Search results for "Spectroscopy"
showing 10 items of 10293 documents
The “recipe” of the stucco sculptures of Giacomo Serpotta
2002
Abstract Mineralogical and chemical data (organic) of some representative samples collected from stucco-works by the famous Sicilian sculptor Giacomo Serpotta (Palermo, 1656–1732) have been combined with the aim of ascertaining their manufacture technology in the light of local historical sources. A complete correspondence between samples belonging to the “Victory” statue (1723) and the S.S. Rosario oratory (1685–1689) as regards stratigraphy, mineralogy of sand aggregate, composition of binder matrix, and nature and concentrations of organic additives is pointed out. Considering that the studied works of art cover more than 35 years of the artist’s activity, it is consequential to think of…
Deep learning to detect built cultural heritage from satellite imagery. - Spatial distribution and size of vernacular houses in Sumba, Indonesia -
2021
Abstract In Sumba Island – Indonesia, the implantation of vernacular houses, inside and outside traditional villages, is considered to be an efficient proxy for the on-going complex cultural transformations resulting from globalization. This study presents an easily reproducible workflow allowing buildings to be automatically detected from satellite imagery, demonstrating how modern computer vision methods based on deep learning can help in this task, which would be far too time-consuming when undertaken by hand. Eight deep learning architectures based on convolutional neural networks were compared in terms of ability to identify and locate precisely traditional houses from satellite images…
Documenting carved stones from 3D models. Part II - Ambient occlusion to reveal carved parts.
2021
10 pages; International audience; Revealing carved parts in rock art is of primary importance and remains a major challenge for archaeological documentation. Computational geometry applied to 3D imaging provides a unique opportunity to document rock art. This study evaluates five algorithms and derivatives used to compute ambient occlusion and sky visibility on 3D models of Mongolian stelae, also known as deer stones. By contrast with the previous companion work, models are processed directly in 3D, without preliminary projection. Volumetric obscurance gives the best results for the identification of carved figures. The effects of model resolution and parameters specific to ambient occlusio…
Exotic insect pests: The impact of the Red Palm Weevil on natural and cultural heritage in Palermo (Italy)
2013
Abstract The impact of invasive exotic pests is increasingly recognised as a global issue. A global strategy to address the exotic pest problem is beginning to evolve, albeit slowly. The International Plant Protection Convention (FAO) has begun the process of harmonizing standards for pest risk analysis to minimise the spread of exotic pests without adversely impacting global trade. However if the impacts of insect invasive species on human health and on agriculture have attracted worldwide attention, researchers and policymakers address directly the connection between invasive species and damage to natural and cultural heritages. The cost of these losses is generally neglected or underesti…
Erratum to “Exotic insect pests: The impact of the Red Palm Weevil on natural and cultural heritage in Palermo (Italy)” [J. Cult. Herit. 14 (3S) (201…
2014
The correct caption for Figure 4 is: Palm groves with Phoenix canariensis palm trees: (a) Cittadella Universitaria (photo already published n S. Colazza, G. Filardo, A. Motisi, G. Barbera 2009. Il campo sperimentale del “giardinetto delle palme” dell’Ateneo palermitano di viale elle Scienze. In La ricerca scientifica sul punteruolo rosso e gli altri fitofagi delle palme in sicilia. (pp. 21–24). Marsala TP: Regione Siciliana ssessorato Agricoltura e Foreste and (b) Palm promenade in Foro Italico; only one palm is present.
