Search results for "Stability."
showing 10 items of 3015 documents
The Instability of Ni{N(SiMe3 )2 }2 : A Fifty Year Old Transition Metal Silylamide Mystery.
2015
The characterization of the unstable Ni(II) bis(silylamide) Ni{N(SiMe3 )2 }2 (1), its THF complex Ni{N(SiMe3 )2 }2 (THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3 )2 }2 (py)2 (3), is described. Both 1 and 2 decompose at ca. 25 °C to a tetrameric Ni(I) species, [Ni{N(SiMe3 )2 }]4 (4), also obtainable from LiN(SiMe3 )2 and NiCl2 (DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of Ni(II) to Ni(I) and the stabilization of 4 through dispersion forces.
Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species
2016
El mateix article està publicat en alemany a l'edició alemanya d' 'Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2016, vol. 128, núm. 21, p.6418–6422. DOI http://dx.doi.org/10.1002/ange.201601396 The reaction of [Fe(CF3SO3)2(PyNMe3)] with excess peracetic acid at −40 °C leads to the accumulation of a metastable compound that exists as a pair of electromeric species, [FeIII(OOAc)(PyNMe3)]2+ and [FeV(O)(OAc)(PyNMe3)]2+, in fast equilibrium. Stopped-flow UV/Vis analysis confirmed that oxygen atom transfer (OAT) from these electromeric species to olefinic substrates is exceedingly fast, forming epoxides with stereoretention. The impact of the electronic and steric properties of the subs…
Recent Borexino results and perspectives of the SOX measurement
2017
International audience; Borexino is a liquid scintillator detector sited underground in the Laboratori Nazionali del Gran Sasso (Italy). Its physics program, until the end of this year, is focussed on the study of solar neutrinos, in particular from the Beryllium, pp, pep and CNO fusion reactions. Knowing the reaction chains in the sun provides insights towards physics disciplines such as astrophysics (star physics, star formation, etc.), astroparticle and particle physics. Phase II started in 2011 and its aim is to improve the phase I results, in particular the measurements of the neutrino fluxes from the pep and CNO processes. By the end of this year, data taking from the sun will be over…
Dynamic Demand and Mean-Field Games
2017
Within the realm of smart buildings and smart cities,\ud dynamic response management is playing an ever-increasing\ud role thus attracting the attention of scientists from different\ud disciplines. Dynamic demand response management involves a\ud set of operations aiming at decentralizing the control of loads\ud in large and complex power networks. Each single appliance\ud is fully responsive and readjusts its energy demand to the\ud overall network load. A main issue is related to mains frequency\ud oscillations resulting from an unbalance between supply and\ud demand. In a nutshell, this paper contributes to the topic by\ud equipping each signal consumer with strategic insight. In particu…
On stability and dissipativity of stochastic nonlinear systems
2012
Input-to-state stability of nonlinear control system is described in several different manners, and has been a central concept since the equivalences among them were verified. In this paper, a framework of stability and dissipativity for stochastic control systems is constructed on the maximal existence interval of behaviors (states and external inputs), by the aid of stochastic Barbalat lemma and stochastic dissipativity. The main work consists of three aspects. First, input-to-state stability and robust stability are extended to the stochastic case, and several criteria are established. Second, two forms of dissipativity and their criteria are presented. Third, the key relations among the…
Stability under influence of noise with regulated periodicity
2009
A very simple stochastic differential equation with quasi‐periodical multiplicative noise is investigated analytically. For fixed noise intensity the system can be stable at high noise periodicity and unstable at low noise periodicity.
Competition between the buckling-driven delamination and wrinkling in compressed thin coatings
2012
Abstract The competition between two common failure modes of a thin coating under in-plane compression, the surface wrinkling and the buckling-driven delamination, is studied to assess the critical strain when the mechanical instability may occur at given geometrical and material parameters. A buckling map is constructed based on results of a finite element analysis, which relates the critical applied strain for the onset of instability to the interface adhesion and elastic properties of materials. An approximate scaling relation is derived for the energy release rate of buckling-driven delamination of a coating deposited on a compliant substrate.
Set-valued and fuzzy stochastic differential equations driven by semimartingales
2013
Abstract In the paper we present set-valued and fuzzy stochastic integrals with respect to semimartingale integrators as well as their main properties. Then we study the existence of solutions to set-valued and fuzzy-set-valued stochastic differential equations driven by semimartingales. The stability of solutions is also established.
High-resolution crystal structure of an avidin-related protein: insight into high-affinity biotin binding and protein stability.
2004
The chicken avidin gene belongs to an extended gene family encoding seven avidin-related genes (AVRs), of which only avidin is expressed in the chicken. The sequences of AVR4 and AVR5 are identical and the common protein (AVR4) has been expressed both in insect and bacterial systems. The recombinant proteins are similarly hyperthermostable and bind biotin with similarly high affinities. AVR4 was crystallized in the apo and biotin-complexed forms and their structures were determined at high resolution. Its tertiary and quaternary structures are very similar to those of avidin and streptavidin. Its biotin-binding site shows only a few alterations compared with those of avidin and streptavidin…
Numerical simulation of resonant activation in a fluctuating metastable model system
1998
We study the escape time from a metastable overdamped model system in the presence of two noise sources: a white noise and a random telegraph noise. The random telegraph noise controls the height of the potential barrier of the metastable system while the white noise mimics the presence of a given temperature. We report on numerical simulations about: (i) the average residence time of the system in the metastable state; (ii) the probability density function (PDF) of the residence time at various values of the correlation time T c of the random telegraph noise. Resonant activation is observed in the dynamics of the investigated system. The PDF shows different shapes for different values of τ…