Search results for "Spectroscopy"
showing 10 items of 10293 documents
Application of non-invasive technologies in dry-cured ham: An overview
2019
Background: Dry-cured ham is one of the most valued food products by Mediterranean consumers. In this sense, the appropriate development of its different production stages is essential to ensure the quality requirements. For this reason, non-invasive technologies have gained popularity and have been reported as useful not only to ensure the food safety of different products, but also to monitor fundamental stages in the production process, such as the salting stage, to analyze the content of different compounds without sample losses, and to correct possible defects in the final product. Scope and approach: This work has been focused on summarizing the studies that describe and have successf…
Quantum correlation of electron and ion energy in the dissociative strong-field ionization of H2
2023
We report on the strong field ionization of H2 by a corotating two-color laser field. We measure the electron momentum distribution in coincidence with the kinetic energy release (KER) of dissociating hydrogen molecules. In addition to a characteristic half-moon structure, we observe a low-energy structure in the electron momentum distribution at a KER of about 3.5 eV. We speculate that the outgoing electron interacts with the molecular ion, despite the absence of classical recollisions under these conditions. Time-dependent density functional theory simulations support our conclusions.
First-principles modelling for time-resolved ARPES under different pump-probe conditions
2021
First-principles methods for time-resolved angular resolved photoelectron spectroscopy play a pivotal role in providing interpretation and microscopic understanding of the complex experimental data and in exploring novel observables or observation conditions that may be achieved in future experiments. Here we describe an efficient, reliable and scalable first-principles method for tr-ARPES based on time-dependent density functional theory including propagation and surface effects usually discarded in the widely used many-body techniques based on computing the non-equilibrium spectral function and discuss its application to a variety of pump–probe conditions. We identify four conditions, dep…
Cavités plasmoniques et nanosources optiques
2013
Optical microcavities exhibit high resonance quality, so that, they are of key interest for the design of low-threshold lasers or for achieving strong coupling regime. But, such systems support modes whose the volume remain diffraction limited.In this manuscript, we are interested in their plasmonic counterparts because they support confined modes at the sub-wavelength scale. First, we study an in-plane plasmonic cavity which is the transposition of 1D optical cavity to surface wave. We characterize the cavity by measuring the fluorescence lifetime of dye molecules deposited inside.Then, we are interested in 3-dimension mode confinement achieved by spherical metal nanoparticles. We discuss …
Ultrafast excitation dynamics of low energy pigments in reconstituted peripheral light-harvesting complexes of photosystem I
2000
AbstractUltrafast dynamics of a reconstituted Lhca4 subunit from the peripheral LHCI-730 antenna of photosystem I of higher plants were probed by femtosecond absorption spectroscopy at 77 K. Intramonomeric energy transfer from chlorophyll (Chl) b to Chl a and energy equilibration between Chl a molecules observed on the subpicosecond time scale are largely similar to subpicosecond energy equilibration processes within LHCII monomers. However, a 5 ps equilibration process in Lhca4 involves unique low energy Chls in LHCI absorbing at 705 nm. These pigments localize the excitation both in the Lhca4 subunit and in LHCI-730 heterodimers. An additional 30–50 ps equilibration process involving red …
Defects in quantum ring to control high-harmonic spectrum
2017
AbstractThe high-harmonic generation from a structured quantum ring (SQR) driven by an intense laser field is presented within the single active electron approximation. The spectrum is studied by varying the symmetry of the physical system. The standard SQR (six identical and equidistant dots in a ring) presents a 60° rotational symmetry, that in this work is broken, moving or changing only one potential hole. We find that careful designed breaking of the geometrical symmetry of the SQR opens the possibility of controlling the characteristics of the harmonic lines such as intensity and polarization. HHG analysis of the emission spectrum performed through a Morlet wavelet, shows that the hig…
CHAPTER 12: Real-time and Real-space Time-dependent Density-functional Theory Approach to Attosecond Dynamics
2018
After the advances in strong infrared laser sources and high harmonic generation techniques, the measurement of attosecond dynamics of excited states in molecules has become a reality in many laboratories around the world. The interpretation of these novel ultrafast experiments, aiming at increasingly large molecules, poses considerable theoretical and computational challenges that can be tackled in the framework of time-dependent density functional theory (TDDFT). In this chapter we survey the basics of TDDFT in its real-time and real-space implementation, with particular emphasis on its advantages and limitations in the description of attosecond dynamics. The applicability of this approac…
Simulating pump-probe photo-electron and absorption spectroscopy on the attosecond time-scale with time-dependent density-functional theory
2013
Molecular absorption and photoelectron spectra can be efficiently predicted with real-time time-dependent density functional theory. We show herein how these techniques can be easily extended to study time-resolved pump-probe experiments, in which a system response (absorption or electron emission) to a probe pulse is measured in an excited state. This simulation tool helps with the interpretation of fast-evolving attosecond time-resolved spectroscopic experiments, in which electronic motion must be followed at its natural timescale. We show how the extra degrees of freedom (pump-pulse duration, intensity, frequency, and time delay), which are absent in a conventional steady-state experimen…
Electrosynthesis of Sn-Co nanowires in alumina membranes
2010
A fabrication process of amorphous nanowires of Sn-Co alloys, based on electrodeposition into anodic alumina membranes, is described. It is shown that nanowires of tin-cobalt alloys with different compositions can be produced by varying electrodeposition time and concentration ratio of salts dissolved into the electrolytic bath. Importance of the chelating agent to produce amorphous Sn-Co alloys has also been addressed. Electrodepositions were carried out potentiostatically at -1 V versus Saturated Calomel Electrode and 60 degrees C for times ranging from 10 to 90 minutes; the atomic fraction of Co2+ in the aqueous electrolyte (Co2+/(Co2+ + Sn2+)) was varied from 0.33 to 0.67. Nanowires asp…
Study of the dynamics of biomolecules by high speed atomic force microscopy and surface enhanced Raman spectroscopy
2015
This thesis focuses on the coupling of High–Speed Atomic Force Microscopy (HS-AFM) and Surface Enhanced Raman Spectroscopy (SERS) for biomolecule analysis. We have designed a fabrication protocol to manufacture “SERS-active” substrates. The efficacy of gold, silver and gold-silver bimetallic crystalline nanoparticle substrates were evaluated. We have investigated the impact of optical and morphological features of the substrates on Raman signal intensity by analyzing well-known samples such as bipyridine ethylene and methylene blue molecules. We took an interest in three distinct biological problematics with HS-AFM and SERS analyses. First, we have detected the chemical signature of cytochr…