Investigation on four centuripe vases (late 3rd-2nd cent. B.C.) by portable X-ray fluorescence and total reflectance-FTIR
2021
Abstract Four Centuripe vases dated back to the late 3rd-2nd centuries B.C. were analysed using imaging under visible and ultra-violet illumination as well as complementary non-invasive and non-destructive portable X-Ray Fluorescence (XRF) and Total Reflectance – Fourier Transform InfraRed (TR-FTIR) spectroscopies. The vases are of great importance since they represent a rare expression of the Hellenistic vase painting. Four specimens, a “pyxis”, a “lebes gamikos” and two “lekanides” decorated with figures of different type, are exhibited in the Antonino Salinas Archaeological Museum in Palermo-Italy. The investigation was aimed to identify the used pigments and the painting technique, to r…
Non-Invasive Investigation of Pigments of Wall Painting in S. Maria Delle Palate di Tusa (Messina, Italy)
2019
The characterization of materials used in the archaeological field needs an experimental approach in order to avoid the destruction or perturbation of artworks. In order to afford this purpose, a multi-analytical spectroscopic approach is regularly used. We combined non-invasive analysis by using handheld spectroscopic instrumentations (mainly XRF and Raman spectrometers) in order to characterize the wall painting preserved in the church of S. Maria delle Palate at Halaesa Arconidea archeological site (Tusa, Messina, Italy). The aim of the work is the characterization of the nature of pigments used for the realization of the wall painting. The wall painting, probably representing St. Franci…
A smartphone-based innovative approach to discriminate red pigments in roman frescoes mock-ups
2022
The characterization of red pigments in frescoes wall paintings has been of great interest for researchers to better understand raw material procurement dynamics, pigment receipts, stylistic evolution and to assess their conservation state. In this study a non-destructive colorimetric approach implementing a smartphone-based method was developed in order to be able to distinguish between three pigments made from minium, haematite and cinnabar minerals, and also mixed pigments, preparing frescoes mock-ups following the roman receipt described by Vitruvius. Portable FT-IR, Raman spectroscopy, portable XRF and visible reflectance spectra analyses were carried out as reference methods for smart…
Unusual oleanane-type saponins from Arenaria montana
2010
Three oleanane-type saponins, 3-O-β-d-glucopyranosylechinocystic acid 28-O-β-d-xylopyranosyl-(1→4)-[α-l-rhamnopyranosyl-(1→2)]-α-l-rhamnopyranosyl ester (1), 3-O-β-d-glucopyranosylechinocystic acid 28-O-α-l-arabinopyranosyl-(1→3)-β-d-xylopyranosyl-(1→4)-[α-l-rhamnopyranosyl-(1→2)]-α-l-rhamnopyranosyl ester (2), 3-O-β-d-glucopyranosylcaulophyllogenin 28-O-β-d-apiofuranosyl-(1→3)-β-d-xylopyranosyl-(1→4)-[β-d-apiofuranosyl-(1→3)]-α-l-rhamnopyranosyl-(1→2)-α-l-rhamnopyranosyl ester (3) were isolated from the whole plant of Arenaria montana. Their unusual structures for the Caryophyllaceae family were established mainly by 2D NMR techniques and mass spectrometry.
New organotin(IV) complexes with L-Arginine,Nα-t-Boc-L-Arginine and L-Alanyl-L-Arginine.Synthesis, structural investigations and cytotoxic activity
2010
Abstract Novel diorganotin(IV) derivatives of l -Arginine (HArg), N α -( tert -Butoxycarbonyl)- l -Arginine (Boc–Arg–OH) and l -Ala- l -Arg (H 2 Ala–Arg), H 2 NC( NH)NH(CH 2 ) 3 CH(NHR′)CO 2 H, where R′ = H in HArg, R′ = C(O)OC(CH 3 ) 3 in Boc–Arg–OH, R′ = H 2 NCH(CH 3 )CO in H 2 Ala–Arg and triorganotin(IV) derivatives of Boc–Arg–OH have been synthesized and structurally characterized. The complexes were investigated by FT-IR and 119 Sn Mossbauer in the solid state and by 1 H, 13 C, 119 Sn and 1 H– 1 H COSY NMR spectroscopy, in solution. The spectroscopic characterization leading to the proposed molecular structures was accomplished on the basis of these experiments. l -Arginine appears to…