated spectra to experimental spectra by adjusting different parameters. The collisional broadening coefficients we have obtained are consistent with available Raman data. We have also studied the Q-branch of the fundamental v1 band of CO 2 in the Fermi resonan…

Synthesis, Characterization of FexZr1-xO2Solid Solution Nanoparticles and Bulk Powders Prepared Using a Sol-Gel Technique

2015

Electrical Transport and Confocal Raman Studies of Electrochemically Modified Individual Carbon Nanotubes

2003

Erratum to ‘Raman spectroscopy of β-irradiated silica glass’ by B. Boizot, S. Agnello, B. Reynard, R. Boscaino and G. Petite [J. Non-Cryst. Solids 32…

2004

<title>Electrochromism of W-oxide-based films: some theoretical and experimental results</title>

1995

We survey some recent work related to electrochromic W-oxide-based thin films. The electronic structure of cubic (perovskite) WO3 and HWO3 was calculated from first principles. It was found, among other things, that hydroxide formation was energetically favored. Experimental studies were made on films prepared by reactive magnetron sputtering in Ar + O2 with and without CF4 addition and substrate bias. Structural studies by atomic force microscopy, x-ray diffraction, infrared reflectance spectroscopy, and Raman spectroscopy indicated that the electron bombardment associated with a positive substrate bias led to grain growth and partial crystallization while maintaining a high density of W e…

High Resolution Coherent Raman Spectroscopy: Studies of Molecular Structures

1992

One of the main advantages of the non-linear coherent Raman techniques is the high resolution that can be achieved in rovibrational spectroscopy. Typically an instrumental function of the order of several thousandths of a wavenumber is routinely achieved in SRS or CARS experiments. Since the first recording of the stimulated Raman spectrum of 12CH4 in 1978 [1], numerous studies of molecules have been performed [2–8]. We have built a stimulated Raman experiment in Dijon in which particular attention has been paid to the frequency measurement of the Raman lines [9]. We will describe the application of our experiment to a wide variety of molecules over the last few years: linear molecules, sph…